全文获取类型
收费全文 | 1056篇 |
免费 | 18篇 |
国内免费 | 3篇 |
专业分类
化学 | 719篇 |
晶体学 | 11篇 |
力学 | 5篇 |
数学 | 75篇 |
物理学 | 267篇 |
出版年
2023年 | 6篇 |
2022年 | 7篇 |
2021年 | 6篇 |
2020年 | 4篇 |
2019年 | 15篇 |
2018年 | 7篇 |
2017年 | 4篇 |
2016年 | 13篇 |
2015年 | 16篇 |
2014年 | 13篇 |
2013年 | 51篇 |
2012年 | 26篇 |
2011年 | 71篇 |
2010年 | 30篇 |
2009年 | 35篇 |
2008年 | 57篇 |
2007年 | 55篇 |
2006年 | 28篇 |
2005年 | 54篇 |
2004年 | 48篇 |
2003年 | 51篇 |
2002年 | 39篇 |
2001年 | 31篇 |
2000年 | 23篇 |
1999年 | 9篇 |
1998年 | 6篇 |
1996年 | 22篇 |
1995年 | 16篇 |
1994年 | 14篇 |
1993年 | 15篇 |
1992年 | 13篇 |
1991年 | 13篇 |
1990年 | 11篇 |
1989年 | 10篇 |
1988年 | 12篇 |
1987年 | 13篇 |
1986年 | 19篇 |
1985年 | 29篇 |
1984年 | 24篇 |
1983年 | 10篇 |
1982年 | 15篇 |
1981年 | 14篇 |
1980年 | 14篇 |
1979年 | 24篇 |
1978年 | 12篇 |
1977年 | 23篇 |
1976年 | 14篇 |
1975年 | 9篇 |
1973年 | 8篇 |
1967年 | 4篇 |
排序方式: 共有1077条查询结果,搜索用时 0 毫秒
11.
Tricyclo[3.3.1.1]decanone azine ( adamantanone azine ) reacts with 4-substituted 1,2,4-triazoline-3,5-diones under elimination of diazo adamantane to give a 1,3-dipole ( “azomethinimine” ), which on treatment with dipolahophiles affords the [ 2 + 3] -cycloadducts. The reaction is compared with singlet oxygen oxidation. 相似文献
12.
Affinity of many inorganic compounds for the malignant tumor was examined, using the rats which were subcutaneously transplanted with Yoshida sarcoma. And the relations between the uptake rate into the malignant tumor and in vitro binding power to the protein were investigated in these compounds. In these experiments, the bipositive ions and anions had not affinity for the tumor tissue with a few exceptions. On the other hand, Hg, Au and Bi, which have strong binding power to the protein, showed high uptake rate into the malignant tumor. As Hg++, Au+ and Bi+++ are soft acids according to classification of Lewis acids, it was thought that these elements would bind strongly to soft base (R-SH, R-S-) present in the tumor tissue. In many hard acids (according to classification of Lewis acids), the uptake rate into the tumor was shown as a function of ionic potentials (valency/ionic radii) of the metal ions. It is presumed that the chemical bond of these hard acids in the tumor tissue is ionic bond to hard base (R-COO-, R-PO3(2-), R-SO3-, R-NH2). 相似文献
13.
The dielectric solvent effect on HCCH, HCNH and HCNC spin coupling constants in ethane, tetrachloroethane and trans N-methylformamide has been calculated by finite perturbation theory based on the INDO and CNDO/2 approximations incorporating solvaton theory. The available experimental data are interpreted using the calculated variations of spin coupling constants. The effect of dielectric constant on the general form of the Karplus relation is included in the finite perturbation calculations. 相似文献
14.
Shin-ichi Hirano Toshinobu Yogo Wataru Sakamoto Seiji Yamada Tomoyuki Nakamura Tomoe Yamammto Hiroyuki Ukai Kouichi Banno Tomoko Nakafuku Yukari Ando 《Journal of Sol-Gel Science and Technology》2003,26(1-3):35-41
Nano sized crystalline particles/polymer hybrids were synthesized form designed metal-organic precursors. The newly developed method is composed of the synthesis of organic matrix by polymerization and the in situ nucleation and growth of crystalline oxide particles in the organic matrix below 100°C. The design of metal-organic precursor modified with polymerizable ligand and the selection of reaction conditions does influence the size and crystallinity of ceramic particles in organic matrix. The nano-sized magnetic particle/polymer hybrid exhibits the interesting feature of superparamagnetism and quantum size effect. The crystalline particles of BaTiO3/, PbTiO3/, and KNbO3/polymer hybrids behave to be dielectric and show the typical electro-rheological behavior. 相似文献
15.
