全文获取类型
收费全文 | 297篇 |
免费 | 12篇 |
国内免费 | 3篇 |
专业分类
化学 | 242篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 14篇 |
物理学 | 53篇 |
出版年
2023年 | 4篇 |
2022年 | 1篇 |
2021年 | 3篇 |
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 2篇 |
2017年 | 1篇 |
2016年 | 11篇 |
2015年 | 7篇 |
2014年 | 8篇 |
2013年 | 16篇 |
2012年 | 18篇 |
2011年 | 21篇 |
2010年 | 16篇 |
2009年 | 2篇 |
2008年 | 11篇 |
2007年 | 16篇 |
2006年 | 16篇 |
2005年 | 20篇 |
2004年 | 15篇 |
2003年 | 10篇 |
2002年 | 12篇 |
2001年 | 6篇 |
2000年 | 7篇 |
1999年 | 6篇 |
1998年 | 8篇 |
1997年 | 8篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 6篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 1篇 |
1981年 | 4篇 |
1980年 | 5篇 |
1979年 | 3篇 |
1977年 | 1篇 |
1976年 | 2篇 |
排序方式: 共有312条查询结果,搜索用时 93 毫秒
141.
142.
Tamao Ishida Yuta Onuma Kota Kinjo Akiyuki Hamasaki Hironori Ohashi Tetsuo Honma Tomoki Akita Takushi Yokoyama Makoto Tokunaga Masatake Haruta 《Tetrahedron》2014
Palladium nanoparticles (Pd NPs) encapsulated by conjugated microporous polymers (CMPs) were prepared by the Pd-catalyzed polymerization followed by a thermal treatment with N2 or H2. The Pd catalysts were embedded in the porous network during polymerization and used as a precursor for the generation of Pd NPs in CMP. Although no Pd NPs were formed in the as-synthesized Pd/CMPs, Pd NPs with 1.6–3.5 nm size were formed after the thermal treatment. The obtained Pd/CMP-N2 and -H2 catalysts were highly selective in the hydrogenation of 4-nitrostyrene to 4-ethylnitrobenzene, whereas Pd NPs supported on carbon (Ketjen black) gave a fully reduced product, 4-ethylaniline. Substituents in CMP framework could change the catalytic activity of Pd NPs; hydroxy-substituted CMP encapsulated Pd NPs showed higher catalytic activity than Pd/CMP-H2 for benzyl alcohol oxidation. 相似文献
143.
Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon‐Assisted CF Bond Cleavage 下载免费PDF全文
144.
Inside Cover: Kinetic Resolution of Allyl Fluorides by Enantioselective Allylic Trifluoromethylation Based on Silicon‐Assisted CF Bond CleavageZ308071 (Angew. Chem. Int. Ed. 2/2014) 下载免费PDF全文
145.
Hiroyuki Kawai Yutaka Sugita Etsuko Tokunaga Hiroyasu Sato Motoo Shiro Norio Shibata 《ChemistryOpen》2014,3(1):14-18
Highly functionalized 5-trifluoromethyl-2-isoxazoline derivatives featuring a triflyl (SO2CF3) group at the 4-position were successfully synthesized via diastereoselective trifluoromethylation and halogenation of isoxazole triflones using the Ruppert– Prakash reagent. The trifluoromethylation is quite general in terms of the substrates including 3,5-diaryl isoxazole triflones and 3-aryl-5-styrylisoxazole triflones to provide products in high yields with excellent diastereoselectivities. The highly functionalized 5-trifluoromethyl-2-isoxazoline derivatives are expected to be a new class of antiparasiticides. Thus the triflyl group both activates isoxazoles and the 4-postion of CF3 adducts, and has a potential biological function. 相似文献
146.
Shinobu Miyagawa Masaki Kimura Shin Kagami Tsuneomi Kawasaki Yuji Tokunaga 《化学:亚洲杂志》2020,15(19):3044-3049
A crown ether/amine‐type [2]rotaxane was synthesized and utilized as a probe for the detection of acids and anions. The addition of acids to the amine‐type [2]rotaxane solution generated corresponding crown ether/ammonium‐type [2]rotaxanes, which were purified by silica gel column chromatography as ammonium salts. The isolated yields of the [2]rotaxanes, possessing a variety of anions, depended on the acidity and polarity of the counter anions. The behaviours of the ammonium‐type [2]rotaxanes on thin‐layer chromatography (TLC) silica gel reflected the properties of the counter anions. The treatment of the amine‐type [2]rotaxane with acids afforded the corresponding ammonium‐type [2]rotaxanes bearing several different anions. The ammonium‐type [2]rotaxanes behaved similarly to the purified [2]rotaxanes on the TLC silica gel. Furthermore, we succeeded in the analysis of anions using mixtures of the amine‐type [2]rotaxane and salts in an appropriate solvent. We demonstrated the detection of anions by the combination of TLC and the utilization of the [2]rotaxane probe. 相似文献
147.
148.
Shin-ichi Tokunaga 《Discrete Mathematics》1996,150(1-3):371-378
Let G be a planar graph with n vertices, v be a specified vertex of G, and P be a set of n points in the Euclidian plane
in general position. A straight-line embedding of G onto P is an embedding of G onto
whose images of vertices are distinct points in P and whose images of edges are (straight) line segments. In this paper, we classify into five classes those pairs of G and v such that for any P and any p P, G has a straight-line embedding onto P which maps v to p. We then show that all graphs in three of the classes indeed have such an embedding. This result gives a solution to a generalized version of the rooted-tree embedding problem raised by M. Perles. 相似文献
149.
150.
Electric field-controlled dissociation and association of porphyrin J-aggregates in aqueous solution
The electrooptic effects of porphyrin J-aggregates of tetraphenyl porphyrin tetrasulfonic acid (TPPS) in aqueous solution were studied using electroabsorption (EA) spectroscopy. When the J-aggregates were three-dimensionally distributed, the EA spectra exhibited broadening in the exciton band. When a DC or AC electric field was applied for a long time, the J-aggregates with KCl were dissociated into monomers via N-mers (N = 2-4) as intermediate states, while those without KCl had an increase in aggregation. The EA spectra showed a red shift in the exciton band for N-mers, which indicates that N-mers are isolated microaggregates with a coherent aggregation number N, and isolated microaggregates have not been microscopically or spectrally observed until now. The estimated third-order nonlinear optical susceptibility χ((3)) for EA spectra in aqueous solution was 10(4) times larger than that in a polymer film. The molecular rearrangement model was applied to a variety of orientational distributions and the results were explained fairly well. The contribution of the electric double layer is the most probable reason for the large enhancement of χ((3)) for the solution sample. The dynamic equilibrium between two types of monomers, J-aggregates of various aggregation numbers and cations such as K(+) and H(+) was investigated to reveal that K(+) is more loosely bound to the constituent monomers in J-aggregates than H(+). Equilibrium equations also show that well-grown aggregates with N > 15 tend to dominate in a solution of J-aggregates, which explains why only well-developed aggregates can be observed spectroscopically. 相似文献