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91.
Kohtani S Yoshida K Maekawa T Iwase A Kudo A Miyabe H Nakagaki R 《Physical chemistry chemical physics : PCCP》2008,10(20):2986-2992
Superoxide anion radical (O(2)(-*)) and OH radical generations in suspensions of Ag metal-, Ag(2)O-, or AgO-loaded TiO(2) and BiVO(4) photocatalysts in alkaline conditions (pH 12.0) were examined by means of a luminol chemiluminescence (CL) technique and a spin-trapping fluorescence one in which terephthalic acid reacts with an OH radical to afford the highly fluorescent 2-hydroxyterephthalic acid (TAOH), respectively. The observed luminol CL intensity was remarkably enhanced by the AgO loading on TiO(2) as well as BiVO(4). This can be explained by enhancement of O(2)(-*) production on the AgO-loaded photocatalysts caused by the synergetic effects on the thermocatalytic activity upon the AgO surface and the efficient electron-hole separation at the photocatalyst/AgO interface. On the other hand, loading effects of AgO on the TAOH formation were not so significant compared to those on the CL observation, though the TAOH formation rates for the TiO(2) samples were much larger than those for the BiVO(4) ones by about three orders of magnitude. The properties of O(2)(-*) and OH radical generations on these photocatalysts are discussed on the basis of the luminol CL kinetics and approximate band edge positions of TiO(2), BiVO(4), and silver oxides. 相似文献
92.
Maho Morita Osamu Ohno Toshiaki Teruya Takao Yamori Toshiyasu Inuzuka Kiyotake Suenaga 《Tetrahedron》2012,68(30):5984-5990
Bioassay-guided fractionation of the marine cyanobacterium Lyngbya sp. led to the isolation of biselyngbyasides B (3), C (4), and D (5), novel analogs of biselyngbyaside (1) and biselyngbyolide A (2). The gross structures of 3–5 were determined by NMR spectral analyses, and their stereochemistries were established based on NOESY spectra and CD data. Biselyngbyasides (1–3) showed growth-inhibitory activity and apoptosis-inducing activity against both HeLa S3 cells and HL60 cells. The fura-2 method revealed that biselyngbyasides (1–3) increased the cytosolic Ca2+ concentration in HeLa S3 cells. 相似文献
93.
Synergistic hybrid catalyst for cyclic carbonate synthesis: remarkable acceleration caused by immobilization of homogeneous catalyst on silica 总被引:3,自引:0,他引:3
Takahashi T Watahiki T Kitazume S Yasuda H Sakakura T 《Chemical communications (Cambridge, England)》2006,(15):1664-1666
The catalytic activity of phosphonium salts towards cyclic carbonate synthesis from propylene oxide and CO2 has been enormously enhanced by their immobilization onto silica that itself has no catalytic activity. 相似文献