Synthesis and antimicrobial evaluation of some heterocyclic chalcone derivatives

Some new heterocyclic compounds containing isoxazole, pyrazole and oxadiazole ring systems were prepared from various chalcones. The synthesized compounds have been characterized by elemental analysis and spectral methods. These compounds were screened for their antimicrobial activities.     

Vesicle growth and deformation in a surfactant solution below the Krafft temperature

We have studied vesicle growth and deformation in aqueous solutions of nonionic surfactant C(16)E(7) below the Krafft temperature by means of an optical microscope. It has been found that vesicles become larger by fusing together, and that the growth rate is slower than that of the unilamellar vesicle or emulsion systems due to the multilamellar structures of shells in a vesicle. The deformation of the vesicles depends on the temperature quench depth, and we found the transformation from spherical vesicles to string-like domains at a certain quench-temperature. From the small angle X-ray scattering and confocal microscope experiments, it can be deduced that the deformation of vesicles would be induced by osmotic pressure due to the micellar concentration difference between inside and outside of vesicles.     

First-Principles Calculation of Lattice Dynamics of bcc and hcp Iron Under High Pressures

Lattice dynamics and electron-phonon coupling are calculated for non-magnetic hcp iron at 100 GPa by a first-principles linear response full-potential LMTO method. Superconducting transition temperature is estimated to be less than 0.5 K. For ferromagnetic bcc iron lattice dynamical calculations are performed for 9.8 GPa as well as for ambient pressure. The results of calculation reproduce well the pressure dependence of phonon dispersion curves observed by neutron scattering measurements.     

Application of metalloporphyrins and methylviologen-pendent iron porphyrin to reduction of diphenylsulfoxide

In the two-electron reduction of diphenylsulfoxide to diphenylsulfide, which is considered a model reaction of sulfite reduction catalyzed by sulfite reductase, methylviologen-pendent iron(III) porphyrin exhibits much higher catalytic activity than usual iron(III) and manganese(III) tetraphenylporphyrins, while cobalt(II) tetraphenylporphyrin exhibits much less catalytic activity than the others. Discussion about the active species and the reason of the acceleration by methylviologen-pendent is presented.     

Microwave preionization of the tokamak discharge at the electron cyclotron resonance

When ohmic heating power is applied during the microwave discharge at the electron cyclotron resonance, the plasma current and density build-up become fast and the loop voltage required to start the tokamak discharge decreases. The micro-wave burst observed in the initial stage is reduced and the burst of hard X-rays, occurring at the quasi-steady stage of discharge in the case of no microwave injection, disappears, suggesting that the production of run-away electrons is suppressed strongly.     

Construction of Some Optimal Ternary Linear Codes and the Uniqueness of [294, 6, 195; 3]-Codes Meeting the Griesmer Bound

Let n_q(k, d) denote the smallest value of n for which there exists an [n, k, d; q]-code. It is known (cf. (J. Combin. Inform. Syst. Sci.18, 1993, 161–191)) that (1) n₃(6, 195) {294, 295}, n₃(6, 194) {293, 294}, n₃(6, 193) {292, 293}, n₃(6, 192) {290, 291}, n₃(6, 191) {289, 290}, n₃(6, 165) {250, 251} and (2) there is a one-to-one correspondence between the set of all nonequivalent [294, 6, 195; 3]-codes meeting the Griesmer bound and the set of all {v₂ + 2v₃ + v₄, v₁ + 2v₂ + v₃; 5, 3}-minihypers, where v_i = (3ⁱ − 1)/(3 − 1) for any integer i ≥ 0. The purpose of this paper is to show that (1) n₃(6, 195) = 294, n₃(6, 194) = 293, n₃(6, 193) = 292, n₃(6, 192) = 290, n₃(6, 191) = 289, n₃(6, 165) = 250 and (2) a [294, 6, 195; 3]-code is unique up to equivalence using a characterization of the corresponding {v₂ + 2v₃ + v₄, v₁ + 2v₂ + v₃; 5, 3}-minihypers.