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21.
Tripathi A Maswadeh WM Snyder AP 《Rapid communications in mass spectrometry : RCM》2001,15(18):1672-1680
Experimental procedures were investigated to improve the efflux of biomolecule pyrolyzates from quartz tube pyrolysis under atmospheric pressure ionization mass spectrometry conditions. Heating regimes, airflows, and ion focusing parameters were optimized to increase the informative mass spectral signals generated from the pyrolysis of Gram-positive bacterial spores and vegetative cells. Dipicolinic acid (DPA) is found in 5-15% by weight in Gram-positive Bacillus spores, and the parameter optimization procedures provided an intense mass spectral signature of the m/z 168 protonated DPA molecule with a minimization of pyrolytic and ionization fragments. Moreover, mass spectral information from the optimization protocols yielded peaks and mass patterns characteristic of DNA and RNA nitrogen bases, protein diketopiperazines, and amino sugars. 相似文献
22.
A simple method has been developed for the extraction, separation, and determination of synthetic colors in ice cream samples. The process involves the breakdown of emulsion by neutral detergents (Triton X-100 and Tween 20) followed by extraction with petroleum ether for removal of fat. The aqueous colored solution obtained is treated with 5% acetic acid, and the uptake of color is carried out by a wool-dyeing technique. The color is eluted from the wool with 5% ammonia solution, the solution is evaporated to dryness, and the residue is dissolved in 60% ethanol for paper chromatography using trisodium citrate-ammonia-water (2 + 5 + 95, w/v/v) as the mobile phase. The colored spots from the paper chromatogram are cut and eluted with 60% ethanol, and the absorbance is measured at the respective lambda maximum corresponding to the Rf value of the appropriate standard. The recoveries of 6 colors, including sunset yellow FCF (SSYFCF), tartrazine, carmoisine, ponceau 4R, brilliant blue FCF (BBFCF), and fast green FCF from spiked samples with either detergent were found to be >90%. However, recoveries of erythrosine were 21 and 65% with Triton X-100 and Tween 20, respectively. Indigo carmine could not be recovered at all because of its fugitive property in 5% ammonia solution, which is used to strip the color from the wool. The sensitivity of the method with the use of Tween 20 is 1 ppm (1 microg/g) for the colors in spiked ice cream samples. With this method, we analyzed samples of 20 branded colored ice cream. The results showed the presence of tartrazine (8.4-43.3 ppm), SSYFCF (23.5-117.6 ppm), carmoisine (traces-53.2 ppm), erythrosine (3.5 ppm), and BBFCF (4.1 ppm) in the ice cream samples. Apart from 2 samples of tuttifruity, all of the ice cream samples showed the presence of permitted synthetic colors below the permissible level of 100 ppm established by the Prevention of Food Adulteration Act of India. 相似文献
23.
Miss S. Baluja R. N. Singh R. Tripathi B. M. Shukla 《Journal of Radioanalytical and Nuclear Chemistry》1985,94(4):233-239
Tracer diffusion of131I– ions is studied at different temperatures /20°C–50°C/ in 2.5% agar gel containing sodium and potassium sulphate solutions over a wide range of concentrations. The results are in qualitative agreement with the theoretical values in the concentration range 10–6–10–1M. Agar gel shows an obstruction effect to diffusional flow. The activation energy for tracer diffusion was found to be of the order of 16.3 kJ mol–1. 相似文献
24.
Tripathi RP Rastogi SK Kundu B Saxena JK Reddy VJ Srivastava S Chandra S Bhaduri AP 《Combinatorial chemistry & high throughput screening》2001,4(3):237-244
A library of 24 glycoconjugates related to glycosylated beta-amino acid derivative (I) was been prepared and screened against DNA topoisomerase-II of the filarial parasite S. cervi. Among these, compound 6 was found to be a potent inhibitor of DNA topoisomerase-II with 95% inhibition at 1.09 microM. Furthermore, compound 6 was at least three times more potent than the lead compound, glycosylated beta-amino acid derivative I. 相似文献
25.
