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201.
Konno T Chae J Tanaka T Ishihara T Yamanaka H 《Chemical communications (Cambridge, England)》2004,(6):690-691
The one-pot synthesis of trisubstituted alkenes starting from fluoroalkylated internal alkynes was investigated. Hydroboration of the alkynes proceeded in a highly regio- and stereoselective manner to give the corresponding vinylboranes in excellent yields. Without isolation, treatment of the vinylboranes with various aryl halides under the Suzuki-Miyaura cross-coupling conditions gave the fluoroalkylated trisubstituted alkenes in high yields with complete retention of the olefinic geometry. 相似文献
202.
Imahori H Kimura M Hosomizu K Sato T Ahn TK Kim SK Kim D Nishimura Y Yamazaki I Araki Y Ito O Fukuzumi S 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(20):5111-5122
Systematic series of indium tin oxide (ITO) electrodes modified covalently with self-assembled monolayers (SAMs) of ferrocene-porphyrin-fullerene triads and porphyrin-fullerene dyads were designed to gain valuable insight into the development of molecular photovoltaic devices. The structures of SAMs on ITO have been investigated by UV/Vis absorption spectroscopy, atomic force microscopy, and cyclic voltammetry. The photoelectrochemical and photophysical (fluorescence lifetime and time-resolved transient absorption) properties were also determined. The highest quantum yield of photocurrent generation (11 %) among donor-acceptor linked systems which are covalently attached to the surface of ITO electrodes was achieved with SAMs of ferrocene-zinc porphyrin-fullerene linked triad on ITO electrodes. The quantum yields of photocurrent generation correlate well with the charge-separation efficiency and the lifetime of the charge-separated state of the porphyrin-fullerene linked systems in solution. These results provide valuable information for the construction of photonic molecular devices and artificial photosynthetic systems on ITO electrodes. 相似文献
203.
204.
Imahori H Liu JC Hosomizu K Sato T Mori Y Hotta H Matano Y Araki Y Ito O Maruyama N Fujita S 《Chemical communications (Cambridge, England)》2004,(18):2066-2067
A hydrogen bonding effect on photocurrent generation has been evaluated successfully in a mixed film of porphyrin and fullerene with hydrogen bonding on an ITO electrode, which exhibits efficient cathodic photocurrent generation as compared to the reference system without hydrogen bonding. 相似文献
205.
Ooe M Murata M Mizugaki T Ebitani K Kaneda K 《Journal of the American Chemical Society》2004,126(6):1604-1605
Dendrimers are well-defined and highly branched macromolecules. By utilizing their capsular architectures, dendrimers encapsulating various catalytically active species can be prepared, which often bring about unique catalysis. Treatment of the alkylated PPI dendrimer with 4-diphenylphosphinobenzoic acid and [PdCl(C3H5)]2 afforded the dendrimer-encapsulated Pd complex using ionic interactions. The dendrimers encapsulating Pd complexes acted as unique supramolecular catalysts for the Heck reaction and allylic amination. The specific nanoenvironment created by the dense amino groups inside the dendrimers can provide high catalytic activity and stability for the Pd complexes. Facile recovery of the dendritic catalysts could be achieved by thermomorphic systems. 相似文献
206.
Rahmiana Zein Edison Munaf Toyohide Takeuchi Tomoo Miwa 《Analytical and bioanalytical chemistry》1997,357(4):466-468
Microcolumn ion chromatography of inorganic anions has been studied using octadecylsilica immobilized with bovine serum albumin
as a stationary phase. The analytes were monitored with a conductivity detector. The detection limits for chloride, nitrate
and thiocyanate at S/N = 3 were 0.8, 1.0 and 3.0 μmol L–1, respectively. The present system was applied to the determination of inorganic anions in tap water and serum samples.
Received: 29 May 1996 / Accepted: 12 August 1996 相似文献
207.
Mori K Hara T Mizugaki T Ebitani K Kaneda K 《Journal of the American Chemical Society》2004,126(34):10657-10666
Treatment of a stoichiometric hydroxyapatite (HAP), Ca10(PO4)6(OH)2, with PdCl2(PhCN)2 gives a new type of palladium-grafted hydroxyapatite. Analysis by means of powder X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray (EDX), IR, and Pd K-edge X-ray absorption fine structure (XAFS) proves that a monomeric PdCl2 species is chemisorbed on the HAP surface, which is readily transformed into Pd nanoclusters with a narrow size distribution in the presence of alcohol. Nanoclustered Pd0 species can effectively promote the alcohol oxidation under an atmospheric O2 pressure, giving a remarkably high turnover number (TON) of up to 236,000 with an excellent turnover frequency (TOF) of approximately 9800 h(-1) for a 250-mmol-scale oxidation of 1-phenylethanol under solvent-free conditions. In addition to advantages such as a simple workup procedure and the ability to recycle the catalyst, the present Pd catalyst does not require additives to complete the catalytic cycle. The diameters of the generated Pd nanoclusters can be controlled upon acting on the alcohol substrates used. Oxidation of alcohols is proposed to occur primarily on low-coordination sites within a regular arrangement of the Pd nanocluster by performing calculations on the palladium crystallites. 相似文献
208.
Retention behavior of polycyclic aromatic hydrocarbons (PAHs) on an acridine derivative stationary phase was examined in microcolumn liquid chromatography. 3,6-Bis(dimethylamino)-10-dodecylacridinium was electrostatically introduced into a cation-exchanger, and its selectivity was compared with that of octadecylsilyl-bonded silica gel. The former stationary phase provided smaller retention for non-planar PAHs than that achieved by the latter stationary phase. The results suggest that interaction between PAHs and the acridinyl ring dominates the retention of PAHs, and preferential retention of planar PAHs is attributed to the fact that they have more chance to interact with the acridinyl ring of the stationary phase than non-planar PAHs. 相似文献
209.
Tomoo Yokoyama 《Topology and its Applications》2009,156(13):2220-2223
We show that there is a 1-dimensional (countable) non-spectral poset X such that for all x≠y∈X, ↑x∩↑y and ↓x∩↓y are finite subsets. On the other hand, we obtain some sufficient conditions for posets to be spectral. 相似文献
210.
We have measured the single intermolecular force of a typical photoionizable molecule, spirobenzopyran, by means of atomic force microscopy, which has proven to be useful in measuring directly single molecular forces. The spirobenzopyran moiety was immobilized covalently on both Au-coated probe tips and substrates by use of a self-assembled monolayer of a hexanethiol derivative incorporating a terminal spirobenzopyran moiety, 1'-(6'-mercaptohexyl)-3',3'-dimethylindolino-6-nitrospiro-(2H-1-benzopyran-2,2'-indoline). Force curve measurements were carried out using the spirobenzopyran-modified probe tip and substrate under dark conditions and in situ UV light irradiation. The adhesion force observed in a polar solvent (i.e., ethanol) was increased substantially under in situ UV light irradiation, which caused photoisomerization of the spirobenzopyran moiety bound to both tip and substrate from its electrically neutral spiropyran form to the corresponding zwitterionic merocyanine one. Statistical analyses of the observed force by autocorrelation technique have revealed that the photoionization enhanced by UV light caused a remarkable increase in the single intermolecular force of the photochromic compound. 相似文献