16.
Yasuhide Yukawa Hisao Morisaki Kiyoshi Tsuji Seung-Geon Kim Takashi Ando 《Tetrahedron letters》1981,22(51):5187-5190
The behavior of ion pairs in the trifluoroacetolysis of 2-arylethyl arenesulfonates was studied by means of tracer techniques with deuterium and oxygen-18. 相似文献
17.
Akira Ando 《Journal of fluorine chemistry》2005,126(5):765-770
Treatment of 2-chloro-3,3-difluoroprop-2-en-1-ol derivatives (2) with methanesulfonyl chloride in the presence of a base did not give the expected esters but 2-chloro-1,1-difluoroprop-2-enyl methanesulfonates (4) through a novel [3,3] sigmatropic rearrangement. Reaction of 4 with diethylzinc in the presence of tetrakis(triphenylphosphine) palladium gave 1-alkyl- or 1-aryl-2-chloro-3-fluoropenta-1,3-dienes in moderate to good yields through a CC bond formation followed by dehydrofluorination. 相似文献
18.
J Holinej H Y Ando J W Snow 《Journal of chemical information and computer sciences》1989,29(4):233-236
Buffer changes and certain drugs cause temperature shifts, amplitude changes, and transition broadening in the differential scanning calorimetric (DSC) analysis of erythrocyte membranes. However, it has been difficult to interpret and quantitate these shifts and changes because the scans are composed of multiple overlapping transitions and because more than one transition may be simultaneously affected. An empirical approach has been developed by using Gaussian modeling to resolve these calorimetric transitions. Data analysis was carried out on a microcomputer using a nonlinear regression program (PCNONLIN) to fit the data scans. These results show that changes in the calorimetric scans of erythrocyte membranes due to alterations in the buffer environment, such as pH and osmolarity, can be resolved by fitting the data scans with the proposed mathematical model and optimizing the resolution parameters with PCNONLIN. In addition, resolution uncovered hidden characteristics that may not have been readily evident. Under certain conditions, for example, apparent transition shifts were shown to actually be amplitude changes and transition broadening. Determination of the limitations and validity of this method was accomplished with simulation studies. This technique offers a simple means for fitting overlapping DSC transitions by use of a commercially available nonlinear regression program that can be run on a microcomputer. 相似文献
19.
The most widely used method for qualitative and quantitative analysis of carbonyl compounds is the 2,4-dinitrophenylhydrazine method through the formation of 2,4-dinitrophenylhydrazone derivatives. However, this method may cause an analytical error because 2,4-dinitrophenylhydrazones have both E- and Z-stereoisomers. Purified aldehyde-2,4-dinitrophenylhydrazone demonstrated only the E-isomer. However under UV irradiation and the addition of acid, both E- and Z-isomers were seen. The spectral patterns of Z-isomers were different from those of E-isomers and the absorption maximum wavelengths were shifted towards shorter wavelengths by 5-8 nm. An equilibrium Z/E isomer ratio was observed in 0.02-0.2% (v/v) phosphoric acid solutions. In the case of acetaldehyde- and propanal-2,4-dinitrophenylhydrazones, the equilibrium Z/E isomer ratios were 0.32 and 0.14, respectively. However, when irradiated with ultraviolet light at 364 nm, the isomer ratios were increased beyond this constant ratio and reached 0.55 and 0.33, respectively. Zero-order rates for decreases of aldehyde derivatives were observed under UV irradiation (364 nm), however the decreases of concentration were not observed in phosphoric acid solutions. The best method for the determination of aldehyde-2,4-dinitrophenylhydrazones by HPLC is to add phosphoric acid to both the sample and the standard solution, to form a 0.02-1% acid solution. 相似文献
20.
Silylcarbenes are generated by the pyrolysis of 1,1-bis(trimethylsilyl)-1-alkanols with elimination of trimethylsilanol. 相似文献