全文获取类型
收费全文 | 1513篇 |
免费 | 32篇 |
国内免费 | 9篇 |
专业分类
化学 | 1118篇 |
晶体学 | 31篇 |
力学 | 29篇 |
数学 | 122篇 |
物理学 | 254篇 |
出版年
2022年 | 5篇 |
2019年 | 14篇 |
2017年 | 8篇 |
2016年 | 23篇 |
2015年 | 20篇 |
2014年 | 34篇 |
2013年 | 89篇 |
2012年 | 75篇 |
2011年 | 77篇 |
2010年 | 44篇 |
2009年 | 58篇 |
2008年 | 92篇 |
2007年 | 83篇 |
2006年 | 97篇 |
2005年 | 98篇 |
2004年 | 80篇 |
2003年 | 66篇 |
2002年 | 74篇 |
2001年 | 20篇 |
2000年 | 35篇 |
1999年 | 21篇 |
1998年 | 18篇 |
1997年 | 14篇 |
1996年 | 21篇 |
1995年 | 13篇 |
1994年 | 23篇 |
1993年 | 12篇 |
1992年 | 10篇 |
1991年 | 9篇 |
1990年 | 8篇 |
1988年 | 7篇 |
1987年 | 11篇 |
1986年 | 9篇 |
1985年 | 29篇 |
1984年 | 21篇 |
1983年 | 14篇 |
1982年 | 31篇 |
1981年 | 31篇 |
1980年 | 18篇 |
1979年 | 18篇 |
1978年 | 11篇 |
1977年 | 11篇 |
1976年 | 16篇 |
1975年 | 10篇 |
1974年 | 7篇 |
1973年 | 17篇 |
1972年 | 6篇 |
1970年 | 4篇 |
1968年 | 6篇 |
1967年 | 4篇 |
排序方式: 共有1554条查询结果,搜索用时 46 毫秒
121.
Koichi Fukase Hideo Nakayama Motohiro Kurosawa Toshiki Ikegaki Takeshi Kanoh Sumihiro Hase 《Journal of carbohydrate chemistry》2013,32(5):715-736
Abstract New bifunctional reagents, 2-amino-6-carboxyethylpyridine and 2-amino-6-cyanoethylpyridine, were designed and synthesized in order to provide a novel procedure for preparation of neoglycoconjugates from fluorescence-labeled and purified sugar chains. Labeling of model sugar chains with these reagents was effected by reductive amination using BH3.Me2NH to give corresponding 6-carboxyethylpyridylaminated (CEPA-) and 6-cyanoethylpyridylaminated (CNEPA-) derivatives, which were readily purified by reversed phase HPLC. The reagent parts of the labeled products possess the functional groups which then serve as linkers for coupling with matrices such as proteins and polymers. A CEPA-derivative of glucose was directly coupled with the ε-amino group of a Lys derivative to give a neoglycoprotein model. CNEPA-sugars were hydrogenated to give 6-aminopropylpyridylaminated (APPA-) derivatives, which can then be readily used for the preparation of various types of neoglycoconjugates by use of appropriate spacers as exemplified by the coupling of APPA-maltotriose with bovine serum albumin (BSA), biotin, and acrylic acid. The reaction of APPA-maltotriose with succinimidyl 3-(3-nitro-2-pyridyldithio)propionate gave the corresponding amide to be used for a disulfide formation with BSA. Condensation with biotin was effected by use of N-hydroxysuccinimidobiotin. The conjugation of APPA-maltotriose with acrylic acid was carried out by use of 4-acryloyloxyphenyldimethylsulfonium methylsulfate to give the corresponding acrylamide, which can be used for the preparation of sugar-acrylamide copolymers. 相似文献
122.
