原子转移自由基聚合法合成磺胺类片段印迹聚合物及其表征

采用原子转移自由基聚合与片段印迹技术相结合的方法,以磺胺类物质的结构类似物4,6-二氯嘧啶为模板合成印迹聚合物。以4,6-二氯嘧啶(模板)︰甲基丙烯酸缩水甘油酯(功能单体)︰2,2′-联吡啶(配体)的摩尔比为10︰180︰1合成印迹聚合物。控制反应温度为60℃,反应时间为5h。印迹聚合物的吸附量为1.48mg/g,非印迹聚合物的吸附量为0.73mg/g。以合成的聚合物为新型材料,对样品中的兽药残留进行选择性分离、富集,结果表明印迹聚合物的选择吸附能力明显优于非印迹聚合物。通过电镜扫描对聚合物的表面形态进行了表征。     

异质Stackelberg寡头竞争下创新产品技术许可策略研究

基于异质产品Stackelberg寡头竞争模型,建立了拥有新产品创新技术在位厂商与潜在竞争对手间的技术许可博弈模型.模型中假设潜在竞争对手可以接受许可,也可通过自我研发创新技术进入市场参与竞争.根据潜在竞争对手研发成本的高低,研究了创新厂商的最优两部制收费策略.研究结果表明:潜在竞争者总会接受创新技术许可,最优许可策略依赖于研发成本、市场参数以及产品的替代系数.     

Rates of convergence for the stability of large order statistics

Forr1 and eachnr, letM _nr be therth largest ofX ₁,X ₂, ...,X _n , where {X _n ,n1} is an i.i.d. sequence. Necessary and sufficient conditions are presented for the convergence of for all >0 and some –1, where {a _n } is a real sequence. Furthermore, it is shown that this series converges for all >–1, allr1 and all >0 if it converges for some >–1, somer1 and all >0.     

光场横向效应导致CO2激光器混沌运转的实验研究

对横向效应导致单纵模多横模CO_2激光器失稳进行了实验研究.观测到了经各种途径到达的激光混沌态,并对其物理机制进行了探讨.     

A rapid screening procedure for 2-aminonaphthalene in natural,synthetic, and refined crudes

The mutagen, 2-aminonaphthalene, which is the dominant aromatic amine species in several fossil fuels, may be isolated readily by using a sequential high-performance liquid chromatographic procedure. An initial isolation is achieved on a semi-preparative scale aminosilane column and the final separation is completed with a nonpolar stationary phase column on an analytical scale with a pH-adjusted solvent. The use of fluorescence detection permits discrimination (at least 100-fold) against the nonmutagenic isomer, 1-aminonaphthalene. The overall recovery of 2-aminonaphthalene, as determined by scintillation counting of a radioactive 1-aminonaphthalene tracer, typically exceeds 50% and can reach 92% depending on both the sample matrix and the solubility of the isolate in acetonitrile. The minimum detectable quantity is 0.06 μg g^-1 of crude sample.     

cis-Dichloro {BIS-1-anti, 3-syn-(o-diphenylphosphino)phenyl-1-methallyl(1-3η) } rhodium(III): a chelate π-allylic complex formed by proton abstraction from an olefinic di-tertiary-phosphine)

The preparation, properties, and single crystal X-ray structure of the title complex,

are described.     

The Law of the Logarithm for Weighted Sums of Independent Random Variables

Let X,X _n ;n1 be a sequence of real-valued i.i.d. random variables with E(X)=0. Assume B(u) is positive, strictly increasing and regularly-varying at infinity with index 1/2<1. Set b _n =B(n),n1. If