全文获取类型
收费全文 | 276篇 |
免费 | 7篇 |
专业分类
化学 | 161篇 |
晶体学 | 9篇 |
力学 | 9篇 |
数学 | 26篇 |
物理学 | 78篇 |
出版年
2022年 | 7篇 |
2021年 | 7篇 |
2020年 | 7篇 |
2019年 | 4篇 |
2018年 | 6篇 |
2016年 | 6篇 |
2015年 | 6篇 |
2014年 | 11篇 |
2013年 | 27篇 |
2012年 | 11篇 |
2011年 | 13篇 |
2010年 | 5篇 |
2009年 | 6篇 |
2008年 | 8篇 |
2007年 | 12篇 |
2006年 | 10篇 |
2005年 | 10篇 |
2004年 | 14篇 |
2003年 | 7篇 |
2002年 | 7篇 |
2001年 | 8篇 |
2000年 | 12篇 |
1999年 | 2篇 |
1998年 | 5篇 |
1997年 | 7篇 |
1996年 | 1篇 |
1995年 | 4篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1981年 | 1篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1973年 | 1篇 |
1970年 | 1篇 |
1968年 | 1篇 |
1967年 | 1篇 |
1959年 | 1篇 |
1954年 | 1篇 |
排序方式: 共有283条查询结果,搜索用时 78 毫秒
61.
A. Dhal R. K. Sinha D. Negi T. Trivedi M. K. Raju D. Choudhury G. Mohanto S. Kumar J. Gehlot R. Kumar S. Nath S. S. Ghugre R. P. Singh J. J. Das S. Muralithar N. Madhavan J. B. Gupta A. K. Sinha A. K. Jain I. M. Govil R. K. Bhowmik S. C. Pancholi L. Chaturvedi 《The European Physical Journal A - Hadrons and Nuclei》2012,48(3):1-10
The odd mass nucleus 137Pm has been studied to high spins through the 109Ag(32S, 2p2n)137Pm reaction at an incident beam energy of 150 MeV. The de-exciting ??-rays were detected using an array of 18 Compton suppressed clover detectors. The level scheme of 137Pm has been extended up to $J^\pi = \tfrac{{43}} {2}^ -$ and excitation energy of E x ? 6 MeV with the observation of 42 new gamma transitions. The linear polarization (IPDCO) measurements for the ??-ray transitions have been done for the first time. The spin and parity assignments for most of the reported levels have been made using these results and the coincidence angular anisotropy (RDCO) measurements. The nuclear shape evolution is discussed in the light of Total Routhian Surface (TRS) and Cranked Shell Model (CSM) calculations. 相似文献
62.
Simone Giombi Shiraz Minwalla Shiroman Prakash Sandip P. Trivedi Spenta R. Wadia Xi Yin 《The European Physical Journal C - Particles and Fields》2012,72(8):1-65
We study three-dimensional conformal field theories described by U(N) Chern?CSimons theory at level k coupled to massless fermions in the fundamental representation. By solving a Schwinger?CDyson equation in light-cone gauge, we compute the exact planar free energy of the theory at finite temperature on ?2 as a function of the ??t?Hooft coupling ??=N/k. Employing a dimensional reduction regularization scheme, we find that the free energy vanishes at |??|=1; the conformal theory does not exist for |??|>1. We analyze the operator spectrum via the anomalous conservation relation for higher spin currents, and in particular show that the higher spin currents do not develop anomalous dimensions at leading order in 1/N. We present an integral equation whose solution in principle determines all correlators of these currents at leading order in 1/N and present explicit perturbative results for all three-point functions up to two loops. We also discuss a light-cone Hamiltonian formulation of this theory where a W ?? algebra arises. The maximally supersymmetric version of our theory is ABJ model with one gauge group taken to be U(1), demonstrating that a pure higher spin gauge theory arises as a limit of string theory. 相似文献
63.
