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41.
László Csaba Bencze Csaba Paizs Monica Ioana Toşa Maria Trif Florin Dan Irimie 《Tetrahedron: Asymmetry》2010,21(16):1999-2004
A highly stereoselective enzymatic kinetic resolution of novel various substituted racemic furylbenzthiazole-2-yl-ethanols and their acetates has been developed. Both processes, the enzymatic acylation of the racemic alcohols and the enzymatic methanolysis of racemic acetates yielded highly enantiomerically enriched (ee >98%) resolution product, when CaL-B was used as a biocatalyst in acetonitrile. The absolute configuration of the obtained (R)-(+)-1-(5-(4-chlorobenzo[d]thiazol-2-yl)furan-2-yl)ethanol was determined by a detailed 1H NMR study of rac- and (+)-1-(5-(4-chlorobenzo[d]thiazol-2-yl)furan-2-yl)ethanol Mosher derivatives. 相似文献
42.
Ultrasonic guided wave becomes one of promising tool for monitoring various types of structures such as large steel plates, vessels, and pipes in oil, chemical or nuclear industry, because guided waves have ability to travel wide range of the target structure in a single position. However, analysis of guided wave signals acquired from structure is difficult on account of low S/N ratio and its dispersive nature. To improve S/N ratio and overcome dispersion effect, focusing techniques for guided waves are needed. Thus, in this study, focusing techniques for guided waves were developed in order to improve long range inspection ability, and performance of the developed techniques was verified by experiments. 相似文献
43.
Murat Aydemir Nermin Meric Akın Baysal Bahattin Gümgüm Mahmut Toğrul Yılmaz Turgut 《Tetrahedron: Asymmetry》2010,21(6):703-710
Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. The new chiral C2-symmetric ligands N,N′-bis-[(1S)-1-sec-butyl-2-O-(diphenylphosphinite)ethyl]ethanediamide, 1 and N,N′-bis-[(1S)-1-phenyl-2-O-(diphenylphosphinite)ethyl]ethanediamide, 2 and the corresponding ruthenium complexes 3 and 4 have been prepared and their structures have been elucidated by a combination of multi-nuclear NMR spectroscopy, IR spectroscopy, and elemental analysis. 1H–31P NMR, DEPT, 1H–13C HETCOR, or 1H–1H COSY correlation experiments were used to confirm the spectral assignments. The catalytic activity of complexes 3 and 4 in transfer hydrogenation of acetophenone derivatives by iso-PrOH has also been studied. Under optimized conditions, these chiral ruthenium complexes serve as catalyst precursors for the asymmetric transfer hydrogenation of acetophenone derivatives in iso-PrOH and act as excellent catalysts, giving the corresponding chiral alcohols in 99% yield and up to 75% ee. This transfer hydrogenation is characterized by low reversibility under these conditions. 相似文献
44.
In a mixture of colloidal particles and polymer molecules,the particles may experience an attractive"depletion force"if the size of the polymer molecule is larger than the interparticle separation.This is because individual polymer molecules experience less conformational entropy if they stay between the particles than they escape the inter-particle space, which results in an osmotic pressure imbalance inside and outside the gap and leads to interparticle attraction.This depletion force has been the subject of several studies since the 1980s,but the direct measurement of this force is still experimentally challenging as it requires the detection of energy variations of the order of k_BT and beyond.We present here our results for applying total internal reflection microscopy(TIRM) to directly measure the interaction between a free-moving particle and a flat surface in solutions consisting of small water-soluble organic molecules or polymeric surfactants.Our results indicate that stable nanobubbles(ca.150 nm) exist free in the above aqueous solutions.More importantly,the existence of such nanobubbles induces an attraction between the spherical particle and flat surface.Using TIRM,we are able to directly measure such weak interaction with a range up to 100 nm.Furthermore,we demonstrate that by employing thermo-sensitive microgel particles as a depleting agent,we are able to quantitatively measure and reversibly control k_BYT-scale depletion attraction as function of solution pH. 相似文献
45.
