The Steady State Fluctuation Relation for the Dissipation Function

We give a proof of transient fluctuation relations for the entropy production (dissipation function) in nonequilibrium systems, which is valid for most time reversible dynamics. We then consider the conditions under which a transient fluctuation relation yields a steady state fluctuation relation for driven nonequilibrium systems whose transients relax, producing a unique nonequilibrium steady state. Although the necessary and sufficient conditions for the production of a unique nonequilibrium steady state are unknown, if such a steady state exists, the generation of the steady state fluctuation relation from the transient relation is shown to be very general. It is essentially a consequence of time reversibility and of a form of decay of correlations in the dissipation, which is needed also for, e.g., the existence of transport coefficients. Because of this generality the resulting steady state fluctuation relation has the same degree of robustness as do equilibrium thermodynamic equalities. The steady state fluctuation relation for the dissipation stands in contrast with the one for the phase space compression factor, whose convergence is problematic, for systems close to equilibrium. We examine some model dynamics that have been considered previously, and show how they are described in the context of this work.     

Monte Carlo simulation of percolative phenomena in the cationic B-sublattice of spinels

The critical probability for the cationic B-sublattice in spinels has been calculated by the Monte Carlo technique as a function of the connectivity of the atomic octahedral sites.     

Boundedness of solutions of linear differential systems with periodic coefficients

Archive for Rational Mechanics and Analysis -     

Long-term evolution of mid-altitude quasi-satellite orbits

Quasi-satellite orbits are of great interest for the exploration of planetary moons because of their dynamical features and close proximity with respect to the surface of scientifically relevant objects like Phobos and Deimos. This paper explores the equations of the elliptical Hill problem, offering a new analytical insight into the long-term evolution of mid-altitude quasi-satellite orbits. Our developments are based on the Yamanaka–Ankersen solution of the Tschauner–Hempel equations and capture the effects of the secondary’s gravity and orbital eccentricity on the shape and orientation of near-equatorial retrograde relative trajectories. The analytical solution of the in-plane and out-of-plane components of the secular motion is achieved by averaging over the relative longitude of a spacecraft as seen from the co-rotating frame of the two primaries. Developments are validated against the numerical integration of quasi-periodic trajectories that densely cover the surface of three-dimensional invariant tori. This analysis confirms the stable nature of quasi-satellite orbits and provides new tools for future spacecraft missions such as the Martian Moons eXploration envisaged by JAXA.

     

Work and Thermal Fluctuations in Crystal Indentation under Deterministic and Stochastic Thermostats: The Role of System–Bath Coupling

The Jarzynski equality (JE) was originally derived under the deterministic Hamiltonian formalism, and later, it was demonstrated that stochastic Langevin dynamics also lead to the JE. However, the JE has been verified mainly in small, low-dimensional systems described by Langevin dynamics. Although the two theoretical derivations apparently lead to the same expression, we illustrate that they describe fundamentally different experimental conditions. While the Hamiltonian framework assumes that the thermal bath producing the initial canonical equilibrium switches off for the duration of the work process, the Langevin bath effectively acts on the system. Moreover, the former considers an environment with which the system may interact, whereas the latter does not. In this study, we investigate the effect of the bath on the measurable quantity of the JE through molecular dynamics simulations of crystal nanoindentation employing deterministic and stochastic thermostats. Our analysis shows that the distributions of the kinetic energy and the mechanical work produced during the indentation processes are affected by the interaction between the system and the thermostat baths. As a result, the type of thermostatting has also a clear effect on the left-hand side of the JE, which enables the estimation of the free-energy difference characterizing the process.     

An integrated approach to ultraintense laser sciences: The PLASMON-X project

In the present paper, we aim to show the interest of combining Multiwavelength Anomalous Diffraction (MAD) and Diffraction Anomalous Fine Structure (DAFS) spectroscopy, in grazing incidence, to obtain structural properties (composition, strain and atomic ordering) of semiconductor heterostructures and nanostructures. As an example we report on preliminary results obtained on a series of Ge/Si(001) nano-island samples: pyramides and domes on nominal and prepatterned surfaces. For free standing domes, it is shown that the Ge content strongly depends on the growth condition with a tendency to increase from the bottom to the top of the nano-islands. There is also some indication of atomic ordering in the upper part of the islands. For small, capped pyramids, we show that the Diffraction Anomalous Fine Structure spectroscopy is the unique non destructive method that allows to recover the actual Ge content, the in-plane and out-of-plane strain and to detect atomic ordering.