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71.
A sensitive determination of gas chromatographic peak yields by a new radio-gas chromatograph equipped with a synchronized accumulating radioisotope detector is described. Peak yields could be easily determined by the radio-gas chromatograph using [3H]hexadecane or [3H]androstenedione as a standard substance. The usefulness of the determination of peak yields was demonstrated by optimizing the derivatization conditions of 6-keto-prostaglandin F1 alpha. 相似文献
72.
S. Banerjee S. N. Ganguli A. Gurtu R. Raghavan K. Shankar Y. Goldschmidt-Clermont R. T. Ross S. Squarcia K. Dziunikowska T. Haupt P. Girtler D. Kuhn G. Koul Devanand P. V. K. S. Baba Gian Singh K. W. J. Barnham J. Wells P. R. S. Wright F. Mandl M. Markytan M. Bardadin-Otwinowska M. Szczekowski 《Zeitschrift fur Physik C Particles and Fields》1986,31(3):409-416
Results are presented on inclusive production of ∑+(1385) and ∑?(1385) inK ? p interactions at 110 GeV/c. The inclusive and topological cross sections have been estimated and compared with published results at lower energies. The inclusive cross section of ∑+(1385) seems to decrease with c.m. energy, while that of the ∑?(1385) is nearly constant. The mean charged multiplicity associate to Σ(1385) increases with c.m. energy. The ∑+(1385) is produced both in the target fragmentation region and in the central region where ∑?(1385) is predominantly produced in the central region. Approximately 16% of the Λ's stem from the decay of ∑±(1385) and the kinematic distributions of these Λ's are not very different from the inclusive Λ's. 相似文献
73.
Jnn'ichi Toei Keizen Fujii Nobuyuki Baba 《Fresenius' Journal of Analytical Chemistry》1989,334(1):13-15
Summary A new type reaction valve for flow injection analysis has been developed. In a FIA system with this valve the injected sample is once passed into a loop of the valve, thereafter the valve is rotated to the next position. Therefore, the sample is retained in the loop in a stop-state for a long time and the next sample is introduced into another loop in the next position. When the valve is rotated for one round, the stopped sample in the fist loop is again passed into the detector flow cell. Thus, an analysis, which needs a long reaction time, can be performed with this valve with high precision.
Verbessertes Reaktionsventil für die Flie\injektionsanalyse相似文献
74.
Han-zhou Yu Jing Li Yan-Lin Ye Biao Yang Cheng-Jian Lin Hui-Ming Jia Jian-Ling Lou Xiao-Fei Yang T. Baba Qi-Te Li Yu-Cheng Ge Zhi-Huan Li Hui Hua Jin-Yan Xu Zai-Hong Yang Jun Feng Hong-Liang Zang Qiang Liu Wei Jiang Yang Liu Jing-Jing Li Wei Liu Shi-Wei Bai Jie Chen Jia-Xing Han Jia-Hao Chen Kai Ma Dong-Xi Wang Lei Yang Nan-Ru Ma LI-Jie Sun 《中国物理C(英文版)》2021,45(8):084002-084002-5
75.
Mahdi Rabbani Yongli Wang Reza Khoshkangini Hamed Jelodar Ruxin Zhao Sajjad Bagheri Baba Ahmadi Seyedvalyallah Ayobi 《Entropy (Basel, Switzerland)》2021,23(5)
Network anomaly detection systems (NADSs) play a significant role in every network defense system as they detect and prevent malicious activities. Therefore, this paper offers an exhaustive overview of different aspects of anomaly-based network intrusion detection systems (NIDSs). Additionally, contemporary malicious activities in network systems and the important properties of intrusion detection systems are discussed as well. The present survey explains important phases of NADSs, such as pre-processing, feature extraction and malicious behavior detection and recognition. In addition, with regard to the detection and recognition phase, recent machine learning approaches including supervised, unsupervised, new deep and ensemble learning techniques have been comprehensively discussed; moreover, some details about currently available benchmark datasets for training and evaluating machine learning techniques are provided by the researchers. In the end, potential challenges together with some future directions for machine learning-based NADSs are specified. 相似文献
76.