Quinton D Girard A Thi Kim LT Raimbault V Griscom L Razan F Griveau S Bedioui F 《Lab on a chip》2011,11(7):1342-1350
In this work we report on the design, microfabrication and analytical performances of a new electrochemical sensor array (ESA) which allows for the first time the simultaneous amperometric detection of nitric oxide (NO) and peroxynitrite (ONOO(-)), two biologically relevant molecules. The on-chip device includes individually addressable sets of gold ultramicroelectrodes (UMEs) of 50 μm diameter, Ag/AgCl reference electrode and gold counter electrode. The electrodes are separated into two groups; each has one reference electrode, one counter electrode and 110 UMEs specifically tailored to detect a specific analyte. The ESA is incorporated on a custom interface with a cell culture well and spring contact pins that can be easily interconnected to an external multichannel potentiostat. Each UME of the network dedicated to the detection of NO is electrochemically modified by electrodepositing thin layers of poly(eugenol) and poly(phenol). The detection of NO is performed amperometrically at 0.8 V vs. Ag/AgCl in phosphate buffer solution (PBS, pH = 7.4) and other buffers adapted to biological cell culture, using a NO-donor. The network of UMEs dedicated to the detection of ONOO(-) is used without further chemical modification of the surface and the uncoated gold electrodes operate at -0.1 V vs. Ag/AgCl to detect the reduction of ONOOH in PBS. The selectivity issue of both sensors against major biologically relevant interfering analytes is examined. Simultaneous detection of NO and ONOO(-) in PBS is also achieved. 相似文献
46.
Gates AJ Kemp GL To CY Mann J Marritt SJ Mayes AG Richardson DJ Butt JN 《Physical chemistry chemical physics : PCCP》2011,13(17):7720-7731
In protein film electrochemistry a redox protein of interest is studied as an electroactive film adsorbed on an electrode surface. For redox enzymes this configuration allows quantification of the relationship between catalytic activity and electrochemical potential. Considered as a function of enzyme environment, i.e., pH, substrate concentration etc., the activity-potential relationship provides a fingerprint of activity unique to a given enzyme. Here we consider the nature of the activity-potential relationship in terms of both its cellular impact and its origin in the structure and catalytic mechanism of the enzyme. We propose that the activity-potential relationship of a redox enzyme is tuned to facilitate cellular function and highlight opportunities to test this hypothesis through computational, structural, biochemical and cellular studies. 相似文献
47.
Nguyen To Nhu Jose M. R. Sanjurjo Tran Van An 《Proceedings of the American Mathematical Society》1997,125(10):3089-3098
In this second part of our paper, we apply the result of Part 1 to show that the compact convex set with no extreme points, constructed by Roberts (1977), is an AR.
48.
Hung‐Chuan Cheng Li‐Tang Wang Ashraf Taha Khalil Yao‐To Chang Yu‐Chi Lin Ya‐Ching Shen 《中国化学会会志》2004,51(2):431-435
Phytochemical investigation of the stem bark of Calophyllum inophyllum resulted in the isolation of a new dipyrenoxanthone, calophinone ( 1 ), together with four related xanthones ( 2–5 ). Identification of the isolated compounds was achieved through intensive studies of their spectral data, especially 2D NMR. 相似文献
49.
Pulsed UV laser beams, which are widely used in the processing of polymers, have many advantages because their photon energy is higher than the binding energy of polymers. Fabricating polymers with a UV laser process is faster, cleaner, and more convenient than with other processes. Nevertheless, some problems occur in the precision microprocessing of polymers. For example, the formation and deposition of surface debris, which is produced from the breakdown of either polymer chains or radical bonds.To determine the formation and origin of surface debris, a KrF excimer laser beam (248 nm) was used in the processing of poly(ethylene terephthalate) (PET). The investigation of the debris formation was facilitated by UV-vis spectroscopy, ATR FT-IR spectroscopy, and NMR spectroscopy. The UV-vis absorption peak indicates that the primary chromophore in the PET is benzoate. Furthermore, because benzoate causes the primary absorption, the absorbed energy is transferred by heat generation to an unsaturated ester. The ATR FT-IR spectrometer measurements show that the phenyl systems in the benzoate are demolished by ablation. This phenomenon indicates that the photochemical reaction causes the benzoate bonds to break down, and this breakdown in turn causes the carbonization to leave debris on the PET. 相似文献
50.