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451.
Density Functional Theory investigations on the insertion mechanism of phenylacetylene into metal-hydride bonds in bimetallic (Pt,Os) catalysts have been carried out. The results obtained have been also compared with the non-reactive monometallic (Os-based) system, to elucidate the cooperative effects and to explain the observed absence of reactivity. The identified reaction path involves phenylacetylene coordination followed by the insertion into the metal-hydride bond, leading to the formation of the experimentally observed products. Both steps do not require large energies compatible with the experimental conditions. The comparison with the reaction path for the monometallic species gives some hints on the cooperative effects due to the presence of the second metal which is related to its role in the CO release for creating a coordination site for phenylacetylene and not in the insertion energetics. The calculations provide a detailed analysis of the reaction complexity and provide a rationale for the efficiency of the process. 相似文献
452.
David Arcoya Lucio Boccardo Tommaso Leonori 《NoDEA : Nonlinear Differential Equations and Applications》2013,20(6):1741-1757
In this paper we deal with solutions of problems of the type $$\left\{\begin{array}{ll}-{\rm div} \Big(\frac{a(x)Du}{(1+|u|)^2} \Big)+u = \frac{b(x)|Du|^2}{(1+|u|)^3} +f \quad &{\rm in} \, \Omega,\\ u=0 &{\rm on} \partial \, \Omega, \end{array} \right.$$ where ${0 < \alpha \leq a(x) \leq \beta, |b(x)| \leq \gamma, \gamma > 0, f \in L^2 (\Omega)}$ and Ω is a bounded subset of ${\mathbb{R}^N}$ with N ≥ 3. We prove the existence of at least one solution for such a problem in the space ${W_{0}^{1, 1}(\Omega) \cap L^{2}(\Omega)}$ if the size of the lower order term satisfies a smallness condition when compared with the principal part of the operator. This kind of problems naturally appears when one looks for positive minima of a functional whose model is: $$J (v) = \frac{\alpha}{2} \int_{\Omega}\frac{|D v|^2}{(1 + |v|)^{2}} + \frac{12}{\int_{\Omega}|v|^2} - \int_{\Omega}f\,v , \quad f \in L^2(\Omega),$$ where in this case a(x) ≡ b(x) = α > 0. 相似文献
453.
Marcelli T van Maarseveen JH Hiemstra H 《Angewandte Chemie (International ed. in English)》2006,45(45):7496-7504
In the steadily expanding field of organocatalysis, cinchona alkaloids play a prominent role. Until the late 1990s, bifunctional catalysts based on this scaffold relied exclusively on the C9-hydroxy group as the hydrogen-bond donor. Recently, new cinchona catalysts have been developed that feature a phenolic OH group in the C6' position-a structural feature that allows a diverse set of reactions to be catalyzed in a highly stereoselective fashion. This Minireview describes the scope and modes of action of this new class of asymmetric bifunctional organocatalysts. 相似文献
454.
Mecca T Consoli GM Geraci C La Spina R Cunsolo F 《Organic & biomolecular chemistry》2006,4(20):3763-3768
A mutual induced fit mechanism is responsible for the exceptional complexation performances exhibited by calix[8]arene polycations towards heparin. The recognition process was studied in comparison with two other heparin antagonists: protamine and polylysine. The arrangement of multiple functional groups on the flexible macrocyclic scaffold of calix[8]arene, with respect to the conformationally rigid protamine and low ordered polylysine, allowed a mutual adaptability between calixarene polycations and heparin, significantly enhancing the recognition performances. Fluorescence, NMR titration, and activated partial thromboplastin time (aPTT) experiments confirmed that these calixarene derivatives have a very high specificity and affinity towards heparin neutralization as in aqueous solution as in blood. Analogous results were obtained with low molecular weight heparin (LMWH) whose effect protamine is unable to completely reverse. 相似文献
455.
Stener M Di Tommaso D Fronzoni G Decleva P Powis I 《The Journal of chemical physics》2006,124(2):024326
In the present work the photoelectron circular dichroism of camphor has been theoretically studied using B-spline and continuum multiple scattering-Xalpha methods, and comparisons are made with available experimental data. In general, rather large dichroism effects have been found for both valence and core (O 1s, C 1s) photoionizations. The agreement between the two calculations reported here and previous experimental measurements for core C 1s data is essentially quantitative. For valence ionization satisfactory agreement between theory and experiment has been obtained and the discrepancies have been attributed to both exchange-correlation potential limitations and the absence of response effects in the adopted formalism. The calculations predict, moreover, important features in the cross-section profiles, which have been discussed in terms of dipole-prepared continuum orbitals. 相似文献
456.
457.
Every 1‐rotational solution of a classic or twofold Oberwolfach problem (OP) of order n is generated by a suitable 2‐factor (starter) of or , respectively. It is shown that any starter of a twofold OP of order n gives rise to a starter of a classic OP of order (doubling construction). It is also shown that by suitably modifying the starter of a classic OP, one may obtain starters of some other OPs of the same order but having different parameters. The combination of these two constructions leads to lots of new infinite classes of solvable OPs. Still more classes can be obtained with the help of a third construction making use of the possible gracefulness of a graph whose connected components are cycles and at most one path. As one of the many applications, Hilton and Johnson's [J London Math Soc, 64 (2001) 513–522] bound about the solvability of OP is improved to in the case of r even. © 2012 Wiley Periodicals, Inc. J. Combin. Designs 20: 483‐503, 2012 相似文献
458.
Reineri F Viale A Ellena S Alberti D Boi T Giovenzana GB Gobetto R Premkumar SS Aime S 《Journal of the American Chemical Society》2012,134(27):11146-11152
(15)N-Propargylcholine has been synthesized and hydrogenated with para-H(2). Through the application of a field cycling procedure, parahydrogen spin order is transferred to the (15)N resonance. Among the different isomers formed upon hydrogenation of (15)N-propargylcholine, only the nontransposed derivative contributes to the observed N-15 enhanced emission signal. The parahydrogen-induced polarization factor is about 3000. The precise identification of the isomer responsible for the observed (15)N enhancement has been attained through a retro-INEPT ((15)N-(1)H) experiment. T(1) of the hyperpolarized (15)N resonance has been estimated to be ca. 150 s, i.e., similar to that reported for the parent propargylcholine (144 s). Experimental results are accompanied by theoretical calculations that stress the role of scalar coupling constants (J(HN) and J(HH)) and of the field dependence in the formation of the observed (15)N polarized signal. Insights into the good cellular uptake of the compound have been gained. 相似文献
459.
Tommaso Leonori Alessio Porretta 《Journal of Mathematical Analysis and Applications》2018,457(2):1492-1501
We prove a comparison principle for unbounded weak sub/super solutions of the equation where is a bounded coercive matrix with measurable ingredients, and has a super linear growth and is convex at infinity. We improve earlier results where the convexity of was required to hold globally. 相似文献
460.