Mono-alkene-inserted [n]cycloparaphenylenes 1 [(ene)-[n]CPP] with n=6, 8, and 10, mono-ortho-phenylene-inserted [6]CPP 2 , and di-alkene-insertved [n]CPP 3 [(ene)2-[n]CPP] with n=4, 6, and 8 were synthesized by fusing CPP precursors and alkene or ortho- phenylene groups through coupling reactions. Single-crystal X-ray diffraction analyses reveal that the strips formed by the π-surfaces of 1 and 2 exhibited a Möbius topology in the solid state. While the Möbius topology in the parent 1 and 2 in solution was lost due to the free rotation of the paraphenylene unit even at low temperatures, ene-[6]CPP 4 with eight 1-pyrrolyl groups preserved the Möbius topology even in solution. Despite a twist, 1 has in-plane conjugation and possesses a unique size dependence of the electronic properties: namely, the opposite size dependency of the HOMO–LUMO energy relative to conventional π-conjugated molecules. 相似文献
Summary: The photo‐crosslinking of carbazole dendrimers was analyzed by UV and IR spectroscopic methods. Photoirradiation results in the formation of a film that is insoluble in toluene and benzene. Time‐of‐flight mass spectrometry studies revealed that the photoirradiation lead to an oligomerization of the dendrimer through crosslinking. The resulting insoluble dendrimer film could be applied as a hole‐transport layer in efficient polymer electroluminescence devices (PLEDs).
Luminance‐voltage characteristics for PLEDs wherein PEDOT:PSS and CbzG3 complex with SnCl2 were employed as the hole transport layer (ITO/HTL/EML/Ca/Ag). 相似文献
The peptide-containing block copolymer poly(N-acetyliminoethylene)-block-poly(L -phenylalanine) (1) formed large water-soluble aggregates in water due to the hydrophobic and hydrogen-bonding character of the poly(L -phenylalanine) block. The solution properties of 1 were compared with those of the block copolymer poly(N-acetyliminoethylene)-block-poly(N-benzoyliminoethylene) (2) with an analogous structure. 1 formed aggregates even though the poly(phenylalanine) segment was short as compared with 2 in which hydrophobic interaction may be the only driving force to form aggregates. The aggregates have strong capability of incorporating Lipase P and largely increase the hydrolysis activity against p-nitrophenyl propionate as compared with that of free Lipase P. 相似文献
Various types of molecular assembly of long-chain compounds in solid states were investigated by means of infrared absorption, Raman and Brillouin spectroscopic methods. As for the polymorphism in even-numbered n-fatty acids, three monoclinic modifications, B, C, and E, all consisting of the orthorhombic polyethylene sublattice, give rise to their characteristic infrared and Raman spectra. A dynamical equilibrium between cis and trans conformations of the hydrogen-bonded carboxyl groups in modification C, which is related to the high-temperature stable character of this phase, is reflected to a dramatic change with temperature in the low-frequency Raman spectra. A new type of reversible solid state phase transition was found between two A-type (triclinic) modifications of myristic, palmitic, and stearic acids. The γ→α phase transition of oleic acid was found to be caused by a conformational disordering of polymethylene chains at the lamellar interfacial region. Two basic polytype structures, Mon and Orth II, of stearic acid B were investigated, and it was found that the low-frequency phonon frequencies (below 50 cm−1) were strongly influenced by the polytype structure. Based on the spectroscopic considerations, Orth II was predicted as the thermodynamically stable phase around room temperature compared with Mon, and the stability is responsible for the vibrational free energy term. Some experimental findings which support this prediction were obtained. The values of the stiffness tensor elements of Mon and Orth II, measured by Brillouin scattering, indicate that the mechanical behavior of bulk crystals is very dependent on the polytype structure. The relationship between the mobility of chain molecules and the width of the spectral bands was investigated in a quantitative manner for the case of n-alkane molecules entrapped in the urea inclusion adducts. The changes in the half-width for the polarization components of various Raman bands on the transition from the orthorhombic to the hexagonal phase are interpreted in terms of the correlation functions of the Raman tensor related to the rotational motion of the alkane molecules around the chain axes. 相似文献