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41.
Surface-enhanced Raman spectra (SERS) on silver hydrosols of p-nitrobenzoic acid, p-aminobenzoic acid and aniline are reported. Several theoretical and practical aspects of the hydrosol preparation protocols and sample preparation procedures, and their effects on the sensitivity and reproducibility of the Raman signals are discussed. The effect of acidity on SERS signal intensity is shown to depend on the time of observation of the Raman spectra, illustrating the relevance of time to quantitative SERS data. the identification power of SERS at trace levels for closely related compounds (p-nitrobenzoic acid, p-aminobenzoic acid and aniline) is illustrated. 相似文献
42.
Guerreiro C. T. R. Ribeiro C. A. Crespi M. S. Torres C. 《Journal of Thermal Analysis and Calorimetry》2002,67(2):419-424
Magnesium ion was reacted with 5,7-dibromo-, 5,7-dichloro-, 7-iodo-and 5-chloro-7-iodo-8-hydroxyquinoline, in acetone/ammonium
hydroxide medium under constant stirring to obtain (I) Mg[(C9H4ONBr2)2]·2H2O; (II) Mg[(C9H4ONCl2)2]·3H2O; (III) Mg[(C9H5ONI)2]·2H2O and (IV)Mg[(C9H4ONICl)2]·2.5H2O complexes. The compounds were characterized by elemental analysis, IR spectra, ICP, TG-DTA and DSC.
Through thermal decomposition residues were obtained and characterized, by X-ray diffractometry, as a mixture of hexagonal
MgBr2 and cubic MgO to the (I) compound at 850°C; cubic MgO to the (II), (III) and (IV) compounds at750, 800 and 700°C, respectively.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
43.
Martinez-Diaz MV Rodriguez-Morgade MS Feiters MC van Kan PJ Nolte RJ Stoddart JF Torres T 《Organic letters》2000,2(8):1057-1060
[formula: see text] New unsymmetrically substituted DB24C8-phthalocyanines, which are able to form complexes with suitable dialkylammonium cations, have been prepared. These complexes most probably have a pseudorotaxane geometry. 相似文献
44.
Guldi DM Gouloumis A Vázquez P Torres T Georgakilas V Prato M 《Journal of the American Chemical Society》2005,127(16):5811-5813
Induction of self-organization between zinc phthalocyanine (ZnPc) and C60 moieties in a novel amphiphilic ZnPc-C60 salt results in uniformly nanostructured 1-D nanotubules. Their photoreactivity, in terms of ultrafast charge separation (i.e., approximately 1012 s-1) and ultraslow charge recombination (i.e., approximately 103 s-1), is remarkable. In addition, the observed ZnPc*+-C60*- lifetime of 1.4 ms implies, relative to that of the monomeric ZnPc-C60 ( approximately 3 ns), an impressive stabilization of 6 orders of magnitude. 相似文献
45.
L. V. Gorshkova V. P. Zvolinskii N. S. Prostakov A. V. Varlamov M. Torres V. F. Zakharov 《Chemistry of Heterocyclic Compounds》1980,16(12):1245-1248
The diene condensation of 1,3-diphenyl-2-azaanthracene with maleic anhydride proceeds under more severe conditions than the analogous condensation with anthracene. On the basis of an analysis of the PMR data for the adduct obtained it was assumed that isomers of ,-[9,10-dihydro-2-aza-1,3-diphenylanthrylene(9,10)]succinic anhydride with respect to the position of the anhydride bridge relative to the pyridine ring are formed in this condensation. 9,10-Dihydro-2-aza-1,3-diphenyl-9, 10-(1-cyanoethylene)anthracene was obtained in the condensation of the same azaanthracene with acrylonitrile. ,-[5H-8-Aza-7-phenylbenzo[a]fluoranthrylene (5,12b) ]succinic anhydride is formed as a result of the similar condensation of 8-aza-7-phenylbenzo[a]fluoranthene with maleic anhydride, while isomeric (with respect to the position of the nitrile group in the ethylene bridge) 5H-8-aza-7-phenyl-5,12b-(cyanoethylene)benzo[a]fluoranthenes were isolated in its condensation with the acrylonitrile. Data from the PMR and IR spectra were used to prove the structures of the adducts of the diene synthesis obtained.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1645–1647, December, 1980. 相似文献
46.
Feng G Mareque-Rivas JC Torres Martín de Rosales R Williams NH 《Journal of the American Chemical Society》2005,127(39):13470-13471
The activity of a Zn(II) complex of a tetradentate, tripodal ligand for catalyzing phosphodiester cleavage is enhanced 750-fold by introducing three hydrogen bond donors to the ligand. Inhibition studies show that the Zn-aqua complex is the kinetically active form and that it binds the transition state with a formal dissociation constant of 3 x 108 M-1. The effect of these ligand modifications on the transition-state affinity is comparable to the rate acceleration provided by the metal ion itself. Overall, this mononuclear complex is more active than the most reactive dinuclear Zn(II) complexes reported to date. 相似文献
47.
