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21.
Duong Quoc Hoan Le Thi Hoa Trinh Thi Huan Nguyen Huu Dinh 《Journal of heterocyclic chemistry》2020,57(4):1720-1728
An efficient and simple method has been reported for the synthesis of 4-(1-Chloro-1-nitroethyl)-6,7-dimethoxy-2-methylquinazoline ( 2 ) as a key compound for further transformation to other novel 6,7-dimethoxy-2-methyl-4-substituted quinazolines. The structure of the synthesized compounds was characterized by spectroscopic methods. The pathway of some unprecedented reactions was proposed. (E)-1-(6,7-dimethoxy-2-methylquinazolin-4-yl)-3-(4-nitrophenyl)prop-2-en-1-one (11) exhibits high in vitro cytotoxicity on three cell lines, Hepatocellular carcinoma (Hep-G2), Human lung carcinoma (LU-1), and Human breast carcinoma (MCF-7) with IC50 of 2.1, 11.6 and 2.2 μM, respectively. 相似文献
22.
Quach Thi Thanh Van Le Thi Vien Tran Thi Hong Hanh Phan Thi Thanh Huong Nguyen The Cuong Nguyen Phuong Thao 《Natural product research》2020,34(9):1276-1281
AbstractUsing various chromatographic separations, three new acylated flavonoid glycosides, namely barringosides G–I (1–3), were isolated from the water-soluble extract of Barringtonia racemosa branches and leaves. The structure elucidation was performed by extensive analysis of the 1D and 2D NMR and HR-QTOF-MS data. Of the isolated compounds, barringoside I (3) showed moderate inhibitory effects on LPS-induced NO production in RAW264.7 cells with an IC50 of 52.48?±?1.04?µM. 相似文献
23.
Le Hoang Vien Le Thi Hanh Tran Thi Hong Thanh Nguyen Van Nam Nguyen Hoai 《Natural product research》2020,34(8):1061-1067
AbstractFrom the MeOH extract of the Vietnamese sea cucumber Holothuria edulis, eight triterpene glycosides (1–8), including one new compound namely holothurin A5 (1), were isolated by using various chromatographic separations. Their structures were established by spectroscopic experiments including 1D, 2D NMR and HR-ESI-MS. Holothurin A5 (1) has a hydroperoxy group at C-25. To the best of our knowledge, this is the first report of this group in triterpene saponins obtained from sea cucumbers to date. In addition, the in vitro cytotoxicity against five human cancer cell lines (HepG2, KB, LNCaP, MCF7 and SK-Mel2) of all isolated compounds was also evaluated using SRB assays. 相似文献
24.
Galteland Olav Rauter Michael T. Bratvold Mina S. Trinh Thuat T. Bedeaux Dick Kjelstrup Signe 《Transport in Porous Media》2022,145(1):153-173
Transport in Porous Media - Darcy’s law for porous media transport is given a new local thermodynamic basis in terms of the grand potential of confined fluids. The local effective pressure... 相似文献
25.
Regular conjugated terpolymers comprising two different acceptors and bithiophene donor in repeating group: Effect of strong and weak acceptors on semiconducting properties
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Duc Nghia Nguyen Trinh Tung Ngo Dae Hee Lee Min Ju Cho Dong Hoon Choi 《Journal of polymer science. Part A, Polymer chemistry》2016,54(10):1339-1347
Diketopyrrolopyrrole (DPP)‐based terpolymers—P(DPP‐TPyT) and P(DPP‐T3MTT)—bearing bithiophene donating groups and weak accepting units such as pyridine (Py) or methyl thiophene‐3‐carboxylate (3MT), in the polymer backbone, were successfully synthesized. Although the two polymers had similar physical and electrochemical properties, grazing incidence X‐ray diffraction patterns of P(DPP‐TPyT) and P(DPP‐T3MTT) showed mixed and edge‐on orientations, respectively, in thermally annealed films. Accordingly, the P(DPP‐T3MTT) showed twice the hole mobility of P(DPP‐TPyT) in a thin‐film transistor, and a blended film of P(DPP‐T3MTT) and [6,6]‐phenyl‐C71‐butyric acid methyl ester (PC71BM) showed better power conversion efficiency in a polymer solar cell. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1339‐1347 相似文献
26.