Hiroyuki Suga Satoshi Higuchi Daisuke Ishimoto Yuta Hashimoto Teruko Tsuchida Toshihide Baba 《Tetrahedron》2010,66(16):3070-6287
High enantioselectivities (94-96% ee) were obtained for the inverse electron-demand 1,3-dipolar cycloadditions between cyclohexyl vinyl ether and 2-benzopyrylium-4-olate generated via Rh2(OAc)4-catalyzed decomposition of o-methoxycarbonyl-α-diazoacetophenone. The reactions were effectively catalyzed by Eu(OTf)3, Ho(OTf)3, or Gd(OTf)3 complexes (10 mol %) of chiral 2,6-bis[(4S,5S)-4,5-diphenyl-2-oxazolinyl]pyridine. The reactions with the other electron-rich dipolarophiles such as allyl alcohol, 2,3-dihydrofuran, and butyl-tert-butyldimethylsilylketene acetal showed moderate enanantioselectivities (60-73% ee). Good to high enantioselectivities (73-97% ee) were also obtained for the cycloadditions between 3-acyl-2-benzopyrylium-4-olates, generated from methyl 2-(2-diazo-1,3-dioxoalkyl)benzoates and butyl or cyclohexyl vinyl ethers, in the presence of binaphthyldiimine (BINIM)-Ni(II) complexes (10 mol %). Under similar conditions, the reaction between methyl 2-(2-diazo-1,3-dioxohexyl)benzoate and 2,3-dihydrofuran was highly endo-selective, and moderately enantioselective (70% ee). For the BINIM-Ni(II)-catalyzed reactions of cyclohexyl vinyl ether, the use of an epoxyindanone as the 3-acyl-2-benzopyrylium-4-olate precursor revealed that the chiral Lewis acid can function as a catalyst for asymmetric induction. The scope of the cyclic carbonyl ylides was extended to those generated from 1-diazo-2,5-pentanedione derivatives, which were reacted with butyl or TBS vinyl ether and catalyzed using the (4S,5S)-Pybox-4,5-Ph2-Lu(OTf)3 complex to give good levels of asymmetric inductions (75-84% ee). 相似文献
77.
Nitroxyl radicals (nitroxides) with unpaired electron are widely used as antioxidants, contrast agents, and spin probes. Although piperidine nitroxyl radicals have many applications, these are mainly tetramethylpiperidine compounds, and only a few reports consider the substitution of N-O surround as a reaction site, such as 2,2,6,6-tetrasubstituted piperidine nitroxyl radicals. Our results revealed that the 2,6-position of the 2,2,6,6-tetramethylpiperidin-4-one compound was substituted by cyclohexyl groups to produce 2,2,6,6-tetrasubstituted piperidin-4-one derivatives under mild reaction conditions. An interesting result was obtained by using 15N-labeled NH4Cl instead of 14NH4Cl: it gave 15N-labeled 2,2,6,6-tetrasubstituted piperidin-4-one-1-oxyls with a high 15N content. In conclusion, the new method for the synthesis of nitroxyl radicals readily yields 2,2,6,6-tetrasubstituted piperidin-4-one under mild conditions. 相似文献
78.
Haruka Baba 《Tetrahedron letters》2010,51(15):2063-4307
Treatment of alkylbenzenes with p-toluenesulfonamide and 1,3-diiodo-5,5-dimethylhydantoin (DIH) in a small amount of carbon tetrachloride at 60 °C gave the corresponding α-p-toluenesulfonylamido)alkylbenzenes in good to moderate yields. The present reaction is a simple method for the α-sulfonylamidation of the benzylic position in alkylbenzenes. 相似文献
79.
Susumu Kuwamura Yuuki Yoshinoya Noriaki Miura Fumiaki Tsumuraya Makoto Sakamoto Naoshi Baba 《Optical Review》2011,18(1):19-26
A bispectral method for astronomical speckle imaging utilizes an average speckle bispectrum of an object to derive its Fourier
phase. There has been, however, a problem in conventional bispectral algorithm owing to difficulty in processing bispectral
data in a four-dimensional (4D) space. In this paper, we propose an implementation to overcome this problem, where a one-dimensional
(1D) object projection is reconstructed from a two-dimensional (2D) average bispectrum of speckle projections, and object
projections so obtained at various angles are then tomographically combined into a 2D object image. In this tomographic approach,
processes are separable into those for individual projection angles, implying that bispectral data required to be stored at
a time are from 4D to 2D and computation time can be substantially reduced by parallelizing angle-by-angle processes. We have
performed experiments using simulated and observed data, and have demonstrated the feasibility of the present approach with
an achievable accuracy comparable to that of a conventional approach. 相似文献
80.
Tomohiro Suetsuna Seiichi SuenagaShinya Sakurada Koichi HaradaMaki Tomimatsu Toshihide Takahashi 《Journal of magnetism and magnetic materials》2011,323(13):1793-1798
Self-forming core/shell nanoparticles of magnetic metal/oxide with crystalline grain size of less than 40 nm were synthesized. The nanoparticles were highly concentrated in an insulating matrix to fabricate a nanocomposite, whose magnetic properties were investigated. The crystalline grain size of the nanoparticles strongly influenced the magnetic anisotropy field, magnetic coercivity, relative permeability, and loss factor (tan δ=μ″/μ′) at high frequency. The packing ratio of the magnetic metallic phase in the nanocomposite also influenced those properties. High permeability with low tan δ of less than 1.5% at up to 1 GHz was obtained in the case of the nanoparticles with crystalline grain size of around 15 nm with large packing ratio of the nanoparticles. 相似文献