Technique of Broadband Measurements of Frequency Conversion Efficiency for Each Harmonique in Frequency Multipliers up to Terahertz Range

The paper describes technique of quantitative analysis of a millimeter- and submillimeter-wave range multipliers performance in particular the measurement of the frequency conversion efficiency. The output power on each harmonic produced by the multiplier can be measured separately without any changes in the setup even in the case of simultaneous emission of all harmonics including the fundamental in a frequency range up to 1 THz and well above. The measuring technique primarily developed for high resolution microwave spectroscopy is based on absorption of radiation in spectral lines of rarefied sample gas and photo-acoustic method of the absorption detection. Sensitivity independence of the detection method on frequency and well known spectral parameters of the lines provide the technique with broadbandness, high spectral resolution and power measurement reliability. Principal limits of measurable radiation power may vary from nanowatts up to hundreds of watts. The technique permits real time operation convenient, e.g., for multiplier tuning. Practical examples include measurements of harmonic generation efficiency of multipliers of 78-118 GHz fundamental frequency range, and power measurement up to 6-th harmonic of 230 GHz fundamental radiation of phase locked Backward Wave Oscillator (BWO).     

Determination of the dislocation structure in paratellurite single crystals using the piezo-optic effect

It is shown theoretically and experimentally that dislocations in paratellurite single crystals can be revealed using the piezo-optic effect. The mechanical-stress distribution near dislocations is calculated. Dislocations in the samples are observed using the photoelastic method and chemical etching. Data on the spatial distribution of dislocations in Czochralski-grown paratellurite crystals are reported.     

Spirocyclic derivatives of nitronyl nitroxides in the design of heterospin CuII complexes manifesting spin transitions

A method was developed for the synthesis of a nitronyl nitroxide containing cyclopentane substituents in positions 4 and 5 of the imidazoline ring, viz., 2-(3-pyridyl)-4,5-bis(spiropentyl)-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl (L^CP). The reaction of Cu^II hexafluoroacetylacetonate with L^CP affords different products depending on the reaction conditions: mononuclear [Cu(hfac)₂(L^CP)₂], binuclear [Cu(hfac)₂L^CP]₂, tetranuclear {[Cu(hfac)₂]₄(L^CP)₂}, or chain polymer {[Cu(hfac)₂]₃(L^CP)₂} _n . Temperature changes induce structural transformations accompanied by a change in the spin state in exchange clusters in the solid [Cu(hfac)₂L^CP]₂ and {[Cu(hfac)₂]₄(L^CP)₂}.     

Molecular-Thermodynamic Model of Solubilization in Direct Spherical Micelles of Nonionic Surfactants

Colloid Journal - A thermodynamic model has been formulated for the formation work of a molecular aggregate consisting of molecules of a nonionic surfactant and a solubilisate in a...     

Synthesis of 2-[(Pyrrol-2-yl)sulfanyl]acetic Acids by Reaction of Pyrrolo[2,1-c][1,4]oxazinetriones with 2-Sulfanylacetic Acid

Russian Journal of Organic Chemistry - 8-Aroyl-3,4-dihydro-1H-pyrrolo[2,1-c][1,4]oxazine-1,6,7-triones reacted with 2-sulfanylacetic acid to give...     

Reaction of Pyrrolooxazinetriones with Diphenylguanidine. Synthesis of Substituted Spiro[imidazole-4,2′-pyrroles]

Russian Journal of Organic Chemistry - 8-Aroyl-3,4-dihydropyrrolo[2,1-c][1,4]oxazine-1,6,7(1H)-triones reacted with 1,3-diphenylguani­dine to give...     

STRUCTURAL FEATURES OF THE 12-NUCLEAR Cu(hfac)2 COMPLEX WITH SPIN-LABELED PYRAZOLE

Journal of Structural Chemistry - A 12-nuclear heterospin complex of Cu(II) hexafluoroacetylacetonate with dialkylpyrazolyl-substituted nitroxide [Cu2(hfac)4LBu/Et]6 is found, which has a...     

S<Stack><Subscript>N</Subscript><Superscript>H</Superscript></Stack> Reaction of lithiated nitronyl nitroxide with quinoline <Emphasis Type="Italic">N</Emphasis>-oxide

The S_N^H reaction of lithiated 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide with quinoline N-oxide affords 4,4,5,5-tetramethyl-2-(1-oxidoquinolin-2-yl)-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide.