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821.
According to Fukumoto's method, a new series of ionic liquids (ILs) based on alanine, [Cnmim][Ala] ( n=2,3,4,5,6), which comprise 1-alkyl-3-methylimidazolium cation ([Cnmim](+)) and alanine anions ([Ala] (-)), were prepared and characterized. In terms of standard addition method, the density and surface tension of amino acid ILs [Cnmim][Ala] (1-alkyl-3-methylimidazolium alpha-aminopropionic acid salt) were measured in the temperature range 293.15-343.15+/-0.05 K. The volume and surface properties of the ILs [Cnmim][Ala] were discussed. A new method of determining parachor of ionic compound was proposed and was applied to estimate the physicochemical properties of amino acid ionic liquids (AAILs): molecular volume, surface tension, molar enthalpy of vaporization, and thermal expansion coefficient. In comparison with Deetlefs's method of using neutral parachor contribution, the method proposed in this work makes smaller error in estimating properties of AAILs.  相似文献   
822.
用混合法制备了工业乙苯脱氢催化剂,考察了新鲜催化剂和使用34个月后的催化剂的催化性能,并应用多种表征手段详细研究了所制备的工业催化剂在使用前后体相和表面的变化情况.活性测试结果发现,催化剂使用34个月后,活性下降12%,消炭后催化剂活性有所提高,但很快又恢复到失活后的水平.表征结果发现,积炭、钾的流失和催化剂活性相的烧结都不是导致催化剂失活的根本原因,而助催化剂钾的不均匀分布和催化剂活性相中Fe3 的还原可能是催化剂失活的主要原因.  相似文献   
823.
This work concentrates on pH-zone-refining counter-current chromatography of two isomeric dicaffeoylquinic acids, 3,5-dicaffeoylquinic acid and 3,4-dicaffeoylquinic acid along with 3-caffeoylquinic acid, from crude extracts of Flos Lonicerae. The elution sequence of the isomeric dicaffeoylquinic acids, the mixing zone and mechanism of separation are discussed. The separation of 2.136g of the crude sample from Flos Lonicerae yielded two isomeric compounds: 0.289g 3,5-dicaffeoylquinic acid and 0.106g 3,4-dicaffeoylquinic acid plus 0.690g 3-caffeoylquinic acid at a high purity of over 92.9%, 94.2% and 97.5%, respectively.  相似文献   
824.
Polyelectrolyte-layered films containing beta-cyclodextrin (beta-CD) were fabricated by a layer-by-layer deposition of carboxymethyl-beta-cyclodextrin (CM-beta-CD) as a polyanion and cationic photosensitive diazoresin (DR) on a solid surface. Under UV irradiation, following the decomposition of diazonium group between the adjacent interfaces of the multilayers, the ionic bonds of the self-assembly film convert to covalent bonds and the film become stable toward many common organic solvent. When a high-ionic-strength buffer is employed as a bathing solution, the film is thicker than that deposited from water solution. And the deposition increases with the increase of the carboxymethylated degree of CM-beta-CD. The CM-beta-CD/DR film can bind methylene blue (MB), and the durability of MB-adsorbing films to reductive glucose indicates that MB molecules not only diffuse into the film, but also load to the cavity of beta-CD through a host-guest complexation assisted by electrostatic interactions. The binding quantity of MB increases linearly with increasing the number of bilayers, and is influenced obviously by the pH value of MB aqueous solution. MB molecules can desorb from the 12-bilayer MB-absorbing CM-beta-CD/DR films when being immersed in water/ethanol mixture, and the released quantity of MB increases a little with increasing the concentration of water when it is below 30%, while decreases evidently over 30%.  相似文献   
825.
A series of 6-O-benzoyl-beta-cyclodextrins (CDs) with methyl, methoxy, methoxycarbonyl, and bromo substituent(s) at the ortho-, meta-, and/or para-position(s) were synthesized as chiral sensitizing hosts for the use in supramolecular enantiodifferentiating photoisomerization of (Z)-cyclooctene (1Z) to its chiral (E)-isomer (1E). The complex stability constants (K(S)) of the modified beta-CDs with 1Z in aqueous methanol solutions were highly sensitive to the substituent(s) introduced to the benzoate moiety, and the log K(S) values decreased linearly with slightly different slopes with increasing methanol content. The enantiomeric excess (ee) of 1E obtained upon photosensitization with these hosts was a critical function of the size and position of the substituent, varying from almost zero to 46% ee. This indicates that even an apparently small structural difference between methyl and methoxy can critically affect the enantiodifferentiating photoisomerization of a guest included in the chiral cavity, probably through manipulation of both the orientation of ground-state 1Z and the subsequent rotational relaxation of excited 1Z inside the chiral cavity.  相似文献   
826.
The NO catalytic direct decomposition was studied over La2CuO4 nanofibers, which were synthesized by using single walled carbon nanotubes (CNTs) as templates under hydrothermal condition. The composition and BET specific surface area of the La2CuO4 nanofiber were La2Cu0.882+Cu0.12+O3.94 and 105.0 m2/g, respectively. 100% NO conversion (turnover frequency-(TOF): 0.17 gNO/gcatalyst s) was obtained over such nanofiber catalyst at temperatures above 300 °C with the products being only N2 and O2. In 60 h on stream testing, either at 300 °C or at 800 °C, the nanofiber catalyst still showed high NO conversion efficiency (at 300 °C, 98%, TOF: 0.17 gNO/gcatalyst s; at 800 °C, 96%, TOF: 0.16 gNO/gcatalyst s). The O2 and NO temperature programmed desorption (TPD) results indicated that the desorption of oxygen over the nanofibers occurred at 80-190 and 720-900 °C; while NO desorption happened at temperatures of 210-330 °C. NO and O2 did not competitively adsorb on the nanofiber catalyst. For outstanding the advantage of the nanostate catalyst, the usual La2CuO4 bulk powder was also prepared and studied for comparison.  相似文献   
827.
Reductive elimination of alkyl−PdII−O is a synthetically useful yet underdeveloped elementary reaction. Here we report that the combination of an H-bonding donor [PyH][BF4] and AgNO3 additive under toluene/H2O biphasic system can enable such elementary step to form alkyl nitrate. This results in the Pd0-catalyzed asymmetric carbonitratations of (Z)-1-iodo-1,6-dienes with (R)-BINAP as the chiral ligand, affording alkyl nitrates up to 96 % ee. Mechanistic studies disclose that the reaction consists of oxidative addition of Pd0 catalyst to vinyl iodide, anion ligand exchange between I and NO3, alkene insertion and SN2-type alkyl−PdII−ONO2 reductive elimination. Evidences suggest that H-bonding interaction of PyH⋅⋅⋅ONO2 can facilitate dissociation of O2NO ligand from the alkyl−PdII−ONO2 species, thus enabling the challenging alkyl−PdII−ONO2 reductive elimination to be feasible.  相似文献   
828.
Liu  Hong-Ju  Tian  Wan-Lu  Wang  Xiao-Yue  Lei  Tong  Li  Pei  Xu  Guo-Yong  Li  Chao  Zhang  Shao-Jie  Wang  Fu-Zhou 《高分子科学》2023,41(6):905-914
Chinese Journal of Polymer Science - Branched polyolefins with controllable topology structures were generated from the chain-walking (co)polymerizations of ethylene, 1-pentene (1P) and 2-pentene...  相似文献   
829.
CMSX-4 is the second-generation nickel-based single crystal superalloy used widely in the world. The oxidation resistance and corrosion resistance of CMSX-4 alloy can be improved by adding trace lanthanum (La), cerium (Ce) and other rare earth elements. A method for the simultaneous determination of La and Ce in CMSX-4 nickel-based superalloy by wet dissolution-inductively coupled plasma mass spectrometry was established. The sample was heated and dissolved under normal pressure by aqua regia and hydrofluoric acid, and the interference of fluorine ion was eliminated by using perchloric acid. The amount of dissolved acid and the digestion conditions were optimized. The limits of detection were 0.23 μg/g for La and 0.85 μg/g for Ce under optimized conditions. The spiked recoveries were 95.0%–98.9% with the relative standard deviations of 1.3%–3.9%, which can meet the requirements of accurate and rapid determination of La and Ce in CMSX-4 nickel-based superalloy. © 2023, Youke Publishing Co.,Ltd. All rights reserved.  相似文献   
830.
An analytical method was developed using a solid phase extraction (SPE) cleanup and gas chromatography for detecting the residues of difenoconazole in Chinese cabbage and soil. The recovery and the relative standard deviation of this method in Chinese cabbage was 87.6-99.0%, 1.71-10.50%, respectively; in soil was 92.4-95.5%, 4.93-10.70%, respectively. Further degradation of difenoconazole residue in Chinese cabbage and soil was studied to evaluate residue behavior and environmental safety of difenoconazole. Degradation rate of difenoconazole in both Chinese cabbage and soil followed the first order kinetics with the half-lives of 6.6-7.8 and 54.2-55.0 days, respectively.  相似文献   
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