不同水胶比混凝土内部温湿度长期变化规律研究

鉴于混凝土内部温湿度显著影响混凝土耐久性, 为研究混凝土内部温湿度长期的变化规律, 将不同水胶比混凝土放置于室内大气环境中, 并测量其距离表面3cm、5cm、7cm及9cm处140d内温湿度的演变规律. 研究结果表明: 正常室温条件下, 混凝土内部温度变化主要受环境温度影响, 且与环境温度变化趋势基本相同, 浇筑完成7d后内部温度与环境温度温差大约为2℃, 60d以后内外温差基本消失. 高水灰比混凝土内部含水量充足, 140d内部相对湿度一直保持在85%以上; 低水灰比混凝土内部含水量较少, 早期相对湿度变化受水化耗水影响明显, 混凝土内部相对湿度存在明显梯度差, 5cm、7cm处相对湿度最低分别为60.18%和29.83%; 随着水化作用进行, 长期来看混凝土内部湿度逐步与环境湿度趋于一致.     

Complete stability of large order statistics

Fix an integerr1. For eachnr, letM _nr be the rth largest ofX ₁,...,X _n, where {X _n,n1} is a sequence of i.i.d. random variables. Necessary and sufficient conditions are given for the convergence of _n=r n P[|M _nr /a _n –1|<] for every >0, where {a _n} is a real sequence and –1. Moreover, it is shown that if this series converges for somer1 and some >–1, then it converges for everyr1 and every >–1.     

Rates of convergence for the stability of large order statistics

Forr1 and eachnr, letM _nr be therth largest ofX ₁,X ₂, ...,X _n , where {X _n ,n1} is an i.i.d. sequence. Necessary and sufficient conditions are presented for the convergence of for all >0 and some –1, where {a _n } is a real sequence. Furthermore, it is shown that this series converges for all >–1, allr1 and all >0 if it converges for some >–1, somer1 and all >0.     

Flow morphologies of two shock-accelerated unstable gas cylinders

Our highly reproducible shock-tube experiments examine the interaction of two unstable, compressible gas cylinders accelerated by a planar shock wave. Flow visualization shows that the evolution of the double-cylinder flow morphologies is dominated by two counter-rotating vortex pairs, the strength and behavior of which are observed to be highly sensitive to the initial cylinder separation. Simulations of the flow based on idealized vortex dynamics predict grossly different morphologies than those observed experimentally, suggesting that interactions at early time weaken the inner vortices. A correlation-based ensemble averaging procedure permits decomposition of the concentration field into mean and fluctuating components, providing evidence that energy is transferred from the intermediate to the small scales at late time.     

The Law of the Logarithm for Weighted Sums of Independent Random Variables

Let X,X _n ;n1 be a sequence of real-valued i.i.d. random variables with E(X)=0. Assume B(u) is positive, strictly increasing and regularly-varying at infinity with index 1/2<1. Set b _n =B(n),n1. If

纤维改性硫氧镁基仿木保温材料性能研究

为了提高硫氧镁基仿木保温材料的各项性能, 分别研究了相同长度的聚丙烯纤维(PPF)、聚乙烯醇纤维(PVAF)、玻璃纤维(GF)对其性能的影响. 结果表明: 随着纤维掺量的增加, 硫氧镁基仿木保温材料的流动性有所降低; GF对其抗压抗折强度的提高效果最明显, 其中GF掺量为1.0 kg·m^-3时早期抗压强度最高, PVAF掺量为0.5 kg·m^-3时其早期抗压强度最高; PPF明显提高了硫氧镁基仿木保温材料的耐水性, 其掺量为0.5 kg·m^-3时软化系数最大, 而GF掺量在1.0 kg·m^-3时, 浸水软化系数稍高于未加纤维的对比试件; 掺加PVAF后硫氧镁基保温材料的导热系数出现一定程度的降低, 其中PVAF掺量在1.5 kg·m^-3时其导热系数最低. GF和PPF可以明显地降低硫氧镁基仿木保温材料的收缩值, 其中GF降低自收缩效果较好, 而PPF可以明显地降低其干燥收缩值.     

Statistical theory for hydrogen bonding fluid system of A_aD_d type (I): The geometrical phase transition

The influence of hydrogen bonds on the physical and chemical properties of hydrogen bonding fluid system of AaDd type is investigated from two viewpoints by the principle of statistical mechanics. In detail, we proposed two new ways that can be used to obtain the equilibrium size distribution of the hydrogen bonding clusters, and derived the analytical expression of a relationship between the hydrogen bonding free energy and hydrogen bonding degree. For the nonlinear hydrogen bonding systems, it is shown that the sol-gel phase transition can take place under proper conditions, which is further proven to be a kind of geometrical phase transition rather than a thermodynamic one. Moreover, several problems associated with the geometrical phase transition and liquid-solid phase transition in nonlinear hydrogen bonding systems are discussed.     

光场横向效应导致CO2激光器混沌运转的实验研究

对横向效应导致单纵模多横模CO_2激光器失稳进行了实验研究.观测到了经各种途径到达的激光混沌态,并对其物理机制进行了探讨.     

A rapid screening procedure for 2-aminonaphthalene in natural,synthetic, and refined crudes

The mutagen, 2-aminonaphthalene, which is the dominant aromatic amine species in several fossil fuels, may be isolated readily by using a sequential high-performance liquid chromatographic procedure. An initial isolation is achieved on a semi-preparative scale aminosilane column and the final separation is completed with a nonpolar stationary phase column on an analytical scale with a pH-adjusted solvent. The use of fluorescence detection permits discrimination (at least 100-fold) against the nonmutagenic isomer, 1-aminonaphthalene. The overall recovery of 2-aminonaphthalene, as determined by scintillation counting of a radioactive 1-aminonaphthalene tracer, typically exceeds 50% and can reach 92% depending on both the sample matrix and the solubility of the isolate in acetonitrile. The minimum detectable quantity is 0.06 μg g^-1 of crude sample.