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51.
A DC-set is a set defined by means of convex constraints and one additional inverse convex constraint. Given an arbitrary closed subsetM of the Euclideann-space, we show that there exists a DC-set in (n+1)-space being homeomorphic to the given setM. Secondly, for any fixedn2, we construct a compactn-dimensional manifold with boundary, which is a DC-set and which has arbitrarily large Betti-numbersr
k
fork n–2. 相似文献
52.
Ordered deuterium arrangements and order-disorder transformations of the tantalum deuterides in the range TaD0.50TaD0.78 have been studied by neutron diffraction and calorimetry at temperatures between ?170 and 120°C. In addition to the disordered phase (α), three ordered phases based on the superstructures Ta2D1+x (β1), Ta4D3, (γ), and TaD (δ) are clarified. The Ta2D1+x structure is a nonstoichiometric from of the Ta2D superstructure over the rangex < 0.5. The γ-phase is formed below ?70°C near Ta4D3, and transforms into theβ1and δ-phases, respectively, in the hypo and hyperstoichiometric compositions. The δ-phase that exists beyond TaD0.75 changes to the disordered α-phase around 100°C. 相似文献
53.
Okino T Hoashi Y Furukawa T Xu X Takemoto Y 《Journal of the American Chemical Society》2005,127(1):119-125
We synthesized a new class of bifunctional catalysts bearing a thiourea moiety and an amino group on a chiral scaffold. Among them, thiourea 1e bearing 3,5-bis(trifluoromethyl)benzene and dimethylamino groups was revealed to be highly efficient for the asymmetric Michael reaction of 1,3-dicarbonyl compounds to nitroolefins. Furthermore, we have developed a new synthetic route for (R)-(-)-baclofen and a chiral quaternary carbon center with high enantioselectivity by Michael reaction. In these reactions, we assumed that a thiourea moiety and an amino group of the catalyst activates a nitroolefin and a 1,3-dicarbonyl compound, respectively, to afford the Michael adduct with high enantio- and diastereoselectivity. 相似文献
54.
The first Ritter-type reaction of alkylbenzenes with nitriles has been successfully achieved by the use of N-hydroxyphthalimide (NHPI) as a key catalyst. Thus, treatment of ethylbenzene with ammonium hexanitratocerate(IV) (CAN) in the presence of a catalytic amount of NHPI in EtCN under argon produced the corresponding amide in good selectivity. 相似文献
55.
Nakashima Y Shimizu T Hirabayashi K Iwasaki F Yamasaki M Kamigata N 《The Journal of organic chemistry》2005,70(13):5020-5027
Optically active seleninate esters were obtained for the first time by chromatographic resolution on an optically active column. The absolute configurations of the optically active seleninate esters were determined by comparing their chiroptical properties with those of two analogous sulfinate esters, the absolute configuration of one of which is known and that of the other was determined by X-ray crystallographic analysis. The optically active seleninate esters were found to racemize in solution. Kinetic studies of the racemization, the oxygen exchange reaction with H(2)(18)O, and theoretical studies clarified that the racemization of the optically active seleninate esters in solution proceeded via an achiral hypervalent selenurane intermediate that was formed by the reaction with water. The reaction of the optically active seleninate ester and the sulfinate ester having bulky substituents with Grignard reagents was found to proceed with the retention of stereochemistry to give an optically active selenoxide and sulfoxides, respectively. 相似文献
56.
