全文获取类型
收费全文 | 97篇 |
免费 | 2篇 |
国内免费 | 1篇 |
专业分类
化学 | 70篇 |
晶体学 | 5篇 |
力学 | 2篇 |
数学 | 5篇 |
物理学 | 18篇 |
出版年
2023年 | 1篇 |
2021年 | 4篇 |
2020年 | 3篇 |
2019年 | 2篇 |
2018年 | 2篇 |
2017年 | 2篇 |
2016年 | 2篇 |
2014年 | 2篇 |
2013年 | 4篇 |
2012年 | 2篇 |
2011年 | 6篇 |
2010年 | 7篇 |
2009年 | 3篇 |
2008年 | 7篇 |
2007年 | 8篇 |
2006年 | 6篇 |
2005年 | 4篇 |
2004年 | 4篇 |
2002年 | 4篇 |
2001年 | 3篇 |
2000年 | 1篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 1篇 |
1994年 | 1篇 |
1993年 | 2篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1985年 | 2篇 |
1982年 | 1篇 |
1977年 | 1篇 |
1974年 | 2篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1963年 | 1篇 |
排序方式: 共有100条查询结果,搜索用时 15 毫秒
91.
Lundgren E Gustafson J Mikkelsen A Andersen JN Stierle A Dosch H Todorova M Rogal J Reuter K Scheffler M 《Physical review letters》2004,92(4):046101
The oxidation of the Pd(100) surface at oxygen pressures in the 10(-6) to 10(3) mbar range and temperatures up to 1000 K has been studied in situ by surface x-ray diffraction (SXRD). The results provide direct structural information on the phases present in the surface region and on the kinetics of the oxide formation. Depending on the (T,p) environmental conditions, we observe either a thin (sqrt[5]xsqrt[5])R27 degrees surface oxide or the growth of a rough, poorly ordered bulk oxide film of PdO predominantly with (001) orientation. By either comparison to the surface phase diagram from first-principles atomistic thermodynamics or by explicit time-resolved measurements we identify a strong kinetic hindrance to the bulk oxide formation even at temperatures as high as 675 K. 相似文献
92.
J.-L. Lu S. Kaya T.K. Todorova J. Sauer S. Shaikhutdinov H.-J. Freund 《Surface science》2006,600(13):L164
We have observed formation of one-dimensional silica structures of 0.5 nm in width on Mo(1 1 2) single crystal surface. Combination of high-resolution scanning tunneling microscopy, photoelectron and infrared spectroscopy, and density functional theory provides strong evidence for formation of paired rows of corner sharing [SiO4] tetrahedra chemisorbed on a metal substrate. 相似文献
93.
Trendafilova A Todorova M Nikolova M Gavrilova A Vitkova A 《Natural product communications》2011,6(12):1851-1854
Antioxidant capacity of the methanolic extract of Alchemilla mollis was measured by its ability to scavenge the DPPH radical. The EtOAc fraction obtained after partition of the total extract was found to be the most active radical scavenger (IC50 9.8 +/- 1.8 microg/mL) and was subjected to fractionation by Sephadex LH-20 CC. Further purification by RP-18 CC led to the isolation of eight flavonoid glycosides: cis- and trans-tiliroside (1 and 2), rhodiolgin (3), hyperoside (4), isoquercitrin (5), miquelianin (6), sinocrassoside D2 (7), and gossypetin-3-O-beta-D-galactopyranosyl-7-O-alpha-L-rhamnopyranoside (8). It was found that 8 is a new compound and its antioxidant activity is also reported. Identification of the isolated compounds was carried out by spectroscopic and spectrometric analysis (1D and 2D NMR, UV and MS). 相似文献
94.
Z. Cherkezova-Zheleva D. Paneva S. Todorova H. Kolev M. Shopska I. Yordanova I. Mitov 《Hyperfine Interactions》2014,226(1-3):529-543
Iron and iron-platinum catalysts supported on activated carbon have been successfully synthesized by wet impregnation method and low-temperature treatment in inert atmosphere. The content of the supported phases corresponds to 10 wt % Fe and 0.5 wt % Pt. Four catalytic samples were synthesized: Sample A—activated carbon impregnated with Fe nitrate; Sample B—activated carbon impregnated with Pt salt; Sample C—activated carbon impregnated consequently with Fe and Pt salts; Sample D—activated carbon impregnated simultaneously with Fe and Pt salts. The as-prepared materials were characterized by Mössbauer spectroscopy, X-ray diffraction, infrared and X-ray photoelectron spectroscopy. The spectra show that the activated carbon support and the preparation procedure give rise to the synthesis of isolated metal Pt ions and ultradispersed Fe and Pt oxide species. Probably the presence of different functional groups of activated carbon gives rise to registered very high dispersion of loaded species on support. The catalytic tests were carried out in PROX reaction. A lower activity of bimetallic Pt-Fe samples was explained with the increase in surface oxygen species as a result of predomination of iron oxide on the support leading to the increase in selectivity to the H2 oxidation. Partial agglomeration of supported iron oxide phase was registered after catalytic tests. 相似文献
95.
Batovska DI Todorova IT Bankova VS Parushev SP Atanassov AI Hvarleva TD Djakova GJ Popov SS 《Natural product research》2008,22(14):1231-1236
Surface leaf metabolites of two seedlings of a Bulgarian winemaking cultivar Storgozia I(1) were analyzed in two seasons - summer (July) and autumn (October). The resistance towards some fungal pathogens of one of the plants was estimated as superior to the resistance of the other one. Significant seasonal variations in the chemical constituents of the two seedlings were observed. The main metabolites of the summer samples were sterols, terpenes, fatty acids and heterocyclic compounds. In autumn, sterol and fatty acid contents decreased, mono- and diterpenes and heterocyclic compounds disappeared and instead of them hydrocarbons and alcohols were detected. Some individual components - stearic acid, alpha-amyrin, lupeol and squalene - correlated with the estimated resistance and were therefore proposed as biomarkers for the fungal resistance in grape-vine leaves. 相似文献
96.
