Hydrothermal Synthesis and Crystal Structure of a Novel Polyoxometalate K(C_4N_2H_(12))_4(C_4N_2H_(11))_(2-)[Mo_8~ⅤMo_4~ⅥCdP_8O_(54)(OH)_8]F·6H_2O

The title compound 1 has been synthesized by the reaction of H_2MoO_4, CdCl_2, H_3PO_4, KF, piperazine hexahydrate and water in aqueous solution under mild hydrothermal conditions. Single-crystal X-ray analysis reveals that the title compound crystallizes in the triclinic system, space group P(-1) with a = 14.049(3), b = 15.972(3), c = 20.043(4) (A), α = 85.82(3), β = 81.28(3),γ = 67.15(3)°, V= 4095.9(14) (A)~3, M_r = 3204.62, Z=2,D_c = 2.598 g/cm~3,μ = 2.360 mm~(-1), F(000) = 3124, the final R = 0.0314, wR = 0.0826 and S = 0.989 for 18592 observed reflections with I > 2σ(I). The crystal packing is stabilized by N-H…O and O-H…O intra- and intermolecular hydrogen bonds to form an infinite 3D network.     

A Simple and Rapid Label-free Fluorimetric “Turn Off-on” Sensor for Cadmium Detection Using Glutathione-capped CdS Quantum Dots

A convenient label-free fluorescence(FL) nanoprobe for rapid detection of cadmium(Cd) was established using glutathione-capped CdS quantum dots(QDs) and 1,10-phenanthroline(phen). The prepared CdS QDs exhibited a strong FL emission at 536 nm, which could be quenched by phen due to the photoinduced hole transfer(PHT) mechanism. The existence of Cd effectively recovered the FL intensity of CdS QDs, which was due to the easy detachment of phen from the surface of QDs to form[Cd(phen)₂(H₂O)₂]²⁺ in solution. Cd concentrations were linearly correlated with the FL intensity in the range of 0.0625-1.25 μmol/L under the optimized conditions and the detection limit was 0.01 μmol/L. Finally, the Cd concentration was accurately quantified in real water sample using the proposed sensor.     

基频估计算法研究平均骨小梁间距

超声背散射信号能提供松质骨微结构信息从而能有效的诊断骨质疏松,而平均骨小梁间距(MTBS)是表征松质骨微结构的重要参数之一.本文提出了一种基频估计的MTBS估计算法,对仿真信号和离体牛胫骨松质骨中的超声背散射信号分别进行分析处理,并和现有的两种算法(简易反向滤波跟踪(SIFT)算法和AR倒谱法)进行比较.实验结果表明基频估计算法对噪卢和随机散射回波有更好的鲁棒性,在信噪比较低和随机散射回波幅度较大时估计值更加精确,且有很好的方差性能.充分说明了本文算法是一种有效的MTBS估计算法.     

纳米尺度CeO2在多相催化反应中的形貌效应

CeO2的催化性能不仅与粒子大小有关,而且与其形貌密切相关. 本文分析了CeO2的纳米结构和氧化还原特性,综述了CeO2在催化反应中的形貌效应,着重介绍了CeO2的结构和形貌对CO氧化、水气变换和乙醇水蒸气重整制氢以及二元醇脱水反应活性的影响.     

《硅光电池特性》实验教学探索和实践

为了更好地培养全校本科生的创新思维和动手实践能力,探索了适合九零后学生的教学方法。针对实验中存在的一些问题,引导学生积极思考,找到一些快速完成实验并且大大降低仪器损耗率的实验技巧,实现学生、教师、学校三方共赢的目标。     

Co3O4纳米立方体的可控合成及其CO氧化反应性能

在乙醇和三乙胺的混合溶液中,采用溶剂热法制备了尺寸为10 nm的Co₃O₄立方体. 考察了钴盐前驱体和溶解氧对Co₃O₄纳米立方体结构的影响规律,通过对合成过程中不同阶段产物的结构分析和表征,提出了Co₃O₄纳米立方体的形成机制是溶解再结晶的过程. 将所制备的Co₃O₄纳米立方体在200 ℃焙烧处理后,尺寸和形貌均可保持稳定,但400 ℃焙烧后,变为球形纳米粒子. 这种主要暴露{100}晶面的Co₃O₄纳米立方体催化CO氧化反应的活性低于纳米粒子({111}晶面),验证了四氧化三钴纳米材料在CO氧化反应中的晶面效应.     

Synthesis of the p-keto acids from benzimidazolium iodides and ethyl malonate

The reaction of benzhnidazole methiodide with ethyl malonate in the existence of base was studied,and a new convenient synthetic method of the β-keto acid was provided.     

超声背散射法评价松质骨状况的研究

超声背散射法评价松质骨状况及诊断骨质疏松症是近年来医学超声领域内的研究热点之一,现已取得了显著的进展。本文将介绍近年来超声背散射法及其参量评价松质骨状况的研究进展,并分析超声背散射相关参量频谱质心偏移量（SCS）和平均骨小梁间距（TbSp）与骨矿密度（BMD）的相关性。研究结果表明,超声背散射参量与BMD有较高的相关性。最后提出了将来研究中需要努力的方向。