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111.
Murahashi S Imada Y Kawakami T Harada K Yonemushi Y Tomita N 《Journal of the American Chemical Society》2002,124(12):2888-2889
A chiral titanium complex, Ti(O-i-Pr)(4)/BINOL/tert-butylcatechol, catalyzes enantioselective addition reaction of ketene silyl acetals to nitrones to give optically active beta-amino acid derivatives which are biologically active compounds and useful synthetic intermediates of natural products and pharmaceuticals such as beta-lactam antibiotics. The combined process of catalytic oxidation of secondary amines and enantioselective carbon-carbon bond formation of nitrones thus obtained with ketene silyl acetals provides a useful two-step method for the synthesis of optically active beta-amino acid derivatives and related nitrogen compounds. 相似文献
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S. Tomita M. Kato K. Maki 《Physica C: Superconductivity and its Applications》2009,469(15-20):1074-1076
For analyzing the checker-board like modulation of the local density of states (LDOS) around a vortex observed in the slightly overdoped Bi2Sr2CaCu2Ox, we examined the effect of pseudogap state of high-Tc superconductors to the LDOS around the vortex. We first derived the Bogoliubov-de Gennes equation for d-wave superconductivity (d-SC) in the presence of d-spin density wave (d-SDW). Using the Fourier–Bessel expansion, we solved this equation for a single vortex state, numerically. We found that the peak of the bound states around E = 0 becomes small and modulation of the LDOS is observed for larger d-SDW order parameter. 相似文献
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Jiro Tsuji Yuichi Kobayashi Hideaki Kataoka Takashi Takahashi 《Tetrahedron letters》1980,21(35):3393-3394
2-Substituted 2-alkoxycarbonyl-3-vinylcyclopentanones (2), easily prepared by the palladium-catalyzed cyclization of 2-substituted 3-oxo-8-phenoxy-6-octenoates (1), are very suitable building blocks for CD rings of steroids, bearing particularly a functionalized 18-methyl group. 相似文献
117.
External periodic modulation of a nonlinear oscillator may lead to a chaotic output behaviour. This phenomenon is attributed to the existence of a strange attractor, which embodies essentially a folding motion as is met in Bernoulli shift or the Baker's transformation. 相似文献
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A simple Raman probe was realized using a single flexible hollow waveguide (HW). A HW coated with a silver film, which had reasonable transmission and little optical background noise, was used as a bidirectional transmission fiber for both the excitation and collection of Raman scattered light. The HW itself generated no Raman scattering or fluorescence noise during transmission. A complex filtering system at the end of the waveguide was thus unnecessary. In addition, the measured Raman spectra showed better signal-to-noise ratios than a conventional Raman fiber probe. The HW's suitability as a Raman fiber probe was also demonstrated. 相似文献
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