三维相位展开算法在精密运动测试中的应用

三维相位展开算法将基于空间的相位展开算法拓展到时间轴上,包含了一维时间和二维空间信息,适合于运动测试。通过建立一维时间相位展开算法的数学模型,分析了该算法运动测试的基本原理,讨论了在精密测试中的使用方法和适用范围,并对微谐振器的微结构进行运动测试。实验表明,算法在相位展开中引入时间信息,不仅消除了形变测量中需选取静止点为相位参考点或参考平面的限制,还可以同时测量物体表面某点纳米级的离面运动曲线和表面形变。     

激光辐照下皮肤组织光热响应有限元分析

为了更好地选择临床激光医疗曝光参量,采用有限元数值计算方法,模拟了脉冲激光与连续激光对人皮肤组织的光热作用及导致的温度变化效应,比较了两者的不同,得到了热响应时间及热弛豫时间与组织深度的关系,即组织越深(0～60 μm),其热响应时间(0～4 ms)与热弛豫时间(0.4～12.1 ms)越长;分析了激光脉宽长短对组织升温的影响;建立了评价脉冲间热损失的评价函数δ,并以此对脉冲间隔的选取作了探讨.     

Characterization and Bioavailability of Vitamin C Nanoliposomes Prepared by Film Evaporation-Dynamic High Pressure Microfluidization

Vitamin C nanoliposomes were prepared by combining a conventional method (film evaporation) with dynamic high pressure microfluidization. Their physicochemical characterizations (antioxidant activity, particle size, entrapment efficiency, morphology, in vitro drug release, and storage stability) and skin permeation behavior were investigated. The results showed that vitamin C nanoliposomes, having equivalent DPPH (2, 2-diphenyl-1-picrylhydrazyl) free radical scavenging capacity of pure vitamin C solution without loss of their biological activity, exhibited better storage stability at 37°C for 24 hours and at 4°C for 60 days, a more excellent sustained drug release as well as higher skin penetration rate than vitamin C liposomes.     

Chiral and water‐soluble poly(2‐oxazoline)s

We describe the synthesis and characterization of the first water‐soluble and chiral poly(2,4‐disubstituted‐2‐oxazoline)s. While poly(2,4‐dimethyl‐2‐oxazoline)s are water soluble up to 100 °C, aqueous solutions of poly(2‐ethyl‐4‐methly‐2‐oxazoline) exhibit a lower critical solution temperature. This is discussed in context with its constitutional isomers poly(2‐oxazoline)s and poly(2‐oxazine)s. Circular dichroism spectroscopy revealed strong Cotton effects, which are also responsive to temperature in aqueous solution. It is therefore hypothesized that structures, comparable to polyproline helices, are formed in aqueous solution. In contrast to polyproline, poly(2,4‐disubstituted‐2‐oxazoline)s are highly water soluble and therefore represent very interesting pseudo‐polypeptides that may be useful to develop responsive biomimetic biomaterials. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013     

Neutron diffraction study on composite compound Nd2Co7

The crystallographic and the magnetic structures of the composite compound Nd₂Co₇ at 300 K are investigated by a combined refinement of X-ray diffraction data and high-resolution neutron diffraction data. The compound crystallizes into a hexagonal Ce₂Ni₇-type structure and consists of alternately stacking MgZn₂-type NdCo₂ and CaCu₅-type NdCo₅ structural blocks along the c axis. A magnetic structure model with the moments of all atoms aligning along the c axis provides a satisfactory fitting to the neutron diffraction data and coincides with the easy magnetization direction revealed by the X-ray diffraction experiments on magnetically pre-aligned fine particles. The refinement results show that the derived atomic moments of the Co atoms vary in a range of 0.7 μ_B-1.1 μ_B and the atomic moment of Nd in the NdCo₅ slab is close to the theoretical moment of a free trivalent Nd³⁺ ion, whereas the atomic moment of Nd in the NdCo₂ slab is much smaller than the theoretical value for a free Nd³⁺ ion. The remarkable difference in the atomic moment of Nd atoms between different structural slabs at room temperature is explained in terms of the magnetic characteristics of the NdCo₂ and NdCo₅ compounds and the local chemical environments of the Nd atoms in different structural slabs of the Nd₂Co₇ compound.     

谐和与噪声联合作用下Duffing振子的安全盆分叉与混沌

研究了软弹簧Duffing振子在确定性谐和外力和有界随机噪声联合作用下，系统安全盆的侵蚀和混沌现象.推导出系统的随机Melnikov过程，根据Melnikov过程在均方意义上出现简单零点的条件给出了系统出现混沌的临界值，然后用数值模拟方法计算了系统的安全盆分叉点.结果表明，由于随机扰动的影响，系统的安全盆分叉点发生了偏移，并且使得混沌容易发生. 关键词： Duffing振子 安全盆 分叉 混沌     

The effect of intragranular microstress in Al2O3—SiC nanocomposites

A theoretical model is established to investigate the intragranular particle residual stress in Al2O3-SiC nanocomposites.Using this model,we calculate the average compressive stress on the Al2O3 grain boundary(GB) and the average tensile stress within Al2O3 grains caused by SiC nanoparticles.The normal compressive stress strengthens the GB,and the average tensile stress weakens the grains.The model gives a reasonable interpretation of the strength changes of Al2O3-SiC nanocomposites with the number of SiC particles.     

Composition heterogeneity of tetrafluoroethylene-hexafluoropropylene random copolymers characterized by successive self-nucleation and annealing

In the present work, successive self-nucleation and annealing (SSA) was applied to a series of tetrafluoroethylene-hexafluoropropylene random copolymers (FEPs). Multiple melting peaks were observed for all FEP samples after SSA thermal treatment. The lamellar crystal thicknesses were calculated from the melting temperatures, and the mass percentages of the crystals of specific thickness were obtained from the areas of the melting peaks. As a result, distributions of the lamellar thickness, which can be correlated to the composition distribution, were determined. It was found that the composition distribution of the FEP samples tended to become more heterogeneous as the content of hexafluoropropylene (HFP) comonomer increases. Samples with the same HFP content might also have different composition distributions.