新疆牛至挥发油化学成分的分析

气相色谱 -质谱技术对新疆牛至花和茎的挥发油化学成分进行分析研究。从牛至茎和花中分别鉴定了 4 2和 37种成分 ,占挥发油总量的 95 %以上 ,茎和花的挥发油化学成分相差很大     

镁基储氢合金的表面处理和表面催化

表面处理作为储氢合金性能改善的有效手段，近年来得到了很好的发展和应用，本文简要介绍了镁基储氢合金表面处理的主要方法及其对合金性能的影响。     

Complete stability of large order statistics

Fix an integerr1. For eachnr, letM _nr be the rth largest ofX ₁,...,X _n, where {X _n,n1} is a sequence of i.i.d. random variables. Necessary and sufficient conditions are given for the convergence of _n=r n P[|M _nr /a _n –1|<] for every >0, where {a _n} is a real sequence and –1. Moreover, it is shown that if this series converges for somer1 and some >–1, then it converges for everyr1 and every >–1.     

原子转移自由基聚合法合成磺胺类片段印迹聚合物及其表征

采用原子转移自由基聚合与片段印迹技术相结合的方法,以磺胺类物质的结构类似物4,6-二氯嘧啶为模板合成印迹聚合物。以4,6-二氯嘧啶(模板)︰甲基丙烯酸缩水甘油酯(功能单体)︰2,2'-联吡啶(配体)的摩尔比为10︰180︰1合成印迹聚合物。控制反应温度为60℃,反应时间为5 h。印迹聚合物的吸附量为1.48 mg/g,非印迹聚合物的吸附量为0.73 mg/g。以合成的聚合物为新型材料,对样品中的兽药残留进行选择性分离、富集,结果表明印迹聚合物的选择吸附能力明显优于非印迹聚合物。通过电镜扫描对聚合物的表面形态进行了表征。     

Rates of convergence for the stability of large order statistics

Forr1 and eachnr, letM _nr be therth largest ofX ₁,X ₂, ...,X _n , where {X _n ,n1} is an i.i.d. sequence. Necessary and sufficient conditions are presented for the convergence of for all >0 and some –1, where {a _n } is a real sequence. Furthermore, it is shown that this series converges for all >–1, allr1 and all >0 if it converges for some >–1, somer1 and all >0.     

Surface-relief diffraction gratings recorded by multiple-beam coherent phase exposure

Surface-relief hexagonal-array diffraction gratings have been produced by three-beam coherent exposure. Collimated light was used in an attempt to produce a uniform relief profile over the total area of a 7.6-cm plate coated with a positive photoresist. The resulting gratings were reproduced in nickel by an electroforming process and analyzed by atomic force microscopy. The topography of the gratings was found to be that predicted by theory. The results obtained show that the gratings were of uniform profile over their total area.     

A quadrature method for a class of strongly oscillatory infinite integrals

A constructive process is presented which leads to a class of quadrature formulas with any preassigned compound precision for the numerical integration of rapidly oscillating functions on (0, ) of the forme ^–x F(x, x), where is a large parameter andF(·,y) is periodic of period unity iny.1980 Mathematics Subject Classification, Primary 41A55, Scondary 41A60     

_f-A_aD_d氢键体系的统计特征

基于氢键的形成和缩聚反应机理在统计意义下的相似性,利用高分子反应统计理论和反应动力学理论对氢键溶液的一个模型体系进行了相关讨论.给出了体系的溶胶分数和发生溶胶-凝胶相变的条件,指出质子受体基团间的竞争作用对溶胶凝胶相变点的影响,进而讨论了体系的数量分布函数和相关问题.     

AB_3型超支化聚(酰胺-酯)的合成及缩聚动力学研究

采用丁二酸酐、三羟甲基氨基甲烷为主要原料 ,在冰水浴条件下 ,合成AB3型单体 ,然后进行熔融缩聚制得超支化聚 (酰胺 酯 ) ,没有出现凝胶现象 .采用Fourier变换红外谱仪 (FTIR)、粘度测试、端基分析等方法对其结构、特性粘数进行了表征 .同时对AB3型超支化聚 (酰胺 酯 )的缩聚反应动力学进行了研究 ,得出了130℃、14 0℃和 15 0℃时的缩聚反应速率常数 ,并进一步得出了缩聚反应活化能 .实验结果证明缩聚过程为自催化过程 ,且为三级反应