导向相应功率定位中时延不确定项的影响

在分布式传声器网络应用中,可控波束形成器导向相应功率(SRP)声源定位算法受到导向时延不准确的影响导致定位不稳定.将导向时延不确定项引入SRP定位模型,并对引起不确定项的主要干扰因素进行了分析建模,同时提出了应对导向时延不确定项的SRP定位算法.蒙特卡罗仿真和分析表明该算法具有抑制噪声和降低定位误差的效果,实际实验数据...     

Efficient estimation for semiparametric varying- coefficient partially linear regression models with current status data

This article considers a semiparametric varying-coefficient partially linear regression model with current status data. The semiparametric varying-coefficient partially linear regression model which is a generalization of the partially linear regression model and varying-coefficient regression model that allows one to explore the possibly nonlinear effect of a certain covariate on the response variable. A Sieve maximum likelihood estimation method is proposed and the asymptotic properties of the proposed estimators are discussed. Under some mild conditions, the estimators are shown to be strongly consistent. The convergence rate of the estimator for the unknown smooth function is obtained and the estimator for the unknown parameter is shown to be asymptotically efficient and normally distributed. Simulation studies are conducted to examine the small-sample properties of the proposed estimates and a real dataset is used to illustrate our approach.     

OPTIMAL CONVERGENCE RATES OF LANDAU EQUATION WITH EXTERNAL FORCING IN THE WHOLE SPACE

In this paper, we combine the method of constructing the compensating function introduced by Kawashima and the standard energy method for the study on the Landau equation with external forcing. Both the global existence of solutions near the time asymptotic states which are local Maxwellians and the optimal convergence rates are obtained. The method used here has its own advantage for this kind of studies because it does not involve the spectrum analysis of the corresponding linearized operator.     

TOBIT模型在医疗费用研究中的应用

对一般人群进行医疗费用调查研究时,会存在有相当一部分人的医疗费用支出为零,以此作为因变量使用经典的线性回归进行统计建模时将会导致估计值的偏差。本文尝试使用Tobit模型及其半参数估计方法解决因变量存在大量零删失数据的问题,通过对太原市城镇居民医疗费用相关影响因素调查数据的实证分析,用以为医疗费用控制和医疗保险制度改革提供更有效的统计学方法支持和政策依据。     

Smoothing Newton-Like Method for the Solution of Nonlinear Systems of Equalities and Inequalities

In this paper, we present a smoothing Newton-like method for solving non-linear systems of equalities and inequalities. By using the so-called max function, we transfer the inequalities into a system of semismooth equalities. Then a smoothing Newton-like method is proposed for solving the reformulated system, which only needs to solve one system of linear equations and to perform one line search at each iteration. The global and local quadratic convergence are studied under appropriate assumptions. Numerical examples show that the new approach is effective.     

A construction of fully diverse unitary space-time codes

Fully diverse unitary space-time codes are useful in multiantenna communications, especially in multiantenna differential modulation. Recently, two constructions of parametric fully diverse unitary space-time codes for three antennas system have been introduced. We propose a new construction method based on the constructions. In the present paper, fully diverse codes for systems of odd prime number antennas are obtained from this construction. Space-time codes from present construction are found to have bet...     

Symmetric and unsymmetric "dumbbells" of Ru2-alkynyl units via C-C bond formation reactions

Oxidative homocoupling (Glaser) reaction of Ru2 compounds bearing peripheral ethyne resulted in symmetric dimers. Cross-coupling (Sonogashira) reaction between Ru2 compounds bearing peripheral iodo and ethyne groups yielded an unsymmetric dimer. Voltammetric data indicated that Ru2 units in the symmetric dimers are noninteracting, and the unsymmetric dimer is best described as a weakly coupled push-pull compound.     

RNA-mediated synthesis of palladium nanoparticles on Au surfaces

RNA catalysts for the shape-controlled synthesis of Pd particles from the precursor complex trisdibenzylideneacetone dipalladium ([Pd2(DBA)3] were recently discovered in our laboratory (J. Am. Chem. Soc. 2005, 127, 17814-17818). In the work described here, RNA codes for hexagonal Pd platelets and Pd cubes were covalently immobilized on gold surfaces and evaluated for their activity toward particle synthesis. When coupled to gold via oligoethylene glycol linkers, both RNA sequences were able to catalyze the formation of Pd particles with the same shape control previously observed in solution. For low surface coverages, the average distance between RNA molecules on the surface was estimated at ca. 300 nm, yet large (e.g., dimensions of hundreds of nanometers) Pd hexagons and cubes still formed. This surprising result suggests that a single RNA molecule may be sufficient for nucleating and controlling the shapes of these particles. Finally, the use of surface-bound RNA as a tool for directing the orthogonal synthesis of materials on surfaces was demonstrated. Patterning the RNA code for Pd hexagons next to the code for Pd cubes, followed by incubation in a solution containing [Pd2(DBA)3], resulted in the spontaneous formation of spatially distinct spots of hexagonal and cubic particles.     

Dipolar control of monolayer morphology: spontaneous SAM patterning

A strategy for controlling relative placements of molecules within multicomponent monolayers at the solution-HOPG interface is demonstrated. The monolayers assemble from complementary pairs of 1,5-bis-alkyldiether-anthracenes bearing self-repelling side chains. Each diether side chain suffers repulsive dipolar interactions if it adsorbs next to an identical side chain in the morphology normally assumed by 1,5-bis-substituted-anthracene monolayers. Complementary side-chain pairs experience attractive dipolar interactions when adsorbed as neighbors in the normal morphology monolayer. The repulsive and attractive forces spontaneously drive formation of a patterned monolayer at the solution-HOPG interface. Each molecule adsorbs in its own row, sandwiched between two rows of the complementary anthracene. These studies demonstrate the viability of using weak dipolar interactions to control molecular placement and monolayer morphology and to pattern multicomponent monolayers.     

Complexation, structure, and superoxide dismutase activity of the imidazolate-bridged dinuclear copper moiety with beta-cyclodextrin and its guanidinium-containing derivative

An imidazolate-bridged homodinuclear complex, {[Cu(L)(H2O)]2(im)}(ClO4)3 (1), assembled with beta-cyclodextrin (betaCD) and its guanidinium-containing derivative (betaGCD), and thus a helical inclusion complex, {[Cu(L)(H2O)(betaCD)]2(im)}(ClO4)3 (2), were successfully isolated and structurally characterized. Structural analysis showed that each Cu(II) ion has a distorted square pyramidal N4Ow coordination sphere and forms a chiral chain through hydrogen-bonding and hydrophobic interactions. The UV-vis data showed that such a chain can provide the imidazolate bridge additional stability and results in the dissociation equilibrium taking place at the physiological pH. The obtained IC50 value for 2 (0.23 muM) showed a high superoxide dismutase (SOD) activity, which corresponds to a highly stable imidazolate bridge. Interestingly, the guanidinium-containing 1/betaGCD system showed higher SOD activity (IC50 = 0.16 muM), which is enhanced at least by 30% in comparison with that of guanidinium-lacking 2. This result supports that the positive guanidinium plays a role in the catalytic mechanism of Cu,Zn-SOD by ensuring that superoxide enters and peroxide leaves rapidly from the coordination sphere of the copper ion.