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101.
Isao Akiyama Masaya Ogawa Keiichi Takase Toshiyuki Takamuku Toshio Yamaguchi Norikazu Ohtori 《Journal of solution chemistry》2004,33(6-7):797-809
Molecular dynamics (MD) simulations and X-ray scattering experiments have been carried out on liquid 1-propanol. The radial distribution functions obtained from these two methods were in good agreement with each other. On the basis of the hydrogen-bond number and the angular correlation functions of the four sequentially hydrogen-bonded O atoms derived from the MD calculation, it was found that the hydrogen-bonded O atoms preferentially form a planar zigzag chain structure, but that the plane undulates like a wave. 相似文献
102.
SVG+Ajax+R: a new framework for WebGIS 总被引:1,自引:0,他引:1
Tomokazu Fujino 《Computational Statistics》2007,22(4):511-520
This paper first proposes a method of establishing a Web-based system that can visualize statistical data that are accompanied
by geographical information and analyze it interactively using dynamic graphics. In terms of the graphics format, our proposed
system uses XML-based 2D vector graphics, known as Scalable Vector Graphics (SVG). To install an enhanced interactive function,
we adopted a technique of server–client asynchronous communication using JavaScript, called Asynchronous JavaScript and XML
(Ajax) and R, which perform statistical analysis on the server side. This enables Web developers to construct a lightweight
system including statistical computing rapidly. Furthermore, many users get possible to utilize such data effectively and
efficiently anywhere anytime. The latter half of this paper introduces the WebGIS realized by this framework. We then discuss
the possibility and advantages of applying this new method to the dynamic graphics proposed previously. 相似文献
103.
N.-A. Noda Y. Takase T. Hamashima 《Archive of Applied Mechanics (Ingenieur Archiv)》2003,73(5-6):311-322
Summary To evaluate the mechanical strength of fiber-reinforced composites, it is necessary to consider singular stresses at the end of fibers because they cause crack initiation, propagation, and final failure. A square array of rectangular inclusions under longitudinal tension is considered in this paper. The body-force method is applied to a unit cell region. Then, the problem is formulated as a system of singular integral equations, where the unknown functions are the densities of body forces distributed in infinite plates having the same elastic constants as those of the matrix and inclusions. The unknown functions are expressed as piecewise-smooth functions using power series and two types of fundamental densities which express singular stresses. Generalized stress intensity factors at the corners of inclusions are systematically calculated with varying the shape and spacing of a square array of square and rectangular inclusions. 相似文献
104.
Tsubaki K Tanima D Nuruzzaman M Kusumoto T Fuji K Kawabata T 《The Journal of organic chemistry》2005,70(12):4609-4616
Various types of chiral host molecules 2-7 based on a phenolphthalein skeleton and two crown ethers were prepared for use in visual enantiomeric recognition, and we examined their enantioselective coloration in complexation with chiral amino acid derivatives 9-22 in methanol solution. Methyl-substituted host (S,S,S,S)-3 showed particularly prominent enantiomer selectivity for the alanine amide derivatives 11 and 12. A combination of methyl-substituted host (S,S,S,S)-3 with guest (R)-11 or (R)-12 developed a purple color, whereas no color development was observed with (S)-11 or (S)-12. On the other hand, phenyl-substituted host (S,S,S,S)-6 showed deeper coloration with a wide range of (S)-beta-amino alcohols compared to that seen with host (S,S,S,S)-6 and the corresponding (R)-beta-amino alcohols at 0 degrees C. Furthermore, absorbance inversion temperatures (AIT) were observed within the range of 0-50 degrees C in many cases. 相似文献
105.
In the present study, we prepared solid dispersions of the poorly water-soluble drug nitrendipine (NIT) using the twin screw extruder method with high-molecular-weight substances, hydroxypropylmethylcellulosephthalate (HPMCP) and Carbopol (CAR), as carriers. Powder X-ray diffraction (PXRD) and differential scanning calorimetry (DSC) evaluation showed that solid dispersions can be formed when NIT-HPMCP and NIT-CAR mixtures are treated with the twin screw extruder method. Fourier Transformation IR Spectroscopy (FT-IR) obtained with NIT-HPMCP and NIT-CAR solid dispersions indicated the presence of hydrogen bonding between the drug and the carriers. NIT-CAR solid dispersions were found to give somewhat higher dissolution than crystalline NIT and physical mixtures, while the dissolution of NIT-HPMCP solid dispersions was markedly decreased compared with the crystalline NIT and physical mixtures. These findings indicated that CAR has a greater ability to improve the dissolution of NIT than HPMCP when a twin screw extruder was employed to prepare the solid dispersions. The twin screw extruder method can be used as a simple and effective method for the preparation of solid dispersions to improve the dissolution properties of poorly water-soluble drugs when choosing proper polymers as carriers. 相似文献
106.