Poineau F Forster PM Todorova TK Gagliardi L Sattelberger AP Czerwinski KR 《Dalton transactions (Cambridge, England : 2003)》2012,41(10):2869-2872
The [Cs((2 + x))][H(3)O((1 - x))]Tc(2)Br(8)·4.6H(2)O (x = 0.221) salt has been synthesized and characterized by single crystal XRD. Multi-configurational quantum chemical calculations on Tc(2)X(8)(n-) (X = Cl, Br; n = 2, 3) have been performed and indicate the π component in the Tc-Tc bond to be stronger for n = 3. 相似文献
97.
P. A. Volkov E. V. Todorova N. D. Bakhteeva A. G. Ivanova A. L. Vasil’ev 《Crystallography Reports》2011,56(3):463-469
An aluminum amorphous alloy doped with transition (Fe and Ni) and rare earth (La) metals has been used as an object of systematic
study of the structural transformations that are characteristic of different methods of sample preparation for transmission
electron microscopy (the mechanical tearing of ribbons, electrochemical thinning, and Ar+-ion etching under different conditions). The results of X-ray diffraction analysis and a calorimetric study of the structure
in comparison with electron microscopy data made it possible to determine the optimal method of sample preparation, which
ensures minimum distortions in the structure of metastable amorphous alloys with a low crystallization temperature. 相似文献
98.
Todorova T Seitsonen AP Hutter J Kuo IF Mundy CJ 《The journal of physical chemistry. B》2006,110(8):3685-3691
The structure, dynamical, and electronic properties of liquid water utilizing different hybrid density functionals were tested within the plane wave framework of first-principles molecular dynamics simulations. The computational approach, which employs modified functionals with short-ranged Hartree-Fock exchange, was first tested in calculations of the structural and bonding properties of the water dimer and cyclic water trimer. Liquid water simulations were performed at the state point of 350 K at the experimental density. Simulations included three different hybrid functionals, a meta-functional, four gradient-corrected functionals, and the local density and Hartree-Fock approximations. It is found that hybrid functionals are superior in reproducing the experimental structure and dynamical properties as measured by the radial distribution function and self-diffusion constant when compared to the pure density functionals. The local density and Hartree-Fock approximations show strongly over- and understructured liquids, respectively. Hydrogen bond analysis shows that the hybrid functionals give slightly smaller average numbers of hydrogen bonds than pure density functionals but similar hydrogen bond populations. The average molecular dipole moments in the liquid from the three hybrid functionals are lower than those of the corresponding pure density functionals. 相似文献
99.
Maria Argirova Maya Guncheva Georgi Momekov Emiliya Cherneva Rositsa Mihaylova Miroslav Rangelov Nadezhda Todorova Petko Denev Kameliya Anichina Anelia Mavrova Denitsa Yancheva 《Molecules (Basel, Switzerland)》2023,28(1)
1H-benzimidazol-2-yl hydrazones with varying hydroxy and methoxy phenyl moieties were designed. Their effect on tubulin polymerization was evaluated in vitro on porcine tubulin. The compounds elongated the nucleation phase and slowed down the tubulin polymerization comparably to nocodazole. The possible binding modes of the hydrazones with tubulin were explored by molecular docking at the colchicine binding site. The anticancer activity was evaluated against human malignant cell lines MCF-7 and AR-230, as well as against normal fibroblast cells 3T3 and CCL-1. The compounds demonstrated a marked antineoplastic activity in low micromolar concentrations in both screened in vitro tumor models. The most active were the trimethoxy substituted derivative 1i and the positional isomers 1j and 1k, containing hydroxy and methoxy substituents: they showed IC50 similar to the reference podophyllotoxin in both tumor cell lines, accompanied with high selectivity towards the malignantly transformed cells. The compounds exerted moderate to high ability to scavenge peroxyl radicals and certain derivatives—1l containing metha-hydroxy and para-methoxy group, and 1b-e with di/trihydroxy phenyl moiety, revealed HORAC values high or comparable to those of well-known phenolic antioxidants. Thus the 1H-benisimidazol-2-yl hydrazones with hydroxy/methoxy phenyl fragments were recognized as new agents exhibiting promising combined antioxidant and antineoplastic action. 相似文献
100.
Ginka Todorova Ernesto Pérez Mónica M. Marugán Manya Kresteva 《Macromolecular Symposia》2004,212(1):497-502
The main-chain thermotropic liquid-crystalline poly(heptane-1,7-diyl biphenyl-4,4′-dicarboxylate) (P7MB) was investigated by time-resolved small-angle X-ray scattering (SAXS), wide-angle X-ray scattering (WAXS), and differential scanning calorimerty (DSC). Nonisothermal crystallisation with different rates of cooling and heating was used. On cooling, two phase transitions are observed, isotropic melt - smectic (I-Sm) and Sm- three-dimensional crystalline structure (Sm-Cr), whereas on heating only one transition is observed, Cr-I transition. The transition enthalpies were calculated. Temperature dependences of d-spacings of all crystalline peaks and of the peak observed at high values of scattering vector in the SAXS region were derived. The temperature dependence of the degree of crystallinity was established, based on the integrated intensities of the crystalline peaks and amorphous halo in WAXS. 相似文献