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I. A. Belogorokhov M. A. Dronov E. V. Tikhonov V. E. Pushkarev L. G. Tomilova D. R. Khokhlov 《JETP Letters》2010,91(11):607-610
The frequency dependences of the imaginary and real parts of the permittivity of organic semiconductors based on butyl-substituted erbium monophthalocyanine have been obtained. The static permittivity and damping factor, which characterizes the relaxation processes in the ensemble of phthalocyanine complexes, have been determined by fitting these dependences in the dipole approximation. 相似文献
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Selective synthesis of substituded europium triphthalocyanine on the base of dilithium 2,3,9,10,16,17,23,24-octa(cyclohexylmethoxy)phthalocyanine
was performed. The structure of the complex obtained was characterized by 1H NMR spectroscopy, mass spectrometry, and UV-visible spectroscopy. 相似文献
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I. P. Kalashnikova I. V. Zhukov L. G. Tomilova N. S. Zefirov 《Russian Chemical Bulletin》2005,54(9):2094-2098
Reactions of 4,5-dibenzyloxyphthalonitrile with salts of rare-earth elements afforded symmetrical lutetium, dysprosium, samarium,
and neodymium complexes with hexadecabenzyloxy(diphthalocyanine), which are well soluble in organic solvents. The spectroscopic
and electrochemical characteristics of the complexes obtained were studied.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2031–2035, September, 2005. 相似文献
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Alpatova N. M. Ovsyannikova E. V. Topolev V. V. Tomilova L. G. Kogan E. G. Berezina N. P. Bobrova L. P. Timofeev S. V. 《Russian Journal of Electrochemistry》2001,37(5):443-447
Anodic polymerization of aluminum tetraaminophthalocyanine chloride on conducting glasses in dimethyl formamide containing Bu4NBF4and the effect of cation exchanger MF4-SK on this process are studied. The polymer accumulation, monitored from optical absorption spectra, shows that introducing MF4-SK into solution or depositing it as a solid layer on the electrode accelerates the polymerization by a factor of four to six. 相似文献
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Magdesieva T. V. Zhukov I. V. Tomilova L. G. Korenchenko O. V. Kalashnikova I. P. Butin K. P. 《Russian Chemical Bulletin》2001,50(3):396-403
The electrochemical and spectroelectrochemical properties of several new rare-earth metal diphthalocyanine complexes with different substituents containing both electron-withdrawing and -donating substituents in the phthalocyanine rings were studied. The influence of structural modification of the phthalocyanine complexes (viz., the nature of the central metal atom and substituents in the phthalocyanine rings and the number of phthalocyanine rings in the complexes) on the total number of redox transitions, their potentials, and spectral characteristics of anionic and cationic forms of the complexes was examined. The potentials of the first anodic and cathodic redox transitions of the diphthalocyanine complexes are in a good linear correlation with the ionic radii of lanthanides. The potentials of the observed redox transitions of the complexes under study correlate well with the sums of Hammett constants for the substituents and the minimum molecular electrostatic potential of the benzene rings in the phthalocyanine moiety, which serves as a measure of electron perturbations introduced by the substituents. The revealed regularities allow the prediction of the redox properties and structure of rare-earth element diphthalocyanine complexes, which are redox-active in a specified potential range. 相似文献
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Structural modification of unsymmetrically substituted monophthalocyanines by nucleophilic reactions
New 2-nitro-substituted phthalocyanine zinc complexes were synthesized. The nucleophilic substitution of the NO2 group was used for the first time for the structural modification of unsymmetrically substituted monophthalocyanines. The
electronic absorption spectra of phthalocyanines were studied.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2036–2040, September, 2005. 相似文献
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Dudnik A. S. Ivanov A. V. Tomilova L. G. Zefirov N. S. 《Russian Journal of Coordination Chemistry》2004,30(2):110-114
Methods of synthesis of ruthenium tetra-tert-butylphthalocyaninate (Pc
t
Ru) were developed. The synthesis performed in both autoclave and in open system (in isoamyl alcohol in the presence (1,8-diazabicyclo[5,4,0]undecene) resulted in Pc
t
Ru() containing CO as axial ligand. When quinoline was used in the synthesis of Pc
t
Ru, the Pc
t
Ru(Iqnl)2 complex was obtained with two isoquinoline molecules (Iqnl) as axial ligands, which were detached consecutively in the course of thermogravimetric analysis. The compounds formed were studied by different physicochemical methods: electron, IR, and 1H NMR spectroscopies, MALDI-TOF mass spectroscopy, thermogravimetric and elemental analyses. 相似文献