Dynamic nuclear polarization studies of nitroxyl spin probes in agarose gel using Overhauser‐enhanced magnetic resonance imaging
下载免费PDF全文
![点击此处可从《Magnetic resonance in chemistry : MRC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
V. Meenakumari Hideo Utsumi Fuminori Hyodo A. Jawahar A. Milton Franklin Benial 《Magnetic resonance in chemistry : MRC》2017,55(11):1022-1028
Agarose is a tissue‐equivalent material and its imaging characteristics similar to those of real tissues. Hence, the dynamic nuclear polarization studies of 3‐carboxy‐2,2,5,5‐tetramethyl‐pyrrolidine‐1‐oxyl (carboxy‐PROXYL) in agarose gel were carried out. The dynamic nuclear polarization parameters such as spin lattice relaxation time, longitudinal relaxivity, leakage factor, saturation parameter and coupling parameter were estimated for 2 mM carboxy‐PROXYL in phosphate‐buffered saline solution and water/agarose mixture (99 : 1). From these results, the spin probe concentration was optimized as 2 mM, and the reduction in enhancement was observed for carboxy‐PROXYL in water/agarose mixture (99 : 1) compared with phosphate‐buffered saline solution. Phantom imaging was also performed with 2 mM concentration of carboxy‐PROXYL in various concentrations of agarose gel at various radio frequency power levels. The results from the dynamic nuclear polarization measurements agree well with the phantom imaging results. These results pave the way for designing model system for human tissues suited to the biological applications of electron spin resonance/Overhauser‐enhanced magnetic resonance imaging. 相似文献
123.
Hirokazu Sato Shusaku Hamada Roberto M. Sertkawa Tatsuya Nishimura Takashi Usui Hideo Sekino 《高压研究》2013,33(1-6):403-413
Abstract Continuous flames have been observed in Supercritical water oxidation (scWO) of isopropyl alcohol (IPA), using a vertical continuous reactor with sapphire windows and a mixing nozzle. Two types of continuous flame were confirmed: the one was long pale blue colored and the other was red short cone shaped, changing blue to red at around air ratio 2.0. The flame was strongly influenced by IPA concentration, air ratio and design of the mixing nozzle. Results for decomposition of PA are presented for IPA concentrations ranging from 600 up to 28260 ppm as TOC and initial reactor temperatures, were mostly around 490°C, at 25 MPa. Decomposition rate at steady state was over 99.9%. Experimentally measured CO2 and O2 concentrations at the flue gas were in good agreement with theoretically calculated values. Even for low air ratio as 1.1, high decomposition rate without CO, NO, NO2 was achieved. 相似文献
124.
125.
In CRM (Customer Relationship Management), the importance of a segmentation method for identifying good customers has been increasing. For evaluation of different segmentation methods, Accuracy often plays a key role. This indicator, however, cannot distinguish two types of errors. The purpose of this paper is to overcome this pitfall by introducing two different indicators: Recall and Precision. Assuming that a promotion is addressed exclusively to the selected target customers, the financial effectiveness of the underlying segmentation method is expressed as a function of Recall and Precision. An optimization problem is then formulated so as to maximize the financial measure by finding the optimal threshold level in terms of the severeness for estimating the target set. By introducing a functional form which represents correctness and mistakes about the target set, the unique optimal solution is derived explicitly. The proposed approach is validated by using real customer purchase data. 相似文献
126.
127.
Hideo Kozono 《Mathematische Annalen》2001,320(4):709-730
Consider the nonstationary Stokes equations in exterior domains with the compact boundary . We show first that the solution decays like for all as . This decay rate is optimal in the sense that for some as occurs if and only if the net force exerted by the fluid on is zero.
Received: 15 June 2000 / Published online: 18 June 2001 相似文献
128.
129.
Novel fluoroalkyl end‐capped vinyltrimethoxysilane oligomer/hydroxyapatite (HAp) nanocomposites were prepared by the reaction of calcium nitrate tetrahydrate and phosphoric acid in the presence of the corresponding oligomer. These fluorinated oligomer/HAp composites thus obtained are nanometer size‐controlled fine particles (83–173 nm), and were found to exhibit good dispersibility in methanol, ethanol, and isopropyl alcohol. These fluorinated HAp nanocomposites were applied to the surface modification of glass and poly(methyl methacrylate) (PMMA) to exhibit good hydro‐ and oleophobic characteristics imparted by fluorine on their surface. In addition, the surface structural changes of the modified polyethylene terephtalate and PMMA films treated with these fluorinated nanocomposites before and after soaking in a simulated body fluid (SBF) were analyzed by using SEM, XRD, and EDX to observe the formation of spherical HAp deposits on the surface. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
130.
We have determined the orientational distribution of cyano-substituted side chains of a rubbed polyimide film, and a liquid crystal monolayer adsorbed on the film, by means of optical second harmonic generation. With the orientational distribution of a main chain that was measured in a previous study by means of near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, we have obtained the correlation of all the orientational distributions contributing to the alignment of LC molecules, i.e. pretilt angle. We find that the side chain plays a role in increasing the pretilt angle, but in the case of rubbing strength dependence, the main chain has stronger correlation with the pretilt angle than has the side chain. 相似文献