The 25% niobium substituted crystalline titanosilicate with the composition Na1.5Nb0.5Ti1.5O3SiO4·2H2O (Nb-TS) was synthesized under hydrothermal conditions. Its selectivity for radioactive 137Cs and 89Sr was compared with the TS, Na2Ti2O3SiO4·2H2O, having sitinakite topology. The Nb-TS shows significantly higher uptake value for 137Cs but lower for 89Sr than the TS. To investigate the origin of selectivity, the ion exchanged Cs+ and Sr2+ forms with the composition, CsxNaHyNb0.5Ti1.5O3SiO4·zH2O (x=0.1, 0.2 and 0.3, x+y=0.5 and z=1-2) and Sr0.2Na0.6H0.5Nb0.5Ti1.5O3SiO4·H2O, respectively, were structurally characterized from the X-ray powder diffraction data using the Rietveld refinement technique. Simultaneously the kinetics of 137Cs and 89Sr uptake was investigated for the NbV free and doped samples. While the Cs+ and Sr2+ exchanged form of Nb-TS and the Cs+ exchanged form of TS retain the symmetry of the parent compound, the Sr2+ exchanged form of TS undergoes a symmetry change. The differences in the uptake of Cs+ and Sr2+ result from the different coordination environments of cesium and strontium in the eight-ring channel, that result from various hydration sites in the tunnel. The origin of selectivity appears to arise from the higher coordination number of cesium or strontium. Other effects due to NbV substitution are reflected in the increase of both, the a- and c-dimensions and thus the unit cell volume, and the population of water vs. Na+ in the channel to charge-balance the Nb5+↔Ti4+ substitution. 相似文献
26.
β-Keto esters and acetyl acetone on condensation with glycosylated amino esters in the presence of IR-120 resin resulted in high yields of glycosyl enamino esters or ketones. The latter on cyclisation with NaH in toluene at reflux gave 6-glycosyl-5,6-dihydro-1H-pyridin-4-ones in fair to good yields. 相似文献
27.
Swadesh Kumar Gupta Dharmendra Pratap Singh Pankaj Kumar Tripathi Mahesh Varia Laxmi K. Sagar 《Liquid crystals》2013,40(4):528-533
Cadmium selenide quantum dot (CdSe QD) has been used as a dopant in ferroelectric liquid crystal (FLC) 2-methylbutyl 4-(4-decyloxybenzylideneamino) cinnamate (DOBAMBC). Effect of CdSe QD in DOBAMBC on its different electro-optical (E-O) properties has been studied in the SmC* phase. The optical micrographs recorded for the pure and composite material are showing good dispersion of QDs in the FLC matrix. Micrographs of unaligned sample cell revealed that CdSe QDs induce homeotropic alignment of FLC molecules. An appreciable change in the value of E-O parameters like tilt angle, spontaneous polarisation and response time with shifting of SmA–SmC* phase transition temperature has been observed for CdSe QD–DOBAMBC composite. The observed properties of composite system have been discussed on the basis of surface properties of QDs in FLC system. 相似文献
28.
Afshan Siddiqui Kajal Singh Kanchan Lata Singh Shailendra Kumar Gupta Mohd Safi Ahmad U. N. Tripathi 《应用有机金属化学》2012,26(5):203-211
Mixed ligand complexes of Iron(III) with aspartic acid and 3(2′‐hydroxy phenyl)‐5‐(4′‐substituted phenyl) pyrazolines of type [Fe(C4O4NH6)2(C15H12N2OX)] and [Fe(C4O4NH6)(C15H12N2OX)2], where (C4O4NH6) = aspartate, (C15H12N2OX) = deprotonated 3(2′‐hydroxyphenyl)‐5‐(4′‐substituted phenyl) pyrazolines (X = H, CH3, OCH3, Cl), have been synthesized. These newly synthesized derivatives have been physicochemically characterized by elemental analysis (C, H, N, Cl and Fe), magnetic moment data, thermogravimetric analysis, molar conductance, cyclic voltammetry, spectral analysis (UV–visible, IR, far IR and fast atom bombardment mass spectrometry). Scanning electron microscopy, transmission electron microscopy and X‐ray powder diffraction studies have been carried out for powdered samples, which show nanometric particles of these derivatives. Antibacterial and antifungal potential of free pyrazoline and some iron(III) complexes have been evaluated. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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