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301.
302.
Fe(II)--Fe(III) hydroxy-chloride, -sulphate and -carbonate were prepared by oxidation of a ferrous hydroxide precipitate in anion-containing aqueous solutions. The compounds are characterized by monitoring the redox potential Eh and the pH of stochiometric suspension vs time with the appropriate concentration ratios. X-ray diffraction allows us to characterize the crystal structure by distinguishing “green rust one” (GR1) from “green rust two” (GR2). Since green rusts (GRs) are of a pyroaurite-sjögrenite-like structure, i.e., consisting of intercalated foreign anions and water molecules in the interlayers between the brucite-like layers of Fe(OH)2, their chemical formulae can be determined from the Mössbauer spectra. Three quadrupole doublets are observed: D1 and D2 correspond to a ferrous state with isomershift IS of about 1.27 mm s-1 and quadrupole splittings QS of about 2.85 and 2.60 mm s-1, respectively, whereas D3 corresponds to a ferric state with IS and QS of about 0.4 mm s-1. The hyperfine parameters of these doublets are similar from one green rust to another but their intensity ratios vary considerably. Finally, Eh and pH equilibrium diagrams of the Fe species in the presence of chloride, sulphate and carbonate anions contained within the water solution are drawn and the thermodynamic conditions of existence and degrees of oxidation of green rusts are discussed. 相似文献
303.
One of the shortcomings of R&D evaluation is a lack of emphasis on analytical assessment of the value of an on-going R&D project. This paper addresses the problem concerning the distributive aspect of access to superior knowledge. Decision tree analysis and probability models appear to be appropriate tools for assessing the values of an intermediate result and patent reward of a firm's R&D decision in an environment of perfect information and oligopolistic competition. The assessed values are used as minimum prices acceptable to the firm when the knowledge is disseminated to the public. This paper will attempt to resolve this problem through the determination of the appropriate values of the reservation price of the first-stage invention in terms of the final reward and of a patent reward for which the inventor is willing to apply. 相似文献
304.
Dr. David J. Lurie I. Nicholson J. S. McLay J. R. Mallard 《Applied magnetic resonance》1992,3(5):917-925
The technique of Field-Cycled Dynamic Nuclear Polarization (FC-DNP) involves the EPR irradiation of a free radical solution and the subsequent observation of the NMR signal, the experiment being carried out at a range of magnetic field strengths in order to measure the free radical’s EPR spectrum. In this work FC-DNP has been used to study the EPR spectrum of DMPO spin-trapped hydroxyl free radicals at magnetic field strengths between 0.5 mT and 13.0 mT (5–130 Gauss). The low-field EPR spectrum contains six separate EPR lines, in contrast to the well-known X-band spectrum where only four are seen. Knowledge of the spin-adduct’s EPR spectrum will be of use to workers involved in low-field EPR, especially those conducting biological or in-vivo spin-trapping experiments. 相似文献
305.
Flux jumps have been observed in a large (138 mg) single crystal of La1.86Sr0.14CuO4. Both complete and incomplete flux jumps are observed with the energy dissipated by complete flux jumps consistent with temperature rises to nearly Tc. The systematics of these flux jumps with respect to field history, temperature and the time duration of the hysteresis measurements are reported. The field at which flux jumps first occur and their subsequent spacing are not consistent with a simple adiabatic theory of flux jumps for our experimental conditions. Instead, the crystal is observed to be stabilized against flux jumps by flux creep which occurs during the time interval over which field steps are accomplished as well as during imposed time intervals between field steps. 相似文献
306.
Cheriyan and Hagerup developed a randomized algorithm to compute the maximum flow in a graph with n nodes and m edges in O(mn + n2 log2n) expected time. The randomization is used to efficiently play a certain combinatorial game that arises during the computation. We give a version of their algorithm where a general version of their game arises. Then we give a strategy for the game that yields a deterministic algorithm for computing the maximum flow in a directed graph with n nodes and m edges that runs in time O(mn(logm/n log nn)). Our algorithm gives an O(mn) deterministic algorithm for all m/n = Ω(nε) for any positive constant ε, and is currently the fastest deterministic algorithm for computing maximum flow as long as m/n = ω(log n). 相似文献
307.
A. R. Kuznetsov S. G. Lunter S. I. Nikitina A. G. Plyukhin Yu. K. Fedorov 《Journal of Applied Spectroscopy》1992,56(1):68-72
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 56, No. 1, pp. 90–95, January, 1992. 相似文献
308.
A. S. Kalashnikov 《Journal of Mathematical Sciences》1997,85(6):2287-2301
The paper deals with several problems having the following common feature. The differential equation under consideration contains
a power function of the solution or of its gradient, with the exponent depending on a small parameter. This dependence is
such that a certain property of the solutions corresponding to the positive values of the parameter may disappear as the latter
tends to zero. This phenomenon is shown to be lacking in the case where not only the said exponent, but also the coefficients
of the equation depend on the small parameter in a suitable way. Several theorems are proved on sharp conditions, ensuring
such uniformity of various properties exhibited by the solutions. Bibliography: 44 titles.
Dedicated to Olga Arsenievna Oleinik
This paper has been supported in part by the Russian Foundation for Basic Research (Project 93-013-1744) and by the International
Science Foundation (Grant MIE000).
Translated from Trudy Seminara imeni I. G. Petrovskogo, No. 19, pp. 000-000, 0000. 相似文献
309.
310.
S. Ya. Yakubov 《Results in Mathematics》1995,28(1-2):153-168
In this paper we find conditions guarantee that irregular boundary value problems for elliptic differential-operator equations of the second order in an interval are fredholm. We apply this result to find some algebraic conditions guarantee that irregular boundary value problems for elliptic partial differential equations of the second order in cylindrical domains are fredholm. Apparently this is the first paper where the regularity of an elliptic boundary value problem is not satisfied on a manifold of the dimension equal to dimension of the boundary. Nevertheless the problem is fredholm and the resolvent is compact. It is interesting to note that the considered boundary value problems for elliptic equations in a cylinder being with separating variables are noncoercive. 相似文献