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91.
[reaction: see text] The cross metathesis reactivities of alpha-methylene-gamma-butyrolactone and an alpha-methylene-delta-lactone have been investigated. alpha-Methylene-gamma-butyrolactone undergoes rapid and efficient olefin isomerization in the presence of second-generation metathesis catalysts. However, cross metathesis can be achieved with the additive 2,6-dichlorobenzoquinone. In contrast, the alpha-methylene-delta-lactone neither isomerizes nor couples under similar conditions. 相似文献
92.
Zafiropoulos NA Ngo HL Foglia TA Samulski ET Lin W 《Chemical communications (Cambridge, England)》2007,(35):3670-3672
Recyclable and reusable heterogeneous diarylammonium catalysts are highly effective in catalyzing the esterification of the free fatty acid (FFA) present in greases to methyl esters to reduce the FFA content from 12-40 wt% to 0.5-1 wt%; the resulting ester-glyceride mixture (pretreated grease) could then be readily converted to methyl esters by base-catalyzed transesterification. 相似文献
93.
Marc Chardin Nguyen Cong Minh Ngo Viet Trung 《Proceedings of the American Mathematical Society》2007,135(6):1597-1606
This paper proves the formulae
for arbitrary monomial complete intersections and , and provides examples showing that these inequalities do not hold for general complete intersections.
for arbitrary monomial complete intersections and , and provides examples showing that these inequalities do not hold for general complete intersections.
94.
The acyl endoperoxide arteannuin H, recently reported as a novel natural product from Artemtsia annua, has been obtained in two steps from the photooxidation of dihydroartemisinic acid, thereby confirming biogenetic speculation regarding its derivation from a secondary allylic hydroperoxide. The little studied 3,2-rearrangement reaction of such allylic hydroperoxides is also discussed. 相似文献
95.
Photooxidation of 4-amorphen-11-ol (1), recently reported as one of the major sesquiterpene natural products from the medicinal plant Fabiana imbricata, results in three allylic hydroperoxides 6, 9 and 10, which are expected from the “ene-type” reaction of molecular oxygen with the tri-substituted double bond in 1. The tertiary allylic hydroperoxide 6 undergoes carbon-carbon bond cleavage and a second autoxidation reaction to yield the more highly oxygenated seco-amorphane 11 under very mild conditions. In acid, this compound may then undergo either a second carbon-carbon bond cleavage reaction to yield nor-sesquiterpenes 2 and 3 (reported as bona fide natural products from F. imbricata, or cyclize to the sesquiterpene peroxofabianane (5), which is a presumed precursor to the natural product fabianane (4). Some mechanistic investigations concerning the two chemical processes: viz:- carbon-carbon bond cleavage and autoxidation which would account for the formation of natural products 2, 3 and 4 from 1 are reported. Tertiary allylic hydroperoxide 32, which lacks the 11-hydroxyl functional group present in 1 undergoes only C-4/C-5 carbon-carbon bond cleavage under more forcing conditions, suggesting a role for this functional group in assisting the autoxidation reactions of 4-amorphen-11-ol. 相似文献
96.
Eka Sunarwidhi Prasedya Nur Ardiana Hasriaton Padmi Bq Tri Khairina Ilhami Ni Wayan Riyani Martyasari Anggit Listyacahyani Sunarwidhi Aluh Nikmatullah Sri Widyastuti Haji Sunarpi Andri Frediansyah 《Molecules (Basel, Switzerland)》2021,26(21)
The red macroalga Gelidium latifolium is widely distributed in the coastal areas of Indonesia. However, current knowledge on its potential biological activities is still limited. In this study, we investigated the potential bioactive compounds in Gelidium latifolium ethanol extract (GLE), and its cytotoxic effects against the murine B16-F10 melanoma cell line. GLE shows high total phenolic content (107.06 ± 17.42 mg GAE/g) and total flavonoid content (151.77 ± 3.45 mg QE/g), which potentially contribute to its potential antioxidant activity (DPPH = 650.42 ± 2.01 µg/mL; ABTS = 557.01 ± 1.94 µg/mL). ESI-HR-TOF-MS analysis revealed large absorption in the [M-H]- of 327.2339 m/z, corresponding to the monoisotopic molecular mass of brassicolene. The presence of this compound potentially contributes to GLE’s cytotoxic activity (IC50 = 84.29 ± 1.93 µg/mL). Furthermore, GLE significantly increased the number of apoptotic cells (66.83 ± 3.06%) compared to controls (18.83 ± 3.76%). Apoptosis was also confirmed by changes in the expression levels of apoptosis-related genes (i.e., p53, Bax, Bak, and Bcl2). Downregulated expression of Bcl2 indicates an intrinsic apoptotic pathway. Current results suggest that components of Gelidium latifolium should be further investigated as possible sources of novel antitumor drugs. 相似文献
97.
A novel tunable microwave photonic notch filter using a phase-modulated dual-wavelength fiber laser is presented. A stable dual-wavelength erbium-doped fiber laser with a linear cavity is formed by a polarization-maintaining uniform fiber Bragg grating (PM-FBG) and a polarization maintaining linearly chirped fiber Bragg grating (PM-LCFBG), both of which were fabricated on a high-birefringence (Hi-Bi) fiber. It is found that a stable room-temperature dual-wavelength operation can be achieved due to the presence of two reflection peaks arising from the orthogonal states of polarization (SOP) of the PM-FBG. Experimental results show stable dual-wavelength lasing operation with a wavelength separation of ∼0.36 nm and a large optical signal-to-noise ratio (OSNR) of over 40 dB under room temperature. The dual-wavelength fiber laser is combined with a phase modulator and a segment of single-mode fiber (SMF) as a dispersive device to form a tunable microwave photonic notch filter. By stretching the PM-FBG to tune the wavelength separation of the dual-wavelength fiber laser, a tunable microwave photonic notch filter with various free spectral ranges (FSRs) and a rejection ratio greater than 35 dB was developed. 相似文献
98.
Stable multiwavelength fiber ring laser with equalized power spectrum based on a semiconductor optical amplifier 总被引:1,自引:0,他引:1
We experimentally demonstrated a new structure of a multiwavelength semiconductor optical amplifier (SOA) ring laser based on a fiber Sagnac loop filter that can generate up to 25 stable output lasing wavelengths at room temperature. By varying the length of a polarization-maintaining (PM) fiber within the Sagnac loop filter, the wavelength spacing between the output lasing wavelengths can be changed to a desired value. By tuning a polarization controller (PC) within the Sagnac loop filter, stable multiwavelength 1550-nm operation with up to 17 lasing lines within 3 dB power level variation and with a wavelength spacing of ∼0.8 nm was achieved. The optical signal-to-noise ratios (OSNRs) of all the lasing wavelengths are greater than 40 dB. 相似文献
99.
Nemanja Trišović Nebojša Banjac Nataša Valentić Gordana Ušćumlić 《Journal of solution chemistry》2009,38(2):199-208
The absorption spectra of nine compounds structurally related to phenytoin (5,5-diphenylhydantoin) were recorded in twelve
solvents over the range of 200 to 400 nm. The effects of solvent dipolarity/polarizability and solvent/solute hydrogen bonding
interactions were analyzed by means of the linear solvation energy relationship (LSER) concept proposed by Kamlet and Taft.
The lipophilic activity of the investigated hydantoins was estimated by calculation of their log 10
P values. The calculated values of log 10
P were correlated with the ratio of the contributions of specific and non-specific solute/solvent interactions. The correlation
equations were combined with the corresponding ED50 values to generate new equations that demonstrate exact relationship between solute/solvent interactions and the structure-activity
parameters. 相似文献
100.
Anna Giusti Dr. Gaëlle Charron Dr. Sandra Mazerat Jean‐Daniel Compain Pierre Mialane Prof. Anne Dolbecq Dr. Eric Rivière Dr. Wolfgang Wernsdorfer Dr. Rosa Ngo Biboum Bineta Keita Dr. Louis Nadjo Prof. Arianna Filoramo Dr. Jean‐Philippe Bourgoin Dr. Talal Mallah Prof. 《Angewandte Chemie (International ed. in English)》2009,48(27):4949-4952
A POM to remember : Hexanuclear FeIII polyoxometalate (POM) single‐molecule magnets (see structure) can be noncovalently assembled on the surface of single‐wall carbon nanotubes. Complementary characterization techniques (see TEM image and magnetic hysteresis loops) demonstrate the integrity and bistability of the individual molecules, which could be used to construct single‐molecule memory devices.