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41.
In the title complex, (C6H11N2)3[LaCl6], centrosymmetric octahedral hexa­chloro­lanthanate anions are located at the corners and face‐centers of the monoclinic unit cell. The ring H atoms of the cations interact with the Cl atoms of the anions via hydrogen bonding, and bifurcation of the hydrogen bonding is observed. Cation–cation interactions via hydrogen bonding between the ring H atoms and π‐electrons of aromatic rings are also observed as in other imidazolium salts.  相似文献   
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An antiviral nucleoside or virazole was synthesized efficiently and regioselectively starting with benzyl cyanoformate.  相似文献   
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The adsorbability of pertechnetate ion (TcO 4 ) reached 96% for an active carbon at the 0.1 g/50 ml concentration level, increasing with diminution of acid and its salt concentrations, and depending on the type of anions present. With constant anion concentration, TcO 4 adsorbability rose with decreasing pH in the acidic region, followed in the region around neutrality by a plateau, and in the basic region by an appreciable decline of TcO 4 adsorbability. In the acidic region, part of once-adsorbed TcO 4 appeared to be displaced by other anions. Reversibility was noted between the adsorption and desorption of TcO 4 .  相似文献   
47.
High-speed counter-current chromatography (HSCCC) was used to purify salidroside from an extract of Rhodiola crenulata with two steps using a two-phase solvent system composed of ethyl acetate-n-butanol-water (1:4:5, v/v) in the first run and chloroform-methanol-isopropanol-water (5:6:1:4) in the second run. The method yielded 21.9 mg of salidroside from 1.216 g of the crude sample at 98% purity determined by HPLC analyses. Identification was performed by 1H NMR, 13C NMR, and MS.  相似文献   
48.
To sophisticate the nuclear fuel recycling processes, the transfer percentages for Pd, Mo, Te, and Sb should be determined. Each element solution containing NaNO3 or HNO3 was fed consistently into the thin film evaporator regulated in vac and at 50 °C. The analyte percentages in the inside of the lid, in the condenser, and in the distillate were 10-1%/m2, 10-3%/m2, and 10-3% (DF = 105), respectively. The Mo percentage in the condenser was lower by a factor of 10 than those of other elements investigated. The NO3 - percentages were nearly constant despite increasing HNO3 concentrations, however, the ratios decreased with increasing NaNO3 concentrations.  相似文献   
49.
Isotachophoretic qualitative indices, RE, for twenty-eight dipeptides were measured in the range pH 7.4–9.6. The absolute mobility, mo, and pKa values were evaluated by the use of the least-squares method, utilizing a simulation of the isotachophoretic steady state. The mo values were newly evaluated and the pKa values were in good agreement with literature values. By comparison of the evaluated mo and pKa values of the dipeptides with those of the constituent amino acids, simple relationships were found which may be used to estimate the mo and pKa values of other dipeptides. The separability of the dipeptides was also evaluated by considering the differences between their simulated effective mobilities. It is concluded that isotachophoresis is very convenient for the separation of dipeptides and their constituent amino acids.  相似文献   
50.
Thiazolo[3,2-a]thieno[3,2-d]-, [3,4-d]- and [2,3-d]pyrimidin-5-one derivatives (6, 11 and 16), and polymethylene condensed thieno[3,2-d]-, [3,4-d]- and [2,3-d]pyrimidin-5-one derivatives (19-21), in which the oxygen atom of the oxazolidine moiety in 3 was replaced by a sulfur atom or methylene groups, were synthesized and evaluated for gastric antisecretory activity in pylorus-ligated rats. The structure-activity relationships of these compounds are discussed.  相似文献   
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