库仑加线性位基态解析解

应用新发展的单一轨迹积分方法求解库仑加线性位的基态量子波函数,得到基态能量和波函数的一般解析表达式,并讨论了解的收敛性.应用此方法讨论了重夸克偶素系统.     

Measurement of high energy neutrons by fission reactions

In most high energy radiation fields, such as those encountered around accelerators or cosmic rays in the atmosphere, neutrons produce the largest percentage of the hadron dose. In these radiation fields, the neutron spectrum is typically formed by low energy neutrons (evaporation spectrum) and high energy neutrons (knock-on spectrum).

Neutron spectrometry and dosimetry are better understood for low energy neutrons (i.e. neutrons with energy below 20 MeV) than for those of higher energies. This paper reports the study of different detectors based on the registration of fission fragments of different heavy elements (namely bismuth, gold and tantalum), which have their principal response to high energy neutrons.     

Bismuth-fission detectors for high energy nucleons: II. Proton and neutron responses

A critical requirement for the ²⁰⁹Bi-fission detector is the knowledge of its response as a function of energy for both neutrons and protons. For this reason, stacks of ²⁰⁹Bi-fission detectors have been exposed to proton beams of 100 and 150 MeV at the Paul Sherrer Institute. Similar stacks have been exposed to neutron beams of 100 and 160 MeV at the Svedberg Laboratory from Uppsala University. The calibrations data with neutrons have been compared with those obtained with protons of the same energies. This comparison has proved that the response of ²⁰⁹Bi-fission detector for neutrons is two to three times smaller than that for protons at least in the range of nucleon energy up to 150 MeV.     

New dosimeters for solar-flare radiations

From the extensive investigations carried out since 1992 with the dosimetric ANPA-stack on 107 long-haul flights, it is possible to conclude that the cumulative dose per flight on a given route changes within less than 20% among different repeated routes, two different aircrafts (Boeings 747 and 767), and among different locations within the aircraft. In contrast to galactic cosmic rays, solar-flare radiation is totally unpredictable and extremely variable in terms of energy spectrum, intensity, direction, duration and starting time.

Most of the dosimetric systems used to date for the galactic cosmic rays may not be appropriate for solar-flare-radiation dosimetry. For this reason, different dosimetric systems have been investigated for both the retrospective and prospective dosimetry of solar flares. While waiting for the rare solar flare to occur, these dosimetric systems could be used for the validation of the computer-estimated route doses and/or for dosimetry in space, where frequent measurements of solar-flare events are needed.     

Cosmic rays and dosimetry at aviation altitudes

Recent concerns regarding the effects of the cosmic radiation field at aircraft altitudes on aircrew have resulted in a renewed interest in detailed measurements of the neutral and charged particle components in the atmosphere. CR-39 nuclear track detectors have been employed on a number of subsonic and supersonic aircraft to measure charge spectra and LET spectra at aircraft altitudes. These detectors are ideal for long term exposures required for these studies and their passive nature makes them suitable for an environment where interference with flight instrumentation could be a problem. We report here on measurements and analysis of short range tracks which were produced by high LET particles generated mainly by neutron interactions at aviation altitudes. In order to test the overall validity of the technique measurements were also carried out at the CERN-CEC field which simulates the radiation field at aviation altitudes and good agreement was found with dose values obtained using mainly heavy ion calibration.     

Heteropentanuclear Oxalato‐Bridged nd–4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis,Crystal Structures,Aqueous Stability and Antiproliferative Activity

A series of heteropentanuclear oxalate‐bridged Ru(NO)‐Ln (4d–4f) metal complexes of the general formula (nBu₄N)₅[Ln{RuCl₃(μ‐ox)(NO)}₄], where Ln=Y ( 2 ), Gd ( 3 ), Tb ( 4 ), Dy ( 5 ) and ox=oxalate anion, were obtained by treatment of (nBu₄N)₂[RuCl₃(ox)(NO)] ( 1 ) with the respective lanthanide salt in 4:1 molar ratio. The compounds were characterized by elemental analysis, IR spectroscopy, electrospray ionization (ESI) mass spectrometry, while 1 , 2 , and 5 were in addition analyzed by X‐ray crystallography, 1 by Ru K‐edge XAS and 1 and 2 by ¹³C NMR spectroscopy. X‐ray diffraction showed that in 2 and 5 four complex anions [RuCl₃(ox)(NO)]^2? are coordinated to Y^III and Dy^III, respectively, with formation of [Ln{RuCl₃(μ‐ox)(NO)}₄]^5? (Ln=Y, Dy). While Y^III is eight‐coordinate in 2 , Dy^III is nine‐coordinate in 5 , with an additional coordination of an EtOH molecule. The negative charge is counterbalanced by five nBu₄N⁺ ions present in the crystal structure. The stability of complexes 2 and 5 in aqueous medium was monitored by UV/Vis spectroscopy. The antiproliferative activity of ruthenium‐lanthanide complexes 2 – 5 were assayed in two human cancer cell lines (HeLa and A549) and in a noncancerous cell line (MRC‐5) and compared with those obtained for the previously reported Os(NO)‐Ln (5d–4f) analogues (nBu₄N)₅[Ln{OsCl₃(ox)(NO)}₄] (Ln=Y ( 6 ), Gd ( 7 ), Tb ( 8 ), Dy ( 9 )). Complexes 2 – 5 were found to be slightly more active than 1 in inhibiting the proliferation of HeLa and A549 cells, and significantly more cytotoxic than 5d–4f metal complexes 6 – 9 in terms of IC₅₀ values. The highest antiproliferative activity with IC₅₀ values of 20.0 and 22.4 μM was found for 4 in HeLa and A549 cell lines, respectively. These cytotoxicity results are in accord with the presented ICP‐MS data, indicating five‐ to eightfold greater accumulation of ruthenium versus osmium in human A549 cancer cells.     

Bismuth-fission detectors for high energy nucleons: I. Registration characteristics

There is considerable current interest in the detection of high energy nucleons around accelerators, spallation sources, and in cosmic rays. A detector that has its principal response at nucleon-energy above 50 MeV is provided by the fission of Bi-209. The problem of limited sensitivity has been solved by: a) spark counting large detector areas, b) reducing the detector background by special counting procedures, c) using many replicates of a thin track detector between two ²⁰⁹Bi-radiators. Finally, the registration efficiency has been evaluated and determined experimentally using proton beams with energies of 100, 150, and 250 MeV.     

Multi-biofunctional complexes combining antiseptic copper(II) with antibiotic sulfonamide ligands: Structural, redox and antibacterial study

Copper(II) and nickel(II) complexes of sulfadimethoxine, sulfadiazine, sulfamerazine and sulfamethazine were synthesized with a good yield according to an original procedure. These complexes were first characterized by single-crystal X-ray diffraction and electrochemistry. Structural inspections showed that the antibacterial entity of ligands remains non-coordinated to metal ions in the complex high-lighting the fact that in each cluster, antiseptic activity of the metal has been associated to the antibiotic activity of the ligand. In order to confirm this possibility, antibacterial activities of the complexes were studied on several bacteria. The antibacterial activity of the complex is as important as the ligands one with the addition of antiseptic activity via the incorporation of copper ions.