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71.
Tanaka Y Hoshino W Shimizu S Youfu K Aratani N Maruyama N Fujita S Osuka A 《Journal of the American Chemical Society》2004,126(10):3046-3047
When heated, bis-Cu(II) octaphyrin(1.1.1.1.1.1.1.1) is quantitatively split into two Cu(II) porphyrins both in solution and film states, which is accompanied by large absorption spectral changes. 相似文献
72.
The photoinduced decarbonylation of a ruthenium(II) carbonyl octaethylporphyrin (RuOEP(CO)(Py)) complex has been shown to occur upon nanosecond pulse laser irradiation as a visible light excitation source, which is reasonably interpreted by a stepwise two-photon absorption process. 相似文献
73.
74.
Hoshino K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2001,7(13):2727-2731
The present article focuses on a recent finding concerning dinitrogen fixation by using titanium oxide/conducting polymer composite systems and its comparison with an earlier fixation method (Schrauzer process) that makes use of a powdered titanium oxide. Both processes work under the stimulus of light at room temperature and pressure, but dinitrogen is fixed to a solid ammonium salt crystal in the former and to a gaseous ammonia molecule in the latter process. Differences in the physicochemical concepts between the two processes are discussed. 相似文献
75.
Mitsuo Hoshino 《Journal of Pure and Applied Algebra》2003,177(2):159-175
Let A be an artin algebra and e∈A an idempotent with add(eAA)=add(D(AAe)). Then a projective resolution of AeeAe gives rise to tilting complexes for A, where P(l)• is of term length l+1. In particular, if A is self-injective, then is self-injective and has the same Nakayama permutation as A. In case A is a finite dimensional algebra over a field and eAe is a Nakayama algebra, a projective resolution of eAe over the enveloping algebra of eAe gives rise to two-sided tilting complexes {T(2l)•}l?1 for A, where T(2l)• is of term length 2l+1. In particular, if eAe is of Loewy length two, then we get tilting complexes {T(l)•}l?1 for A, where T(l)• is of term length l+1. 相似文献
76.
77.
78.
Microwave spectrum of monodeuterated diacetylene (HCCCCD), which is nonpolar in the equilibrium configuration, was observed in various excited states of bending vibrations. Dipole moments in the ν6, 2ν6, and ν6 + ν9 vibrational states were determined from the Stark effect measurement to be 0.0907(6), 0.1681(14), and 0.0900(4) D with uncertainties in parentheses, where ν6 and ν9 denote respectively the CCH bending and lowest frequency bending vibrations. The l-type doubling constant in the ν6 state is 2.1316(28) MHz. Rotational constants were determined in MHz; ν6(Π), 4086.2165(44); 2ν6(Δ), 4087.6963(58); ν6 + ν9(Δ), 4097.7537(50); 2ν8(Δ), 4094.4786(103); ν6 + ν7(Δ), 4092.9074(176); ν7 + ν8(Δ), 4095.8925(354); 2ν6 + ν9(Φ), 4098.9505(339). 相似文献
79.
Reika Fukuizumi Tohru Ozawa 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2005,16(3):1000-1011
Exponential decay estimates are obtained for complex-valued solutions to nonlinear elliptic equations in
\mathbbRn ,\mathbb{R}^{n} ,
where the linear term is given by Schr?dinger operators H = − Δ + V with nonnegative potentials V and the nonlinear term is given by a single power with subcritical Sobolev exponent in the attractive case. We describe specific
rates of decay in terms of V, some of which are shown to be optimal. Moreover, our estimates provide a unified understanding of two distinct cases in
the available literature, namely, the vanishing potential case V = 0 and the harmonic potential case V(x) = |x|2. 相似文献
80.
[Structure: see text] The morphinan skeleton was effectively synthesized by an intramolecular Mannich-type reaction. Further transformation led to total synthesis of morphine. 相似文献