Chetan K. Modi Parthiv M. Trivedi Sanjeev K. Gupta Prafulla K. Jha 《Journal of inclusion phenomena and macrocyclic chemistry》2012,74(1-4):117-127
A series of zeolite-Y encapsulated hybrid catalysts, [M(STCH)·xH2O]-Y have been prepared by encapsulating Schiff base complexes [where M?=?Mn(II), Fe(II), Co(II), Ni(II); (x?=?3) and Cu(II); (x?=?1); H2STCH?=?salicylaldehyde thiophene-2-carboxylic hydrazone] in zeolite-Y matrix by flexible ligand method. These hybrid materials have been characterized by various physico-chemical techniques such as ICP-OES, elemental analyses, (FT-IR and electronic) spectral studies, BET, scanning electron micrographs, thermal analysis and X-ray powder diffraction patterns. X-ray powder diffraction analysis reveals that the structural integrity of the mother zeolite in the hybrid material remained intact upon immobilization of the complex. Density functional theory is employed to calculate the relaxed structure, bond angle, bond distance, dihedral angle, difference of highest occupied molecular orbital and lowest unoccupied molecular orbital energies gap and electronic density of states of ligand and their neat transition metal complexes. The hybrid materials are active catalysts for the hydroxylation of phenol using hydrogen peroxide (30% H2O2) as an oxidant in order to selectively synthesize catechol or hydroquinone, amongst them [Cu(STCH)·H2O]-Y shown the highest % of selectivity towards catechol (81.3%). 相似文献
64.
Arun A. YadavPrajakta S. Sarang Manishankar SauSrinath Thirumalairajan Girish K. Trivedi Manikrao M. Salunkhe 《Tetrahedron letters》2012,53(28):3599-3602
[5+2] Cycloaddition followed by asymmetric dihydroxylation procedure have been utilized to prepare novel cyclitols. Accordingly, rac-2α-hydroxy-6α-ethoxy-1,5-anhydro cyclohept-3-ene, 10 derived from [5+2] cycloaddition of 3-oxidopyrylium ylide and vinyl ether has been recognized as a seven-membered carbasugar equivalent and elaborated to 1,4,5-tribenzoyloxy-2-ethoxy cycloheptanes through a flexible, regio- and stereoselective strategy involving Sharpless asymmetric dihydroxylation conditions to resolve the compounds obtained. The structures and relative configurations of newly synthesized (+)-2α-acetoxy-6α-ethoxy-3β,4β-dihydroxy-1,5-anhydro cycloheptane ((+)-12)); (−)-1β,4β,5β-tribenzoyloxy-6α-ethoxy cycloheptane ((−)-17) and (+)-1α,4α,5α-tribenzoyloxy-6β-ethoxy cycloheptane ((+)-17) are unambiguously established by single crystal X-ray analysis and duly supported by 1H and 13C NMR spectroscopy data. 相似文献
65.
Chhavi Bhanot Shruti Trivedi Arti Gupta Shubha Pandey Siddharth Pandey 《The Journal of chemical thermodynamics》2012,45(1):137-144
Correlation between the dynamic viscosity (η) and the microviscosity of a hybrid green medium constituted of water and poly(ethylene glycol) (PEG) of average molar mass (200, 400, and 600) g · mol?1, respectively, is explored over the temperatures range (10 to 90) °C across the complete composition regime. The microviscosity is obtained using a fluorescence probe 1,3-bis-(1-pyrenyl)propane (BPP), which is manifested through the ratio of the monomer-to-intramolecular excimer intensities (IM/IE). Aqueous PEG mixtures are observed to behave similar to Newtonian fluids as the temperature dependence of dynamic viscosity follows Arrhenius-type behavior. Surprisingly, a simple and convenient linear dependence of ln η with wt% PEG of the mixture is established. The BPP IM/IE is observed, in general, to increase with the bulk dynamic viscosity of the mixture having >10 wt% PEG suggesting a good correlation between the bulk dynamic viscosity and BPP-reported microviscosity when the viscosity of the aqueous PEG mixture is relatively high. 相似文献
66.
Experiments were performed to study the diffusion process between matrix and fracture while there is flow in fracture. 2-inch
diameter and 6-inch length Berea sandstone and Indiana limestone samples were cut cylindrically. An artificial fracture spanning
between injection and production ends was created and the sample was coated with heat-shrinkable teflon tube. A miscible solvent
(heptane) was injected from one end of the core saturated with oil at a constant rate. The effects of (a) oil type (mineral
oil and kerosene), (b) injection rates, (c) orientation of the core, (d) matrix wettability, (e) core type (a sandstone and
a limestone), and (f) amount of water in matrix on the oil recovery performance were examined. The process efficiency in terms
of the time required for the recovery as well as the amount of solvent injected was also investigated. It is expected that
the experimental results will be useful in deriving the matrix–fracture transfer function by diffusion that is controlled
by the flow rate, matrix and fluid properties. 相似文献
67.