M. Ito Y. Sakuragi Y. Hirabayashi 《The European Physical Journal A - Hadrons and Nuclei》1999,5(4):373-383
The nuclear reaction dynamics leading to the formation of recently discovered resonance in the mutual-02
+ channel of the 12C+12C inelastic scattering around E
c.m.≃ 32 MeV is studied in terms of the dynamic polarization potential (DPP) induced by the channel coupling among various excited states in 12C. The microscopic 3α cluster-model wave functions are used to generate the 12C−12C diagonal and coupling potentials in the double-folding model. It is found that DPP for the 02
++ 02
+ channel is an unusually strong attractive potential which even exceeds the zeroth-order folding-model potential of this channel
around the nuclear surface region and that the strong coupling between the 02
+ and 22
+ states is predominantly responsible for the unusual DPP in this channel. The effective potential, the sum of the original
folding-model potential and the attractive DPP, is found to generates resonance states in the same energy region as that of
the resonance states generated by the original folding-model potential but the former states are found to be higher-nodal
states having four additional radial nodes. Similar but more moderate property of DPP is also found in the entrance (elastic)
channel. These results suggest that the reaction dynamics of generating the resonance in the 12C(02
+) +12C(02
+) channel may rather differ from that of the simple crossing of the zeroth-order molecular band generated by the potentials
in the entrance and exit channels suggested by the standard band-crossing model.
Received: 17 December 1998 / Revised version: 1 March 1999 相似文献
57.
Deguchi K Ito H Baba T Hirabayashi A Nakagawa H Fumoto M Hinou H Nishimura S 《Rapid communications in mass spectrometry : RCM》2007,21(5):691-698
Structural analyses of various glycans attached to proteins and peptides are highly desirable for elucidating their biological roles. An approach based on mass spectrometry (MS) combining both collision-induced dissociation (CID) and electron-capture dissociation (ECD) in the positive- and negative-ion modes has been proposed as a simple and direct method of assigning an O-glycan without releasing it from the peptide and of determining the amino acid sequence of the peptide and glycosylation site. The instrument used is an electrospray ionization (ESI) linear ion trap (LIT) time-of-flight (TOF) mass spectrometer with tandem LITs for CID by He gas and ECD. The proposed approach was tested with two synthetic O-glycopeptides binding a sialyl Lewis x (sLe(x)) oligosaccharide and a 3'-sialyl N-acetyllactosamine (3'-SLN) on a serine (S) residue. In the negative-ion mode, the CID MS(2) spectra of O-glycopeptides showed a relatively abundant glycoside-bond cleavage between the core N-acetylglucosamine (GlcNAc) and serine (S) that yields deprotonated C(3)-type fragment ions of O-glycan and deprotonated Z(0)-type peptide ions. The structure of the sLe(x) (3'-SLN) oligosaccharide was simply assigned by comparing the CID MS(3) spectrum derived from the C(3)-type fragment ion with the CID MS(2) spectra of the sLe(x) and sLe(a) (3'- and 6'-SLN) standards (i.e., negative-ion MS(n) spectral matching). The amino acid sequence of the peptide including the glycosylation site was determined from the ECD MS(2) spectrum in the positive-ion mode. 相似文献
58.
Mizokawa T Kim C Shen ZX Ino A Yoshida T Fujimori A Goto M Eisaki H Uchida S Tagami M Yoshida K Rykov AI Siohara Y Tomimoto K Tajima S Yamada Y Horii S Yamada N Yamada Y Hirabayashi I 《Physical review letters》2000,85(22):4779-4782
We compare the angle-resolved photoemission spectra of the hole-doped Cu-O chains in PrBa2Cu3O7 (Pr123) and in PrBa2Cu4O8 (Pr124). While, in Pr123, a dispersive feature from the chain takes a band maximum at k(b) (momentum along the chain) approximately pi/4 and loses its spectral weight around the Fermi level, it reaches the Fermi level at k(b) approximately pi/4 in Pr124. Although the chains in Pr123 and Pr124 are approximately 1/4 filled, they show contrasting behaviors: While the chains in Pr123 have an instability to charge ordering, those in Pr124 avoid it and show an interesting spectral feature of a metallic coupled-chain system. 相似文献
59.
K. Morigaki I. Hirabayashi M. Nakayama S. Nitta K. Shimakawa 《Solid State Communications》1980,33(8):851-856
Fatigue in the luminescence was observed in glow discharge amorphous silicon at 4.2 K and 77 K. This fatigue was not recovered by infra-red illumination, but by heating the sample at higher temperatures. These results are interpreted in terms of enhancement of non-radiative recombination associated with dangling bonds created by high optical excitation. 相似文献
60.