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61.
Guillermo A. Ludueña Martin Wegner Lars Bjålie Daniel Sebastiani Priv.‐Doz. Dr. 《Chemphyschem》2010,11(11):2353-2360
Amides and imides of alkali metals are a very promising class of materials for use as a hydrogen‐storage system, as they are able to store and release hydrogen via a chemical route at controllable temperatures and pressures. We critically revise the present picture of the atomic structure of the lightest member (LiNH2/Li2NH) by using a combined computational and experimental approach. Specifically, ab initio path integral molecular dynamics simulations and solid‐state 1H NMR techniques are combined. The results show that the presently assumed local structure might be inconsistent or at least incomplete and needs considerable revision. In particular, the Li atoms turn out to be more mobile and more disordered than suggested by structural data obtained from X‐ray scattering. Also, the configuration of the hydrogen atoms, which is accessible via the NMR experiment and the corresponding first‐principles calculations, is different from the previously assumed data. The computed and experimentally observed 1H NMR parameters are in very good mutual agreement and illustrate the unusual chemical environment of the hydrogen atoms in this system. Incorporating our results on the new lithium data, we show that the effect of nuclear quantum delocalization for the hydrogen atoms is considerably reduced compared to the perfect crystal structure. 相似文献
62.
Antoni T Kuhn AG Briant T Cohadon PF Heidmann A Braive R Beveratos A Abram I Le Gratiet L Sagnes I Robert-Philip I 《Optics letters》2011,36(17):3434-3436
We have designed photonic crystal suspended membranes with optimized optical and mechanical properties for cavity optomechanics. Such resonators sustain vibration modes in the megahertz range with quality factors of a few thousand. Thanks to a two-dimensional square lattice of holes, their reflectivity at normal incidence at 1064?nm reaches values as high as 95%. These two features, combined with the very low mass of the membrane, open the way to the use of such periodic structures as deformable end mirrors in Fabry-Perot cavities for the investigation of cavity optomechanical effects. 相似文献
63.
Sven-Ake Wegner 《Annali dell'Universita di Ferrara》2014,60(2):447-463
The classical theory of Sobolev towers allows for the construction of an infinite ascending chain of extrapolation spaces and an infinite descending chain of interpolation spaces associated with a given \(C_0\) -semigroup on a Banach space. In this note we first generalize the latter to the case of a strongly continuous and exponentially equicontinuous semigroup on a complete locally convex space. As a new concept—even for \(C_0\) -semigroups on Banach spaces—we then define a universal extrapolation space as the completion of the inductive limit of the ascending chain. Under mild assumptions we show that the semigroup extends to this space and that it is generated by an automorphism of the latter. Dually, we define a universal interpolation space as the projective limit of the descending chain. We show that the restriction of the initial semigroup to this space is again a semigroup and always has an automorphism as generator. 相似文献
64.
Tristan J. Keller Christopher Sterzenbach Joshua Bahr Taria L. Schneiders Markus Bursch Julia Kohn Theresa Eder John M. Lupton Stefan Grimme Sigurd Hger Stefan-S. Jester 《Chemical science》2021,12(27):9352
Molecular spoked wheels with D3h and Cs symmetry are synthesized by Vollhardt trimerization of C2v-symmetric dumbbell structures with central acetylene units and subsequent intramolecular ring closure. Scanning tunneling microscopy of the D3h-symmetric species at the solid/liquid interface on graphite reveals triporous chiral honeycomb nanopatterns in which the alkoxy side chains dominate the packing over the carboxylic acid groups, which remain unpaired. In contrast, Cs-symmetric isomers partially allow for pairing of the carboxylic acids, which therefore act as a probe for the reduced alkoxy chain nanopattern stabilization. This observation also reflects the adsorbate substrate symmetry mismatch, which leads to an increase of nanopattern complexity and unexpected templating of alkoxy side chains along the graphite armchair directions. State-of-the-art GFN-FF calculations confirm the overall structure of this packing and attribute the unusual side-chain orientation to a steric constraint in a confined environment. These calculations go far beyond conventional simple space-filling models and are therefore particularly suitable for this special case of molecular packing.Scanning tunneling microscopy investigations of phenylene-based molecular spoked wheels with D3h and Cs symmetries on graphite show the competitive or complementary effects of carboxylic acid groups and alkoxy chains on the nanopattern formation. 相似文献
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N-Carbamoylimidazoles dissociate in solution to yield imidazole and an isocyanate that may be reacted with another aryl amine to form an unsymmetrical biaryl urea. This paper investigates the reaction kinetics and the influence of electron withdrawing/donating substituents on the reaction of N-carbamoylimidazoles with aniline. The overall reaction mechanism involves two zwitterionic intermediates, formed during dissociation and upon reaction of the liberated isocyanate with aniline. The rate limiting step for the reaction is a base catalysed proton transfer from the second zwitterionic intermediate. Although electron withdrawing substituents on the aryl group hinder dissociation, they significantly increase reaction rates compared to compounds bearing electron donating substituents. The imidazole liberated upon dissociation catalyses the rate determining step so that reactions of dissociated N-carbamoylimidazoles proceed more rapidly than those involving only isocyanates. In addition, the imidazole eliminates the need for anhydrous reaction conditions. The N-carbamoylimidazole methodology was demonstrated by preparing sorafenib, a biaryl urea kinase inhibitor, in good yield and excellent purity. 相似文献
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In this paper, the problem of variable selection in classification is considered. On the basis of recent developments in model selection theory, we provide a criterion based on penalized empirical risk, where the penalization explicitly takes into account the number of variables of the considered models. Moreover, we give an oracle-type inequality that non-asymptotically guarantees the performance of the resulting classification rule. We discuss the optimality of the proposed criterion and present an application of the main result to backward and forward selection procedures. 相似文献
70.
Hydrogen Storage Materials: Room‐Temperature Wet‐Chemistry Approach toward Mixed‐Metal Borohydrides
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Dr. Tomasz Jaroń Piotr A. Orłowski Wojciech Wegner Dr. Karol J. Fijałkowski Dr. Piotr J. Leszczyński Prof. Wojciech Grochala 《Angewandte Chemie (International ed. in English)》2015,54(4):1236-1239
The poor kinetics of hydrogen evolution and the irreversibility of the hydrogen discharge hamper the use of transition metal borohydrides as hydrogen storage materials, and the drawbacks of current synthetic methods obstruct the exploration of these systems. A wet‐chemistry approach, which is based on solvent‐mediated metathesis reactions of precursors containing bulky organic cations and weakly coordinating anions, leads to mixed‐metal borohydrides that contain only a small amount of “dead mass”. The applicability of this method is exemplified by Li[Zn2(BH4)5] and M[Zn(BH4)3] salts (M=Na, K), and its extension to other systems is discussed. 相似文献