Shigehiro Takase Yoshikuni Itoh Itsuo Uchida Hirokazu Tanaka Hatsuo Aoki 《Tetrahedron letters》1985,26(7):847-850
Total synthesis of amauromine (), a novel alkaloid possessing two reversed prenyl groups in its molecule, was described. 相似文献
107.
Nakagawa M Nawa N Iyoda T 《Langmuir : the ACS journal of surfaces and colloids》2004,20(22):9844-9851
We demonstrated that the photopatterned single-layer adsorption film of poly(1-dodecyl-4-pyridinium bromide) on a silica surface was available for a template of nickel-phosphorus (Ni-P) electroless plating through sensitization with a SnCl(2) aqueous solution and activation with a PdCl(2) aqueous solution. Four kinds of poly(1-alkyl-4-vinylpyridinium halide)s bearing methyl, propyl, hexyl, and dodecyl groups were prepared. The cationic polymers were adsorbed by a negatively charged silica surface from their solutions, to form single-layer adsorption films exhibiting desorption-resistance toward deionized water and ethanol. The organic adsorption films could be decomposed completely by exposure to 172 nm deep-UV light. The formation and decomposition of the single-layer films were confirmed by deep-UV absorption spectral measurement and zeta-potential measurement. Ni-P electroless plating was carried out on the photopatterned adsorption films, using three types of SnO(x) colloidal materials without and with cationic or anionic surfactant as catalyst precursors in the sensitization step. In the case of the negatively charged SnO(x) colloids surrounded by anionic surfactant, Ni-deposition took place preferentially on the cationic adsorption films remaining in unexposed regions. The Ni-deposition was accelerated significantly on the cationic adsorption film bearing dodecyl groups. It was obvious by ICP-AES analyses that the hydrophobic long-chain dodecyl groups in the adsorption film could promote the adsorption of the negative SnO(x) colloids on the film surface, followed by much nucleus formation of zerovalent Pd catalysts useful for the electroless plating. The result of our experiment clearly showed that, in addition to electrostatic interaction, van der Waals interaction generating between the hydrophobic long-chain hydrocarbons of the adsorption film and the surfactant improved significantly the adsorption stability of the SnO(x) colloids, resulting in highly selective Ni-deposition in accord with the photopattern shape of the cationic single-layer adsorption film. 相似文献
108.
Koichi Takase 《manuscripta mathematica》1986,55(2):137-170
In this paper, we consider 1) the explicit formula of the trace of the Hecke operators acting on the space of the Hilbert cusp forms, and 2) the special values of the second L-functions attached to the Hilbert cusp forms. The method is that of Zagier[12], and the results of this paper are the generalization of his results to the case of the Hilbert modular forms for the congruence subgroup 0 (M). 相似文献
109.
Synthesis of gold nanoparticles from an organometallic compound in supercritical carbon dioxide 总被引:2,自引:0,他引:2
Esumi K Sarashina S Yoshimura T 《Langmuir : the ACS journal of surfaces and colloids》2004,20(13):5189-5191
This article presents the synthesis of gold nanoparticles in a single-phase supercritical fluid carbon dioxide solvent. The gold nanoparticles were formed by the reduction of triphenylphosphine gold(I) perfluorooctanoate with dimethylamineborane. Transmission electron microscopy, X-ray photoelectron spectroscopy, and UV-vis spectroscopy reveal the formation of gold nanoparticles of 1 nm in diameter. A high dispersion stability of the gold nanoparticles in supercritical carbon dioxide can be obtained by binding both triphenylphosphine and fluorocarbon ligands on the surface of the gold nanoparticles. 相似文献
110.
Takeuchi T Ugata S Masuda S Matsui J Yane T Takase M 《Organic & biomolecular chemistry》2004,2(18):2563-2566
Atrazine imprinted synthetic polymers were prepared using a combination of methacrylic acid and 2-sulfoethyl methacrylate that bound and converted atrazine and other 6-chlorotriazine herbicides to less toxic compounds. A chloride at the 6-position of the triazines was converted to a methoxy group by the polymer in a methanol-containing solvent, where the imprinting effects enhanced the catalytic activity. Competitive inhibition of the atrazine methanolysis was observed in the presence of a structurally related binder, ametryn, suggesting that the catalytic reaction proceeded in the binding sites generated by the molecular imprinting process. 相似文献