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21.
Badro J Fiquet G Struzhkin VV Somayazulu M Mao HK Shen G Le Bihan T 《Physical review letters》2002,89(20):205504
We present a new method to separate the crystallographic and electronic phase transitions in hematite using x-ray emission spectroscopy and x-ray diffraction. Our observations, based on the behavior of a metastable high-pressure phase in the stability domain of the low-pressure phase, show that the electronic transition is preempted by the crystallographic transition. The former occurs only afterwards in the high-pressure phase, possibly as a result of a Mott transition. The idea that the electronic transition drives the transition in hematite is therefore invalidated. Such methods should help elucidate the mechanics and the driving forces behind a number of first-order high-pressure phase transitions. 相似文献
22.
23.
O. Volkova E. Goodilin A. Vasiliev D. Khomskii N. Tristan P. Kerschl Yu. Skourski K. -H. Mueller B. Buechner 《JETP Letters》2005,82(10):642-645
The ferrimagnetic compounds Ca(CuxMn3?x)Mn4O12 of the double distorted perovskites AC3B4O12 family exhibit a rapid increase of the ferromagnetic component in magnetization at partial substitution of square coordinated (Mn3+)C for (Cu2+)C. In the transport properties, this is seen as a change of the semiconducting type of resistivity for the metallic one. The evolution of magnetic properties of Ca(CuxMn3?x)Mn4O12 is driven by strong antiferromagnetic exchange interaction of (Cu2+)C with (Mn3+/Mn4+)B coordinated octahedra. The competing interactions of (Mn3+)C with (Mn3+/Mn4+)B lead to the formation of noncollinear magnetic structures that can be aligned by magnetic fields. 相似文献
24.
Tristan?RiviéreEmail author 《Calculus of Variations and Partial Differential Equations》2004,21(3):273-285
Given an almost complex structure J in a cylinder of
(p > 1) together with a compatible symplectic form
and given an arbitrary J-holomorphic curve
without boundary in that cylinder, we construct an holomorphic perturbation of
, for the canonical complex structure J
0 of
, such that the distance between these two curves in W
1,2 and
norms, in a sub-cylinder, are controled by quantities depending on J,
and by the area of
only. These estimates depend neither on the topology nor on the conformal class of
. They are key tools in the recent proof of the regularity of 1-1 integral currents in [RT].Received: 2 October 2003, Accepted: 18 November 2003, Published online: 25 February 2004 相似文献
25.
The intensive reduced efficiency eta(r) is derived for thermoelectric power generation (in one dimension) from intensive fields and currents, giving eta(r)=(E x J) divided by (- inverted Delta)T x J(S). The overall efficiency is derivable from a thermodynamic state function, Phi=1 divided by u + alphaT, where we introduce u=J divided by kappa (inverted Delta)T as the relative current density. The method simplifies the computation and clarifies the physics behind thermoelectric devices by revealing a new materials property s=(sqrt[1+zT]-1) divided by (alphaT), which we call the compatibility factor. Materials with dissimilar compatibility factors cannot be combined by segmentation into an efficient thermoelectric generator because of constraints imposed on u. Thus, control of the compatibility factor s is, in addition to z, essential for efficient operation of a thermoelectric device, and thus will facilitate rational materials selection, device design, and the engineering of functionally graded materials. 相似文献
26.
27.
E. A. Popova N. Tristan A. N. Vasiliev V. L. Temerov L. N. Bezmaternykh N. Leps B. Büchner R. Klingeler 《The European Physical Journal B - Condensed Matter and Complex Systems》2008,62(2):123-128
We present thermodynamic and magnetic studies of single crystalline DyFe3(BO3)4. The data indicate an easy axis antiferromagnetic order below TN~ 38 K which we attribute to the Fe subsystem. The Dy subsystem remains paramagnetic down to the lowest investigated temperatures
of 2 K, but it is polarized by the Fe spins due to a f-d interaction. External magnetic field leads to a spin-flop transition
in the iron subsystem as well as to superposed magnetization in the Dy subsystem. The repopulation of two low-lying Kramers
doublets in Dy3+ ions results in well defined Schottky anomalies in specific heat and magnetization. 相似文献
28.
We consider constructions of manifolds withSU(3) holonomy as embedded in products of complex projective spaces by imposing certain homogeneous holomorphic constraints. We prove that every such construction leads to one deformation class of manifolds withSU(3) holonomy. For a subset of these manifolds we prove simple connectedness, address the problem of calculating the second Betti number and explicitly calculate it for a class of constructions. This establishes a very wide class of manifolds withSU(3) holonomy, that can give rise to yet many more constructions via dividing out the action of suitably chosen discrete groups. Some of the examples studied may yield phenomenologically acceptable models. 相似文献
29.
Tristan A. Reekie Jean-Paul Gisselbrecht Corinne Boudon Nils Trapp François Diederich 《Tetrahedron letters》2017,58(25):2414-2416
Two push-pull chromophores that have shown utility in the field of molecular electronics and non-linear optics are DDMEBT (1, 2-(4-dimethylamino)phenyl)-3-((4-(dimethylamino)phenyl)ethynyl)buta-1,3-diene-1,1,4,4-tetracarbonitrile) and TDMEE (2, 4-(4-dimethylamino)phenyl)but-1-en-3-yne-1,1,2-tricarbonitrile). Unfortunately, the methods reported for their synthesis give variable yields, use toxic solvents, and only provide small amounts of material. We report improved synthetic protocols, providing access to larger quantities of material. By investigating multiple metal-acetylides of 4-ethynyl-N,N-dimethylaniline and their subsequent addition to TCNE, we obtained various products depending on the identity of the metal ion. This led to the simple synthesis of push-pull chromophoric compounds. 相似文献
30.
Antoni T Kuhn AG Briant T Cohadon PF Heidmann A Braive R Beveratos A Abram I Le Gratiet L Sagnes I Robert-Philip I 《Optics letters》2011,36(17):3434-3436
We have designed photonic crystal suspended membranes with optimized optical and mechanical properties for cavity optomechanics. Such resonators sustain vibration modes in the megahertz range with quality factors of a few thousand. Thanks to a two-dimensional square lattice of holes, their reflectivity at normal incidence at 1064?nm reaches values as high as 95%. These two features, combined with the very low mass of the membrane, open the way to the use of such periodic structures as deformable end mirrors in Fabry-Perot cavities for the investigation of cavity optomechanical effects. 相似文献