全文获取类型
收费全文 | 2821篇 |
免费 | 208篇 |
国内免费 | 287篇 |
专业分类
化学 | 2023篇 |
晶体学 | 27篇 |
力学 | 91篇 |
综合类 | 30篇 |
数学 | 631篇 |
物理学 | 514篇 |
出版年
2023年 | 22篇 |
2022年 | 75篇 |
2021年 | 108篇 |
2020年 | 108篇 |
2019年 | 112篇 |
2018年 | 112篇 |
2017年 | 71篇 |
2016年 | 145篇 |
2015年 | 121篇 |
2014年 | 128篇 |
2013年 | 186篇 |
2012年 | 199篇 |
2011年 | 225篇 |
2010年 | 140篇 |
2009年 | 133篇 |
2008年 | 174篇 |
2007年 | 126篇 |
2006年 | 142篇 |
2005年 | 110篇 |
2004年 | 105篇 |
2003年 | 92篇 |
2002年 | 128篇 |
2001年 | 115篇 |
2000年 | 84篇 |
1999年 | 57篇 |
1998年 | 32篇 |
1997年 | 28篇 |
1996年 | 22篇 |
1995年 | 23篇 |
1994年 | 24篇 |
1993年 | 16篇 |
1992年 | 17篇 |
1991年 | 20篇 |
1990年 | 16篇 |
1989年 | 13篇 |
1988年 | 11篇 |
1987年 | 4篇 |
1986年 | 6篇 |
1985年 | 12篇 |
1984年 | 10篇 |
1983年 | 12篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1979年 | 5篇 |
1976年 | 5篇 |
1975年 | 2篇 |
1971年 | 2篇 |
1967年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有3316条查询结果,搜索用时 15 毫秒
41.
Ming Xian LIU Li Hua GAN Gen CHEN Zi Jie XU Zhi Xian HAO Long Wu CHEN 《中国化学快报》2006,17(8):1085-1088
Recently the research on structures with an ordered two-dimensional(2D) pattern has attracted great attention due to its versatile applications in the fields of microelectronic and optoelectronic devices, displays, biochips and sensors, enzymatic immobilization, drug carriers, and photonic band gap materials. Various well-arrayed 2D structures have been made by the modern technique such as laser writing pattern fabrication, photoetching technique, micro-electromechanical systems based on scann… 相似文献
42.
Tomasz Klis Sergiusz Lulinski Janusz Serwatowski 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(3):o145-o146
The molecule of the title compound, 2,3‐F2‐4‐(CHO)C6H2B(OH)2 or C7H5BF2O3, contains a formyl group coplanar with the benzene ring. The boronic acid group is twisted with respect to the benzene ring plane. The molecules are organized into infinite chains via intermolecular O—H⋯O hydrogen bonds. These chains are additionally connected via strong O—H⋯O hydrogen bonds, producing a folded layer structure perpendicular to the a axis. These layers are paired due to B⋯F interactions. 相似文献
43.
Cheng-Ting Zi Liu Yang Fa-Wu Dong Qing-Hua Kong Zhong-Tao Ding Jun Zhou 《Natural product research》2020,34(16):2301-2309
Abstract Two new compounds (9 and 10) having a camptothecin (CPT) analog conjugated to the 4β-azido-4-deoxypodophyllotixin analog by untilizing the copper-catalyzed azide-alkyne cycloadditon (CuAAC) reaction, and were evaluated for their cytotoxicity against a panel of five human cancer cell lines (HL-60, SMMC-7721, A-549, MCF-7 and SW480) using the MTT (3-(4,5-dimethyl-thiahiazo-2-yl)-2,5-diphenyltetrazolium bromide) assay. Two novel conjugates shown weak cytotoxicity, compound 10 showed highly potent against HL-60 cell line tested, with IC50 value 17.69?±?0.19?μM. This compound suggested its potential as anticancer agents for further development. 相似文献
44.
SO_4~(2-)/ZrO_2超强酸制备方法的改进 总被引:1,自引:0,他引:1
用BET、XRD、流动指示剂法、化学分析、低温正丁烷异构化反应等手段研究了制备条件对ZrO2前驱体和SO/ZrO2超强酸性能的影响.实验结果表明,采用不同的制备条件,ZrO2前驱体的比表面可相差1.8倍,SO/ZrO2的酸强度相差约1000倍.SO/ZrO2的正丁烷异构化反应活性相差约300倍.ZrO2最高比表面可达245m2/g,SO/ZrO2酸强度为H0≤-1.60,20℃时SO/ZrO2正丁烷异构化反应速率常数为15.5×10-3h-1。 相似文献
45.
CO hydrogenation on tungsten carbides has been investigated.The methanation activitiesof tungsten carbides are comparable to that of supported Group VIII metal catalysts.Temperature-programmed thermal desorption spectra of CO on tungsten carbide show that CO is adsorbed non-dissociatively,and the surface—CO bond appears to be rather weak. 相似文献
46.
Kruk M Dufour B Celer EB Kowalewski T Jaroniec M Matyjaszewski K 《The journal of physical chemistry. B》2005,109(19):9216-9225
Mesoporous carbons were synthesized from polyacrylonitrile (PAN) using ordered and disordered mesoporous silica templates and were characterized using transmission electron microscopy (TEM), powder X-ray diffraction, nitrogen adsorption, and thermogravimetry. The pores of the silica templates were infiltrated with carbon precursor (PAN) via polymerization of acrylonitrile from initiation sites chemically bonded to the silica surface. This polymerization method is expected to allow for a uniform filling of the template with PAN and to minimize the introduction of nontemplated PAN, thus mitigating the formation of nontemplated carbon. PAN was stabilized by heating to 573 K under air and carbonized under N2 at 1073 K. The resulting carbons exhibited high total pore volumes (1.5-1.8 cm3 g(-1)), with a primary contribution of the mesopore volume and with relatively low microporosity. The carbons synthesized using mesoporous templates with a 2-dimensional hexagonal structure (SBA-15 silica) and a face-centered cubic structure (FDU-1 silica) exhibited narrow pore size distributions (PSDs), whereas the carbon synthesized using disordered silica gel template had broader PSD. TEM showed that the SBA-15-templated carbon was composed of arrays of long, straight, or curved nanorods aligned in 2-D hexagonal arrays. The carbon replica of FDU-1 silica appeared to be composed of ordered arrays of spheres. XRD provided evidence of some degree of ordering of graphene sheets in the carbon frameworks. Elemental analysis showed that the carbons contain an appreciable amount of nitrogen. The use of our novel infiltration method and PAN as a carbon precursor allowed us to obtain ordered mesoporous carbons (OMCs) with (i) very high mesopore volume, (ii) low microporosity, (iii) low secondary mesoporosity, (iv) large pore diameter (8-12 nm), and (v) semi-graphitic framework, which represent a desirable combination of features that has not been realized before for OMCs. 相似文献
47.
Designs, Codes and Cryptography - The problem of classifying linear systems of conics in projective planes dates back at least to Jordan, who classified pencils (one-dimensional systems) of conics... 相似文献
48.
49.
50.
JPC – Journal of Planar Chromatography – Modern TLC - A ten-component mixture of pesticides was applied to the edge of the layer in ‘frontal + elution’ mode for preliminary... 相似文献