全文获取类型
收费全文 | 2151篇 |
免费 | 65篇 |
国内免费 | 17篇 |
专业分类
化学 | 1249篇 |
晶体学 | 15篇 |
力学 | 74篇 |
数学 | 536篇 |
物理学 | 359篇 |
出版年
2023年 | 8篇 |
2022年 | 64篇 |
2021年 | 86篇 |
2020年 | 66篇 |
2019年 | 58篇 |
2018年 | 72篇 |
2017年 | 42篇 |
2016年 | 85篇 |
2015年 | 77篇 |
2014年 | 84篇 |
2013年 | 148篇 |
2012年 | 135篇 |
2011年 | 159篇 |
2010年 | 100篇 |
2009年 | 85篇 |
2008年 | 108篇 |
2007年 | 87篇 |
2006年 | 100篇 |
2005年 | 76篇 |
2004年 | 68篇 |
2003年 | 40篇 |
2002年 | 61篇 |
2001年 | 23篇 |
2000年 | 30篇 |
1999年 | 17篇 |
1998年 | 15篇 |
1997年 | 17篇 |
1996年 | 20篇 |
1995年 | 24篇 |
1994年 | 17篇 |
1993年 | 21篇 |
1992年 | 18篇 |
1991年 | 24篇 |
1990年 | 17篇 |
1989年 | 19篇 |
1988年 | 11篇 |
1987年 | 6篇 |
1986年 | 12篇 |
1985年 | 14篇 |
1984年 | 17篇 |
1983年 | 8篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 5篇 |
1976年 | 6篇 |
1970年 | 10篇 |
1969年 | 5篇 |
1968年 | 6篇 |
1967年 | 10篇 |
排序方式: 共有2233条查询结果,搜索用时 15 毫秒
11.
Tomasz Stawski Janusz Szklarzewicz Krzysztof Lewiński 《Transition Metal Chemistry》2006,31(3):353-361
The single crystal X-ray structure of (AsPh4)[W(bpy)(CN)6] is described. The structure of octa- and hepta-coordinated intermediates of substitutional photolysis of [Mo(CN)8]4− ion in aqueous media were determined by performing semi-empirical calculations. On the basis of obtained results as well
as on empirical data the photolysis scheme has been postulated. 相似文献
12.
Tomasz Rolski 《Probability Theory and Related Fields》1990,84(1):27-37
Summary We discuss in this paper a non-homogeneous Poisson process A driven by an almost periodic intensity function. We give the stationary version A
* and the Palm version A
0 corresponding to A
*. Let (T
i
,i) be the inter-point distance sequence in A and (T
i
0
,i) in A
0. We prove that forj, the sequence (T
i+j,i) converges in distribution to (T
i
0
,i). If the intensity function is periodic then the convergence is in variation. 相似文献
13.
Let (E, ¦·¦) be a uniformly convex Banach space with the modulus of uniform convexity of power type. Let be the convolution of the distribution of a random series inE with independent one-dimensional components and an arbitrary probability measure onE. Under some assumptions about the components and the smoothness of the norm we show that there exists a constant such that |{·<t}–{·+r<t}|r
q
, whereq depends on the properties of the norm. We specify it in the case ofL
spaces, >1. 相似文献
14.
Tomasz Rolski 《Queueing Systems》1989,4(1):17-26
We study single server periodic queues in the day equilibrium conditions. The following characteristics of interest are considered at time of dayt: Vp(t)-the work load, Lp(t)-the number of customers and up(t)-the departure rate. We give relationships between E[Vp(t)], E[Lp(t)] and up(t). We also prove that E[Vp(t)] < and E[Lp(t)] < provided the second moment of the service time is finite. 相似文献
15.
16.
Hiller W Brüll A Argyropoulos D Hoffmann E Pasch H 《Magnetic resonance in chemistry : MRC》2005,43(9):729-735
The application of HPLC-NMR for the analysis of a mixture of fatty alcohol ethoxylates (FAEs) is described. The use of the new generation, cryogenically cooled probes is investigated in respect of the sensitivity advantage that they provide. The FAE mixture is separated using liquid chromatography at the critical point of adsorption. The ability of the method to differentiate between the different end groups and the degree of polymerization of the mixture constituents is investigated. Both on-flow and stop-flow HPLC-NMR techniques were used together with two-dimensional NMR spectroscopy. The results are compared with those obtained by using an evaporative light scattering detector for the HPLC. 相似文献
17.
A method has been developed for species-selective analysis of organotin compounds in solid, biological samples. The procedure is based on accelerated solvent extraction (ASE) of analytes and includes extraction of the tin species with a methanol–water (90% methanol) solution of acetic acid/sodium acetate containing tropolone (0.03% w/v), their ethylation with NaBEt4, and separation and detection by GC–FPD. The analytical procedure was optimized with an unspiked sample of harbor porpoise (Phocoena phocoena) liver. Effects of ASE operational variables (extraction temperature and pressure, solvent composition, number of static extraction steps) are discussed. Method detection limits (MDL) were in the range 6–10 ng(Sn) g–1 dry weight and 7–17 ng(Sn) g–1 dry weight for butyl- and phenyltin compounds, respectively. Recoveries were comparable with or better than those obtained by use of other procedures reported in the literature. The analytical procedure was validated by analysis of NIES No. 11 (fish tissue) certified reference material. 相似文献
18.
Cédric Kalinski Michael Umkehrer Nadine Jäger Wolfgang Hiller 《Tetrahedron letters》2006,47(12):2041-2044
A combinatorial synthetic route yielding fused tetrazolo[1,5-a]quinoxalines is described. The use of 2-fluorophenylisocyanide in the Ugi-tetrazole reaction (tetrazole-U-4CR) followed by a nucleophilic aromatic substitution (SNAr) affords the tricylic tetrazolo[1,5-a]quinoxaline moiety in good yields and with high diversity. 相似文献
19.
The reaction of carbonyl-substituted phenylboronic acids with diethanolamine has been investigated. For compounds containing carbonyl groups at the meta or para positions the reaction occurs exclusively at the boronic acid. Different reactivities were observed for ortho-substituted acetyl- and formylphenylboronic acids where the reaction occurred at both the boronic acid and at the carbonyl group. X-ray studies revealed the presence of a polycyclic structure with tetravalent boron and nitrogen atoms. 相似文献
20.
Low molecular weight tri-podal biphenyl- and benzoate-type mesogens [C6H5C6H4O(CH2)5SiMe2CH2CH2SiMe2]3CH (4), [C11H23O(C6H4)2O(CH2)5SiMe2]3CH (5) and [MeOC6H4OC(O)C6H4O(CH2)5SiMe2]3CH (6) (C6H4 = 1,4-phenylene) were obtained, from branched silyl substituted methane precursors [CH2CH(Me)2Si]3CH (1) and (HMe2Si)3CH (2). The biphenyl-containing ones (4) and (5) were converted into terminal alkenes, which were subsequently hydrosilylated with poly(methylsiloxanes). The polymer derived from (5) exhibited mesomorphic properties. Such systems have the potential to significantly increase the density of liquid crystal rod-like structures in side chains of linear polymers (or dendritic liquid crystal polymers). 相似文献