全文获取类型
收费全文 | 1028篇 |
免费 | 41篇 |
国内免费 | 4篇 |
专业分类
化学 | 784篇 |
晶体学 | 12篇 |
力学 | 10篇 |
数学 | 74篇 |
物理学 | 193篇 |
出版年
2022年 | 7篇 |
2021年 | 4篇 |
2020年 | 15篇 |
2019年 | 15篇 |
2018年 | 10篇 |
2016年 | 18篇 |
2015年 | 20篇 |
2014年 | 27篇 |
2013年 | 54篇 |
2012年 | 50篇 |
2011年 | 68篇 |
2010年 | 42篇 |
2009年 | 43篇 |
2008年 | 82篇 |
2007年 | 75篇 |
2006年 | 55篇 |
2005年 | 48篇 |
2004年 | 54篇 |
2003年 | 46篇 |
2002年 | 39篇 |
2001年 | 26篇 |
2000年 | 24篇 |
1999年 | 13篇 |
1998年 | 12篇 |
1997年 | 7篇 |
1996年 | 12篇 |
1995年 | 6篇 |
1994年 | 4篇 |
1993年 | 8篇 |
1992年 | 15篇 |
1991年 | 14篇 |
1990年 | 4篇 |
1989年 | 16篇 |
1988年 | 10篇 |
1986年 | 4篇 |
1985年 | 5篇 |
1984年 | 11篇 |
1983年 | 11篇 |
1982年 | 7篇 |
1981年 | 7篇 |
1978年 | 14篇 |
1977年 | 9篇 |
1976年 | 5篇 |
1975年 | 10篇 |
1974年 | 8篇 |
1973年 | 5篇 |
1972年 | 3篇 |
1970年 | 3篇 |
1968年 | 4篇 |
1966年 | 4篇 |
排序方式: 共有1073条查询结果,搜索用时 890 毫秒
81.
Spectroscopic Properties of Amine‐substituted Analogues of Firefly Luciferin and Oxyluciferin
下载免费PDF全文
![点击此处可从《Photochemistry and photobiology》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Michio Kakiuchi Soichiro Ito Minoru Yamaji Vadim R. Viviani Shojiro Maki Takashi Hirano 《Photochemistry and photobiology》2017,93(2):486-494
Spectroscopic and photophysical properties of firefly luciferin and oxyluciferin analogues with an amine substituent (NH2, NHMe and NMe2) at the C6' position were studied based on absorption and fluorescence measurements. Their π‐electronic properties were investigated by DFT and TD‐DFT calculations. These compounds showed fluorescence solvatochromism with good quantum yields. An increase in the electron‐donating strength of the substituent led to the bathochromic shift of the fluorescence maximum. The fluorescence maxima of the luciferin analogues and the corresponding oxyluciferin analogues in a solvent were well correlated with each other. Based on the obtained data, the polarity of a luciferase active site was explained. As a result, the maximum wavelength of bioluminescence for a luciferin analogue was readily predicted by measuring the photoluminescence of the luciferin analogue in place of that of the corresponding oxyluciferin analogue. 相似文献
82.
Metal-ion complexation of 7-benzylimidazo[1,2-a]pyrazin-3(7H)-one derivative (2) with Li+, Mg2+, Ca2+, Ba2+, Sc3+, and La3+ in acetonitrile resulted in successive modulations of its UV/vis absorption and fluorescence spectroscopic properties. This result indicates that 2 can be used as a colorimetric and fluorometric sensor of the Lewis acidity of a metal ion in aprotic solutions. The hypothesis that the metal-ion complex has a O10(imidazopyrazinone)-metal ion bond was supported by X-ray crystallographic analysis and quantum chemical calculations for a Li+ complex of 7-methylimidazo[1,2-a]pyrazin-3(7H)-one derivative (1). 相似文献
83.
Masashi Miyakawa Hidenori Hiramatsu Masahiro Hirano 《Journal of solid state chemistry》2010,183(2):385-391
Epitaxial growth and electron doping of 12CaO·7Al2O3 (C12A7) and 12SrO·7Al2O3 (S12A7) are reported. The C12A7 films were prepared on Y3Al5O12 (YAG) single-crystal substrates by pulsed laser deposition at room temperature and subsequent thermal crystallization. X-ray diffraction patterns revealed the films were grown epitaxially with the orientation relationship of (001)[100] C12A7 || (001)[100] YAG. For S12A7, pseudo-homoepitaxial growth was attained on the C12A7 epitaxial layer. Upon electron doping, metallic conduction was achieved in the C12A7 film and the S12A7/C12A7 double-layered films. Analyses of optical absorption spectra for the S12A7/C12A7 films provided the densities of free electrons in each layer separately. Hall measurements exhibited larger electron mobility in the S12A7/C12A7 film than those in C12A7 and S12A7 films, suggesting free electrons may be accumulated at the S12A7/C12A7 interface due presumably to a discontinuity of the cage conduction bands. 相似文献
84.
85.
We present a hierarchy of semidefinite programming (SDP) relaxations for solving the concave cost transportation problem (CCTP), which is known to be NP-hard, with p suppliers and q demanders. In particular, we study cases in which the cost function is quadratic or square-root concave. The key idea of our relaxation methods is in the change of variables to CCTPs, and due to this, we can construct SDP relaxations whose matrix variables are of size O((min {p, q}) ω ) in the relaxation order ω. The sequence of optimal values of SDP relaxations converges to the global minimum of the CCTP as the relaxation order ω goes to infinity. Furthermore, the size of the matrix variables can be reduced to O((min {p, q}) ω-1 ), ω ≥ 2 by using Reznick’s theorem. Numerical experiments were conducted to assess the performance of the relaxation methods. 相似文献
86.
87.
Tomohiro Hirano Kousuke Higashi Makiko Seno Tsuneyuki Sato 《Journal of polymer science. Part A, Polymer chemistry》2004,42(19):4895-4905
We have reported that intramolecular chain‐transfer reaction takes place in radical polymerization of itaconates at high temperatures and/or at low monomer concentrations. In this article, radical polymerizations of di‐n‐butyl itaconate (DBI) were carried out in toluene at 60 °C in the presence of amide compounds. The 13C‐NMR spectra of the obtained poly(DBI)s indicated that the intramolecular chain‐transfer reaction was suppressed as compared with in the absence of amide compounds. The NMR analysis of DBI and N‐ethylacetamide demonstrated both 1:1 complex and 1:2 complex were formed at 60 °C through a hydrogen‐bonding interaction. The ESR analysis of radical polymerization of diisopropyl itaconate (DiPI) was conducted in addition to the NMR analysis of the obtained poly(DiPI). It was suggested that the suppression of the intramolecular chain‐transfer reaction with the hydrogen‐bonding interaction was achieved by controlling the conformation of the side chain at the penultimate monomeric unit of the propagating radical with an isotactic stereosequence. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4895–4905, 2004 相似文献
88.
Nitrogen-rich heterocycles, bis(pyrazino[2′,3′:4,5]imidazole)-fused 1,2,5,6-tetrahydro-1,4,5,8,9,10-hexaazaanthracenes (BPI-HAAs) were prepared by conventional Pd(OAc)2/BINAP-catalyzed C-N coupling reactions of 5-aryl-3-bromoaminopyrazines. The BPI-HAA core is a planar structure with aromaticity, and this heterocycle exhibits red fluorescence and moderate electron-accepting characteristics. 相似文献
89.
90.
Masatoshi Hasegawa Daiki Hirano Mari Fujii Misako Haga Eiichiro Takezawa Shinya Yamaguchi Atsushi Ishikawa Takashi Kagayama 《Journal of polymer science. Part A, Polymer chemistry》2013,51(3):575-592
This work presents novel colorless polyimides (PIs) derived from 1R,2S,4S,5R‐cyclohexanetetracarboxylic dianhydride (H″‐PMDA). Isomer effects were also discussed by comparing with PI systems derived from conventional hydrogenated pyromellitic dianhydride, that is, 1S,2R,4S,5R‐cyclohexanetetracarboxylic dianhydride (H‐PMDA). H″‐PMDA was much more reactive with various diamines than H‐PMDA, and the former led to PI precursors with much higher molecular weights. The results can be explained from the quite different steric structures of these isomers. The thermally imidized H″‐PMDA‐based films were colorless regardless of diamines because of inhibited charge‐transfer interaction. In particular, the H″‐PMDA/4,4′‐oxydianiline system simultaneously achieved a very high Tg exceeding 300 °C, high toughness (elongation at break > 70%), and good solution processability. In contrast, the H‐PMDA‐based counterparts were essentially insoluble. The outstanding solubility of the former probably results from disturbed chain stacking by its nonplanar steric structure. An advantage of chemical imidization process is also proposed. In some cases, a copolymerization approach with an aromatic tetracarboxylic dianhydride was effective to improve the thermal expansion property. The results suggest that the H″‐PMDA‐based PI systems can be promising candidates for novel high‐temperature plastic substrate materials in electronic paper displays. A potential application as optical compensation film materials in liquid crystal displays (LCD) is also proposed in this work. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献