Coordination behavior of N-benzoylamino acids: Synthesis and structure of mixed-ligand complexes of palladium (II) with N-benzoylamino acid dianion and diamine

Four new mixed-ligand complexes of palladium (II) with L₁ (N-benwyl-α-amino acid dianion) and L₂ [ethyldiamine (en), 2. 2′-bipyridine (Bpy) and 1.10-phenanthroline (Phen)] were synthesized. All the complexes have been characterized by elemental analyses, molar conductance, infrared and¹H NMR spectra and thermo-gravimetric analyses. Crystal structures of [Pd(Bpy)(Bzval-N, O)] and [Pd(en)(Bzphe-N, O) ·H₂O have been determined by X-ray diffraction analysis. The results indicate that in all the complexes’ ligand L₁ coordinates to palladium (II) through deprotonated amide nitrogen and carboxylic oxygen, and there are some intramolecular noncovalent interactions in the complexes. Project supported by the Natural Science Foundation of Zhejiang Province, China.     

Polarisation characteristics of a 12 fibre coupler under femtosecond pulsed and continuous wave illumination

We report on the experimental investigation carried out in the polarisation characteristics of femtosecond pulsed and continuous wave beams propagating through a 1×2 fibre coupler. It is demonstrated that the polarisation states of pulsed and continuous wave illumination over the broad wavelength range can be preserved in a conventional fused fibre coupler. Furthermore, the fibre coupler acts as a low-pass spectral filter in the visible wavelength range with a splitting ratio between 99.6/0.4 and 99.7/0.3. The result is of importance for fibre-optic second harmonic generation microscopy which requires the polarisation preservation to extract molecular organization of a sample.     

Direct decoration of disclinations by solidification-induced band texture for a nematic side chain liquid crystalline polymer

For a nematic polymethacrylate side chain liquid crystalline polymer, g 154 N 298 I (°C), the solidification-induced band texture has been observed aligned along the disclination under a polarizing optical microscope, when the specimen was quenched from 280°C to room temperature. The decoration technique of solidification-induced band texture, which is usually reported for main chain liquid crystalline polymers, was then introduced to reveal the director field pattern along a disclination for this side chain liquid crystalline polymer. It was found by infra-red dichroism measurements that the director orientation is parallel with the direction of the band. On this basis, disclinations with strength s=±1/2 and s=±1 were mapped according to the corresponding pattern of solidification-induced band texture. In addition, two types of inversion wall, loop-like and splay-type walls, were also found to be decorated by the solidification-induced band texture.     

氯苯的同步辐射光电离研究

利用真空紫外同步辐射和反射式飞行时间质谱仪对氯苯进行了光电离研究,通过测量各离子的光电离效率(PIE)曲线,得到了氯苯的电离势为(9.11±0.05)eV及两种主要碎片离子C6H+5和C4H+3的出现势分别为(12.96±0.05)和(16.27±0.05)eV.结合有关文献的热力学数据,推导出C6H5Cl+、C6H+5及C4H+3的离子生成焓及一些键的解离能.实验获得了118.0nm同步辐射光电离下氯苯的质谱图.     

Mössbauer study of Fe-B alloys containing Nd additives

The influence of a few percent neodynium additives to Fe-B alloy on the hyperfine parameters was investigated. It was found that Nd decreases the hyperfine field of amorphous Fe-B alloys. The samples annealed at temperatures between 600°C and 700°C contain α-Fe and Fe₃B phases. The average hyperfine field of Fe₃B phase increases with increasing Nd content and decreases with increasing annealing temperature. The average isomer shift of Fe₃B phase decreases with increasing Nd content. The experimental data show that the change of hyperfine parameters of the Fe₃B phase in the studied alloys is due to Nd atom.     

一种求解虚波长路径光网络波长资源优化问题的启发式算法

本文提出了一种虚波长路径光网络的启发式路由选择算法,它可以用来解决以最小化网络所需波长数目为目标的资源优化问题.该算法应用了基于最大概率路径的选路优化策略.对一个样例网络的数值分析结果表明该算法是有效的.     

缺项幂级数的最小模与最大项(英文)

在本文中我们研究缺项幂级数的最小模与最大项间的关系，改进了Ｐ．Ｅｒｄｏｓ和Ａ．Ｊ．Ｍａｃｉｎｔｙｒｅ的结果     

成组Broyden修正矩阵的紧凑形式与成组记忆修正算法

1 引言 成组型线性方程组 其中,p是适中的数值,由于其有相当的实际应用背景,人们一直在研究有效的数值方法,特别是近年来,实际问题中归结出来的成组型方程组,其规模越来越大,又具有稀疏结构,因而使用迭代法是一种有效的途径,目前使用比较多的是Krylov子空间方法中的Lanczos方法,CG方法,GMRES方法等等。这种成组型算法的建立,其基本出发点是使算法具有较少的计算量和存储量,具体体现在: 1)成组型算法在应用于问题(1.1)的求解时,也具有有限终止性性质,而其终止步数一般要比单个型算法的步数减少了户倍,由于成组型算法每迭代一步的计算量基本上等同于单个型算法使用户次的计算量,如此,算法的计算量会有明显的改善。 2)当A存储在二级(secondary)内存时,在迭代计算时需要不断地进行存取交换,由于成组型算法的迭代步数减少了户倍,如此,用在这种交换的时间也要减少户倍,相当有效。 3)由于在成组型算法中,出现的多是AX的形式,其中,故成组型算法便于计算并行化。 4)即使用于求解单个方程组,当A的少数几个极端特征值分离甚远时,这种成组型算法也有可能改善其收敛速度,如成组型的CG方法。 目前,这种成组型算法已体现出很大的实用计算价值,然而其进一步的理论分析还有待深入研究。     

On convergence of a semi-analytical method for American option pricing

We examine the valuation of American put options by a semi-analytical method, and obtain the prior estimate and the convergence of the approximate solution. Our proofs are based on the embedding theorem in Sobolev space and the theory of functional analysis, in particular, the theory of weak compactness. The results in this paper theoretically confirm empirical observations that these methods are accurate and computationally efficient.     

Applicability of improved Rayleigh-Sommerfeld method 1 in analyzing the focusing characteristics of cylindrical microlenses

The applicability of an improved Rayleigh-Sommerfeld method 1 (IRSM1) is investigated by analyzing the focal characteristics of various cylindrical microlenses in both cases of the TE and TM polarizations. The IRSM1 and original Rayleigh-Sommerfeld method 1 (ORSM1) are compared with rigorous boundary element method (BEM) by calculating the average square-root deviation (ASRD) of the intensity distribution on the focal plane for the continuously refractive microlens and diffractive microlenses with continuously varying or 8-level quantized profiles. The results indicate that the applicability of the IRSM1 has limitation in some parametric ranges, for instance, the number of sampling points, f-number, relatively refractive index, and wavelength of the incident light are restricted to some appropriate values.