全文获取类型
收费全文 | 537篇 |
免费 | 36篇 |
国内免费 | 1篇 |
专业分类
化学 | 466篇 |
晶体学 | 5篇 |
力学 | 4篇 |
数学 | 47篇 |
物理学 | 52篇 |
出版年
2023年 | 5篇 |
2021年 | 5篇 |
2020年 | 4篇 |
2019年 | 8篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 14篇 |
2015年 | 15篇 |
2014年 | 17篇 |
2013年 | 25篇 |
2012年 | 19篇 |
2011年 | 27篇 |
2010年 | 24篇 |
2009年 | 7篇 |
2008年 | 24篇 |
2007年 | 21篇 |
2006年 | 23篇 |
2005年 | 31篇 |
2004年 | 26篇 |
2003年 | 32篇 |
2002年 | 25篇 |
2001年 | 4篇 |
2000年 | 3篇 |
1999年 | 7篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 7篇 |
1994年 | 12篇 |
1993年 | 12篇 |
1992年 | 9篇 |
1991年 | 10篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 8篇 |
1987年 | 3篇 |
1985年 | 15篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 16篇 |
1980年 | 9篇 |
1979年 | 12篇 |
1978年 | 7篇 |
1977年 | 9篇 |
1974年 | 4篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1969年 | 1篇 |
1968年 | 2篇 |
排序方式: 共有574条查询结果,搜索用时 15 毫秒
61.
(Imido)vanadium(V) complexes have attracted much attention because of their potential applications as catalysts. Compared with oxo ligands, imido ligands can possess a substituent on the imido nitrogen so that the steric and electronic characters of the metal center are considered to be controlled by the properties of the nitrogen substituent. In such a sense, the design of the imido ligands is envisioned to be one of the key factors in the development of efficient catalysts. Furthermore, architectural control of transition metal-directed assembly to create organized nanostructures is of importance for advanced materials. This review highlights self-assembling properties of (arylimido)vanadium(V) compounds. 相似文献
62.
1-Phenylcyclopentadiene fused with two homoadamantene units at the 2,3- and 4,5-positions (4) was deprotonated with KH to lead to the quantitative formation of the corresponding cyclopentadienyl (Cp) anion 3(-). This anion was oxidized by AgCl to afford an orange crystalline solid consisting of Cp radical 3(?) and cyclopentadiene 4. The ESR spectrum in hexane exhibited approximately 15 lines, demonstrating that the two homoadamantene frameworks were equivalent and that the C1-C2(Ph)-C3 moiety of the five-membered ring formed a symmetrical allyl-like radical in agreement with the prediction by DFT calculation. The reaction of the Cp radical 3(?) with an oxygen molecule in the presence of Ag(+)SbF(6)(-) afforded the SbF(6)(-) salt of a phenylpyrylium ion annelated with two homoadamantene frameworks (8(+)SbF(6)(-)). 相似文献
63.
Amaya T Hifumi M Okada M Shimizu Y Moriuchi T Segawa K Ando Y Hirao T 《The Journal of organic chemistry》2011,76(19):8049-8052
Oxosumanenes were synthesized through benzylic oxidation. The electronic and redox properties were revealed to exhibit the expanded π-conjugation compared to sumanene. Single-crystal X-ray analysis of monooxosumanene showed columnar π-stacking in a concave-convex fashion. Stereoselective trimethylation of the trioxo derivative was performed via 1,2-addition to the carbonyl groups. 相似文献
64.
Lee WE Lee CL Sakaguchi T Fujiki M Kwak G 《Chemical communications (Cambridge, England)》2011,47(12):3526-3528
Liquid crystalline diphenylacetylene polymer derivatives showed piezochromic fluorescence via order-to-disorder phase transition. 相似文献
65.
66.
Positivity - Let $$n\ge 2$$ be the spatial dimension. The purpose of this note is to obtain some weighted estimates for the fractional maximal operator $${{\mathfrak {M}}}_{\alpha }$$ of order... 相似文献
67.
Toshikazu Kaise Hiroshi Yamauchi Yoshiya Horiguchi Takayuki Tani Shigenobu Watanabe Teruhisa Hirayama Shozo Fukui 《应用有机金属化学》1989,3(3):273-277
The acute toxicity of methylarsonic acid, CH3AsO(OH)2 (MAA), dimethylarsininc acid, (CH3)2AsO(OH) (DMAA), and trimethylarsine oxide, (CH3)3AsO (TMAO), were examined in mice with oral administration. The LD50 values of MAA, DMAA and TMAO were 1.8, 1.2 and 10.6 g kg?1 respectively. The toxicity of MAA and DMAA was very much lower than that for inorganic arsenic compounds. It was shown that TMAO has a similar acute toxicity to arsenobetaine. On the other hand, when the mice were administered 14.4 g kg?1 of TMAO once only orally, a garlic-like odor (trimethylarsine, (CH3)3As) was definitely detectable in the exhalation of the animals by the human olfactory sense within about a few minutes. 相似文献
68.
69.
Akiya Ogawa Syoji Ohya Yukihito Sumino Noboru Sonoda Toshikazu Hirao 《Tetrahedron letters》1997,38(52):584-9018
Irradiation with near-UV light, dramatically enhances the reducing ability of ytterbium diiodide (YbI2). Organic bromides, iodides, tosylates, and tellurides are reduced efficiently by a YbI2-hv system, while these can not be reduced with YbI2 in the dark. 相似文献
70.