Low-temperature heat capacity of room-temperature ionic liquid, 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Heat capacities of liquid, stable crystal, and liquid-quenched glass of a room-temperature ionic liquid (RTIL), 1-hexyl-3-methylimidazolium bis(trifluromethylsulfonyl)imide were measured between 5 and 310 K by adiabatic calorimetry. Heat capacity of the liquid at 298.15 K was determined for an IUPAC project as (631.6 +/- 0.5) J K(-1) mol(-1). Fusion was observed at T(fus) = 272.10 K for the stable crystalline phase, with enthalpy and entropy of fusion of 28.34 kJ mol(-1) and 104.2 J K(-1) mol(-1), respectively. The purity of the sample was estimated as 99.83 mol % by the fractional melting method. The liquid could be supercooled easily and the glass transition was observed around T(g) approximately 183 K, which was in agreement with the empirical relation, T(g) approximately ((2)/(3)) T(fus). The heat capacity of the liquid-quenched glass was larger than that of the crystal as a whole. In the lowest temperature region, however, the difference between the two showed a maximum around 6 K and a minimum around 15 K, at which the heat capacity of the glass was a little smaller than that of crystal.     

Synthesis of a phosphorus-containing hybrid porphyrin

A phosphorus-containing hybrid porphyrin was successfully prepared via the BF3-promoted dehydrative condensation between sigma4-phosphatripyrrane and 2,5-bis[hydroxy(phenyl)methyl]thiophene. The NMR and UV-vis absorption spectra, electrochemical measurements, and DFT calculations revealed that the sigma3-P,N2,S-hybrid porphyrin exhibits high aromaticity as an 18pi-electron system in terms of both geometric and magnetic criteria. [structure: see text]     

Isotope shift calculations for open-shell atoms and ions: an extension to the RATIP program

During the past decade, the Ratip program has been found useful for calculating a variety of atomic properties, including energies, transition probabilities, Auger parameters as well as a number of excitation, ionization and capture cross sections for processes with a single electron in the continuum. Recently, in addition, this suite of programs was extended to predict also the isotope shift and hyperfine parameters of open-shell atoms and ions. Here, we review the latest developments of the Ratip program with emphasis on the specific mass-shift M ^sms and field-shift F parameters. Detailed computations for these parameters have been carried out especially for the $4s\;^2S_{1/2} - 4p\;^2P_{1/2,3/2}$ transitions at ~ 397 nm of singly-charged Ca^?+? ions and are compared with available data from the literature.     

Gauss maps of the Ricci-mean curvature flow

In this paper, we investigate the Gauss maps of a Ricci-mean curvature flow. A Ricci-mean curvature flow is a coupled equation of a mean curvature flow and a Ricci flow on the ambient manifold. Ruh and Vilms (Trans Am Math Soc 149: 569–573, 1970) proved that the Gauss map of a minimal submanifold in a Euclidean space is a harmonic map, and Wang (Math Res Lett 10(2–3):287–299, 2003) extended this result to a mean curvature flow in a Euclidean space by proving its Gauss maps satisfy the harmonic map heat flow equation. In this paper, we deduce the evolution equation for the Gauss maps of a Ricci-mean curvature flow, and as a direct corollary we prove that the Gauss maps of a Ricci-mean curvature flow satisfy the vertically harmonic map heat flow equation when the codimension of submanifolds is 1.     

Pseudo-hyperbolic Gauss maps of Lorentzian surfaces in anti-de Sitter space

In this paper, we determine the type numbers of the pseudo-hyperbolic Gauss maps of all oriented Lorentzian surfaces of constant mean and Gaussian curvatures and non-diagonalizable shape operator in the 3-dimensional anti-de Sitter space. Also, we investigate the behavior of type numbers of the pseudo-hyperbolic Gauss map along the parallel family of such oriented Lorentzian surfaces in the 3-dimensional anti-de Sitter space. Furthermore, we investigate the type number of the pseudo-hyperbolic Gauss map of one of Lorentzian hypersurfaces of B-scroll type in a general dimensional anti-de Sitter space.     

pH-responsive movement of cucurbit[7]uril in a diblock polypseudorotaxane containing dimethyl beta-cyclodextrin and cucurbit[7]uril

[Structure: see text] A polypseudorotaxane consisting of cucurbit[7]uril (CB[7])/N,N'-(3-phenylenebis(methylene)dipropargylamine (PMPA), [2]pseudorotaxane, and 2,6-O-dimethyl beta-cyclodextrin (DM-beta-CD)/alpha,omega-bisazidopropylene glycol 400 [2]pseudorotaxane was synthesized using the "click" reaction. The polypseudorotaxane structure was maintained in aqueous solution over a wide range of pH values with the DM-beta-CD units contributing to increased solubilization of the polypseudorotaxane without dethreading. The pH-responsive movement of the CB[7] units in the polypseudorotaxane was also observed.     

Characterization of [ZnO]m[ZnMgO]n multiple quantum wells grown by molecular beam epitaxy

Thermal stability of single-crystalline [ZnO]_m[Zn_0.7Mg_0.3O]_n multiple quantum wells (MQWs) grown on a-plane sapphire substrates by plasma-assisted molecular beam epitaxy is reported. X-ray diffraction analysis revealed that these MQWs were grown as designed with a fixed Zn_0.7Mg_0.3O barrier width of and a series of ZnO well widths of . Cathodoluminescence spectra from these MQWs consisted of two major peaks; one was the emission from the bound excitons in Zn_0.7Mg_0.3O barrier layers, and the other was that from the confined excitons in ZnO well layers. These structural and optical properties were found to be dramatically changed by the ex situ annealing treatments over 700 °C. These changes were presumably due to the onset of phase separation of the Zn_0.7Mg_0.3O barrier layers with pronounced Mg diffusion toward the ZnO wells.