Bulky trialkylsilyl-protected alkynes such as triethylsilyl (TES), tert-butyldimethylsilyl (TBS), and triisopropylsilyl (TIPS) acetylenes underwent the Cadiot-Chodkiewicz cross-coupling reaction with different bromoalkynes to form a variety of synthetically useful unsymmetrical diynes in good yields. The diyne alcohol 10 was transformed regio- and stereoselectively into enynes by hydrotelluration, carbometalation, and reduction reactions. 相似文献
27.
An investigation of the internal flow field for a drop at the antinode of a standing wave has been carried out. The main difference from the solid sphere case is the inclusion of the shear stress and velocity continuity conditions at the liquid-gas interface. To the leading order of calculation, the internal flow field was found to be quite weak. Also, this order being fully time dependent has a zero mean flow. At the next higher order, steady internal flows are predicted and, as in the case of a solid sphere, there is a recirculating layer consisting of closed streamlines near the surface. In the case of a liquid drop, however, the behavior of this recirculating Stokes layer is quite interesting. It is predicted that the layer ceases to have recirculation when [formula: see text], where [symbol: see text] is the liquid viscosity, mu is the exterior gas-phase viscosity, and M is the dimensionless frequency parameter for the gas phase, defined by M = i omega a2 rho/mu, with a being the drop radius. Thorough experimental confirmation of this interesting new development needs to be conducted. Although it seems to agree with many experiments with levitated drops where no recirculating layer has been clearly observed, a new set of experiments for specifically testing this interesting development need to be carried out. 相似文献
28.
The problem of steady streaming around a rigid isolated sphere in a plane standing acoustic field is considered. Existing results in the literature have been generalized to allow for noncompactness of the sphere, and the influence of fluid compressibility on the streaming behavior has been included. It is found that in the high-frequency limit of interest for which the streaming is strongest, the effective steady slip velocity at the edge of the inner boundary layer region that is responsible for driving the steady streaming in the bulk of the fluid in the outer region, has a complex variation over the surface of the sphere that depends on (i) the sphere position (with respect to the node/antinode of the acoustic field), (ii) the extent of sphere compactness, and (iii) on a well-defined function (representing compressibility effects) of the fluid Prandtl number and its ratio of specific heats. Not surprisingly, the contribution from this function is negligible when the host fluid is a liquid. The steady streaming behavior around the sphere is demonstrated with the help of flow streamlines for various cases in the diffusive limit of weak outer flow for low streaming Reynolds numbers. 相似文献
29.
A two-frequency acoustic apparatus has been developed to study the dynamics of a single gas or vapor bubble in water. An advantage of the apparatus is its capability of trapping a bubble by an ultrasonic standing wave while independently driving it into oscillations by a second lower frequency acoustic wave. For a preliminary application, the apparatus is used to study resonant oscillations. First, near-resonant coupling between the volume and the n = 3 shape oscillation modes of air bubbles at room temperature is studied, where n is the mode number. The stability boundary, amplitude versus frequency, of the volume oscillation forms a wedge centered at the resonant frequency, which qualitatively agrees with a theoretical prediction based on a phase-space analysis. Next, the resonant volume oscillations of vapor bubbles are studied. The resonant radius of vapor bubbles at 80 degrees C driven at 1682 Hz is determined to be 0.7 mm, in agreement with a prediction obtained by numerical simulation. 相似文献
30.
The evolution of axisymmetric equilibrium shapes of a rigidly rotating liquid drop can be extended beyond the 2-lobed shape bifurcation point if the rotating drop is driven in the n = 2 axisymmetric shape oscillation (perturbation), where n is the mode of oscillation. A reason for the extended stability of the perturbed rotating drop is that the inertia of the driven axisymmetric shape oscillation suppresses growth of a natural nonaxisymmetric shape fluctuation which leads to the 2-lobed shape bifurcation. The axisymmetric shape of the drop eventually bifurcates into either a 2- or a 3-lobed shape at a higher bifurcation point which is asserted to be the 3-lobed shape bifurcation point. 相似文献