Elenise Bannwart de Moraes Patricia Fazzio Martins César Benedito Batistella Mario Eusebio Torres Alvarez Rubens Maciel Filho Maria Regina Wolf Maciel 《Applied biochemistry and biotechnology》2006,132(1-3):1066-1076
Molecular distillation was studied for the separation of tocopherols from soya sludge, both experimentally and by simulation,
under different operating conditions, with good agreement. Evaporator temperatures varied from 100°C to 160°C and feed flow
rates ranged from 0.1 to 0.8 kg/h. The process pressure was maintained at 10−6 bar, the feed temperature at 50°C, the condenser temperature at 60°C, and the stirring at 350 rpm. For each process condition,
samples of both streams (distillate and residue) were collected and stored at −18°C before tocopherols analyses. Owing to
the differences between molecular weights and vapor pressures of free fatty acids and tocopherols, tocopherols preferentially
remained in the residue at evaporator temperatures of 100°C and 120°C, whereas for higher temperatures (140°C and 160°C) and
lower feed flow rate, tocopherols tended to migrate to the distillate stream. 相似文献
48.
L. C. Balbás A. Rubio M. B. Torres 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1994,31(4):269-273
Total (elastic + inelastic) cross-sections for electron scattering from C, N, O atoms and their simple molecules are studied theoretically. Thee
–-C, N, O atomic calculations are done in the complex optical potential approach. To study the electron scattering from O2, N2, CO, NO, CN, C2 as well as CO2, N2O, NO2 O3 targets, we have adopted an additivity rule, wherein the molecular cross-section is an incoherent sum of the cross-sections of the constituent atoms. The cross-sections of C, N & O atoms are presented at incident energiesE
i
=10–1000 eV, the molecular cross-sections are presented atE
i
=100–1000 eV. The reliability of the additivity rule is discussed against the background of experimental data. 相似文献
49.
Fast reduction of a copper center in laccase by nitric oxide and formation of a peroxide intermediate 总被引:3,自引:0,他引:3
Torres J Svistunenko D Karlsson B Cooper CE Wilson MT 《Journal of the American Chemical Society》2002,124(6):963-967
The rapid reduction of one of the copper atoms (type 2) of tree laccase by nitric oxide (NO) has been detected. Addition of NO to native laccase in the presence of oxygen leads to EPR changes consistent with fast reduction and slow reoxidation of this metal center. These events are paralleled by optical changes that are reminiscent of formation and decay of the peroxide intermediate in a fraction of the enzyme population. Formation of this species is only possible if the trinuclear copper cluster (type 2 plus type 3) is fully reduced. This condition can only be met if, as suggested previously, a fraction of the enzyme contains both type 3 coppers already reduced before addition of NO. Our data are consistent with this assumption. We have suggested recently that fast reduction of copper is the mechanism by which NO interacts with the oxidized dinuclear center in cytochrome c oxidase. The present experiments using laccase strongly support this view and suggest this reaction as a general mechanism by which copper proteins interact with NO. In addition, this provides an unexploited way to produce a stable peroxide intermediate in copper oxidases in which the full complement of copper atoms is present. This enables the O-O scission step in the catalytic cycle to be studied by electron addition to the peroxide derivative through the native electron entry site, type 1 copper. 相似文献
50.
1,5-Bis[(2-pyridyl)-3-sulphophenyl methylene] thiocarbonohydrazide (PSTH) immobilized on an anion-exchange resin (Dowex) has been used for the on-line preconcentration of mercury from biological samples and waters prior to its determination by inductively coupled plasma atomic emission spectroscopy. The metal was eluted from the column using a solution of 2 M HNO(3) and mixed on-line with SnCl(2). The optimum experimental conditions were evaluated for the continuous preconcentration of Hg, the direct generation of mercury vapour and the final determination of this element by ICP-AES. The enrichment, together with low blank levels of the optimized procedure, allow the simple determination of this toxic element at concentrations down to a few nanograms per milliliter. The proposed method has a linear calibration range 5-1000 ng ml(-1) of mercury, with a detection limit of 4 ng ml(-1) (S/N=3) and a sampling rate of 40 h(-1), investigated with a 9 ml sample volume. The precision of the method (evaluated as the relative standard deviation obtained after analyzing ten series of ten replicates) was +/-3.6% at the 10 ng ml(-1) level of Hg(II) and +/-1.3% at the 100 ng ml(-1) level. The accuracy of the method was examined by the analysis of certified reference materials. 相似文献