Amita Singh Archisman Dutta Ashish Kumar Singh Manoj Trivedi Gabriele Kociok-Köhn Mohd. Muddassir Abhinav Kumar 《应用有机金属化学》2020,34(10):e5879
Five new heteroleptic complexes of Cu(I), Ag(I), and Ni(II) having formulae [Cu3(dtc)2(dppf)2]PF6 ( Cu-I ), [Cu3(dtc)2(dppe)2]PF6 ( Cu-II ), [Cu(PPh3)2(dtc)] ( Cu-III ), [Ag3(dtc)2(PPh3)2]NO3 ( Ag-I ), and [Ni(dtc)(dppf)]PF6 ( Ni-I ) (dtc = N-ethanol-N-methylferrocenyl-dithiocarbamate; dppf = 1,1′-bis(diphenylphosphino)ferrocene; dppe = 1,1′-bis(diphenylphosphino)ethane; PPh3 = tripheylphosphine) have been synthesized and characterized using elemental analysis, Fourier-transform infrared, multinuclear nuclear magnetic resonance, UV–Vis spectroscopy, and single-crystal X-ray diffraction. The single-crystal X-ray diffraction studies indicate that Ag-I forms a rare trinuclear cluster in which the geometry around the two silver centers Ag1 and Ag3 is distorted tetrahedral, whereas the third silver center Ag2 shows a distorted trigonal planar geometry. The Ni-I complex has a distorted square-planar geometry around the Ni center. In addition, a side product [Ag2{S2(dppf)2}] ( Ag-II ) was obtained during an attempt to synthesize [Ag(dppf)(dtc)], where the two Ag centers are bridged by two sulfido centers and coordinated with two phosphorus centers of the dppf ligand to give rise to a distorted tetrahedral geometry. The solid-state structures of Ag-I , Ni-I , and Ag-II are stabilized by a variety of weak interactions. The nature of these interactions has been addressed with the help of Hirshfeld surface analyses. In addition, the weak argentophilic interaction in Ag-I and Ag-II have been studied using quantum theory of atoms in molecules and natural bond orbital calculations. The electrochemical properties of the complexes have been investigated using cyclic voltammetry, where Cu-I and Cu-II exhibited two quasi-reversible waves, whereas Cu-III , Ag-I , Ag-II , and Ni-I exhibited only one quasi-reversible peak. 相似文献
68.
Meenakshi Rajendiran Harsh M Trivedi Dandan Chen Praveen Gajendrareddy Lin Chen 《Molecules (Basel, Switzerland)》2021,26(7)
Periodontal diseases like gingivitis and periodontitis are primarily caused by dental plaque. Several antiplaque and anti-microbial agents have been successfully incorporated into toothpastes and mouthwashes to control plaque biofilms and to prevent and treat gingivitis and periodontitis. The aim of this article was to review recent developments in the antiplaque, anti-gingivitis, and anti-periodontitis properties of some common compounds in toothpastes and mouthwashes by evaluating basic and clinical studies, especially the ones published in the past five years. The common active ingredients in toothpastes and mouthwashes included in this review are chlorhexidine, cetylpyridinium chloride, sodium fluoride, stannous fluoride, stannous chloride, zinc oxide, zinc chloride, and two herbs—licorice and curcumin. We believe this comprehensive review will provide useful up-to-date information for dental care professionals and the general public regarding the major oral care products on the market that are in daily use. 相似文献
69.
We report a new formalism to obtain solutions of Einstein-Maxwell’s equations for static spheres assuming the matter content
to be a charged perfect fluid of null-conductivity. Defining three new variablesu=4πεr
2,ν=4πpr
2
2 andw=(4π/3)(ρ+ε)r
2 whereε, ρ andε denote respectively energy densities of the electric, matter and free gravitational fields whereasp is the fluid pressure, Einstein’s field equations are rewritten in an elegant form. The solutions given by Bonnor [1], Nduka
[2], Cooperstock and De la Cruz [3], Mehra [4], Tikekar [5,6], Xingxiang [7], Patino and Rago [8] are all shown to possess
simple relations betweenu, v, andw whereas Pant and Sah’s [9] solution for which all the three functions,u, v, andw are constants is a trivial case of the present formalism, We have presented six new solutions with ε = 2ρ. For the first
three solutionsw andu are constants withv as a variable whereas the remaining three solutions satisfy the equation of state for isothermal gas;v =kw =-ku where (i)k is an arbitrary constant but not equal to 1 or 1/3 (ii)k = 1 and (iii)k = 1/3. We also obtained a generalization of Cooperstock and De la Cruz’s [3] solution which is regular for 2ρ > ε but singular
for 2ρ ≤ ε. 相似文献
70.