首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   1983篇
  免费   20篇
  国内免费   15篇
化学   1054篇
晶体学   20篇
力学   65篇
数学   523篇
物理学   356篇
  2024年   6篇
  2023年   13篇
  2022年   86篇
  2021年   93篇
  2020年   76篇
  2019年   63篇
  2018年   72篇
  2017年   40篇
  2016年   88篇
  2015年   79篇
  2014年   82篇
  2013年   134篇
  2012年   125篇
  2011年   149篇
  2010年   102篇
  2009年   83篇
  2008年   100篇
  2007年   81篇
  2006年   92篇
  2005年   73篇
  2004年   67篇
  2003年   41篇
  2002年   55篇
  2001年   21篇
  2000年   24篇
  1999年   16篇
  1998年   13篇
  1997年   16篇
  1996年   16篇
  1995年   12篇
  1994年   12篇
  1993年   6篇
  1992年   7篇
  1991年   11篇
  1990年   9篇
  1989年   7篇
  1988年   7篇
  1986年   3篇
  1985年   4篇
  1984年   5篇
  1983年   5篇
  1981年   3篇
  1980年   3篇
  1979年   4篇
  1976年   4篇
  1974年   2篇
  1973年   1篇
  1971年   1篇
  1970年   1篇
  1967年   1篇
排序方式: 共有2018条查询结果,搜索用时 0 毫秒
981.
982.
983.
    
Atomic layer deposition (ALD) was used to fabricate transparent and conductive thin films of ZnO. Two hundred‐nano metre thick ZnO films were deposited on glass substrates at low growth temperatures varied between 120 and 240 °C. As zinc and oxygen precursors we used diethylzinc (DEZn) and deionized water, respectively. To find optimal film parameters, the structure, surface morphology, optical and electrical measurements were carried on. The films obtained at 200 °C show the highest carrier concentration (∼1020 cm−3) and the lowest resistivity (2 × 10−3 Ω cm). The films exhibit mobilities up to 37 cm2/Vs that we associate to the process technology used. An important point of our approach was that the films studied were not intentionally doped (with Al or other group III elements) but the high electrical conductivity was achieved by playing with the sample stoichiometry and growth conditions.  相似文献   
984.
    
Materials with unusual mechanical properties can be potentially used as matrices to create high‐performance lightweight composites. The appearance of materials with negative Poisson's ratio (auxetics), has led to the evaluation of auxetic composites for possible engineering applications. Because the experimental evaluation of composites with specific properties is expensive and time consuming, computational modelling and simulation provide efficient alternatives to predict the parameters of the composites. In this paper a finite element method was used to find the engineering constants (Young's modulus and Poisson's ratio) of auxetic composites consisting of concentric cylindrical inclusions made of combinations of auxetic and classic (non‐auxetic) materials. It has been observed that not only the mechanical properties of the different composite phases influence the effective mechanical properties of the whole composite, but also the location of the same material phases do matter.  相似文献   
985.
986.
    
We present a detailed explanation of the blue‐shift that is observed in Ga(As)Sb quantum dots (QD) with increasing pump power density by employing an 8‐band k · p model with the Coulomb attractive potential added into the Hamiltonian. Two types of structures are considered: Ga(As)Sb QDs in a GaAs matrix and the same dots overgrown with an InGaAs quantum well (QW). We show that with increasing charge density the electron and hole energy levels shift relative to each other, which results in an increase of the optical transition energy (i.e. a blue‐shift). The major contribution to the effect arises from the holes and is a result of their 3D confinement inside the dot. Additionally, with increasing charge density the electrons move closer to the dot, which improves the oscillator strength of the ground‐state optical transition. (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
987.
    
Modern small‐size vertical‐cavity surface‐emitting diode lasers (VCSELs) require principally fully vectorial optical modelling because their cavity sizes are of the order of the wavelength of emitted radiation. However, much simpler scalar approaches are often surprisingly exact even beyond the limits of their confirmed validity. Therefore, in the present paper, reasonable limits of an application of simplified scalar optical approaches (instead of more exact but also much more involved and time‐consuming rigorous vectorial ones) are determined to model threshold operation of possible nitride VCSELs equipped with tunnel junctions with the aid of a comparison of results of the scalar effective frequency method with those obtained using the fully vectorial three‐dimensional plane wave admittance method. Both these optical methods have been found to give usually quite close results for the fundamental transverse mode. Larger discrepancies between the results of both approaches have been found for first‐order transverse modes (and even larger are expected for higher‐order ones) and for larger (or very small) active regions. Some structural modifications of nitride VCSELs, which may enable their low‐threshold single‐fundamental‐mode room‐temperature continuous‐wave operation, are proposed. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
988.
    
We consider a model of a molecular junction made of BDT (benzene dithiol) molecule trapped between two Au(100) leads. Using the ab initio approach implemented in the SIESTA package we look for the optimal configurations of the molecule as a function of the distance between the leads. We find that for distances long enough the energy of the system is minimized when the molecule is bonded asymmetrically, i.e. chemisorbed to one of the leads, whereas for distances shorter than 12 Å the energy is minimized when the molecule sits in the middle between the leads. We discuss possible consequences of the above findings for the transport properties of the junction. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)  相似文献   
989.
    
In the present study we report on properties of ZnCoO films grown at relatively low temperature by the atomic layer deposition, using two reactive organic zinc precursors (dimethylzinc and diethylzinc). The use of these precursors allowed us the significant reduction of a growth temperature to below 300 °C. The influence of growth conditions on the Co distribution in ZnCoO films, their structure and magnetic properties was investigated using secondary ion mass spectroscopy, scanning electron microscopy, cathodoluminescence, energy dispersive X‐ray spectrometry (EDX), X‐ray diffraction and superconducting quantum interference device magnetometry. We achieved high uniformity of the films grown at 160 °C. Such films are paramagnetic. Films grown at 200 °C and at higher temperature are nonuniform. Formation of foreign phases in such films was detected using high resolution EDX method. These samples are not purely paramagnetic and show weak ferromagnetic response at low temperature.  相似文献   
990.
    
Substituent effects on the 13C NMR spectra of 4-aryl-2,6-diphenylpyrylium and 1-methyl-4-aryl-2,6-diphenylpyridinium perchlorates and 4-aryl-2,6-diphenylpyridines were investigated. The dual substituent parameter approach indicates that the resonance contribution to the carbon chemical shifts in the para position to the substituent in the 4-aryl moiety is comparable to that for 4-R-biphenyls. Although heterocyclic moieties jointed at the para position with respect to the substituent in the 4-aryl group differ in their deactivating power, they diminish the resonance term to the same extent in each series. This may result in conformational variations of the compounds studied. AM1 calculations were used to explain the chemical shifts observed.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号