Copper‐catalyzed Clauson–Kass pyrroles synthesis in aqueous media

An efficient and convenient copper‐catalyzed Clauson–Kass reaction of 2,5‐dimethoxytetrahydrofuran with amines in aqueous media has been developed, providing a wide range of N‐substituted pyrroles in good yields. It is noteworthy that the Clauson–Kass reaction of 2,5‐dimethoxytetrahydrofuran with p‐phenylenediamine or m‐phenylenediamine proceeds smoothly to afford the corresponding monopyrroles and bispyrroles with high selectivity in impressive yields. A plausible mechanism for the formation of N‐substituted pyrroles has been proposed. Copyright © 2012 John Wiley & Sons, Ltd.     

Resorcinarenes的合成及其边缘化学修饰(Ⅱ)

探讨了烷基醛类（丁醛、戊醛、异丁醛）的Ｒｅｓｏｒｃｉｎａｒｅｎｅｓ的合成及其边缘化学修饰（乙酰化、甲基化），研究了烷基取代基对合成的影响，并用ＩＲ，＾１ＨＮＭＲ，ＭＳ和ＵＶ对这些化合物进行了表征。     

Synthesis of a water-soluble cationic chiral diamine ligand bearing a diguanidinium and application in asymmetric transfer hydrogenation

A novel water-soluble cationic N-monosulfonated chiral diamine ligand diguanidinium 1c was easily prepared from (R,R)-DPEN and its rhodium complex and was successfully applied in the asymmetric transfer hydrogenation of prochiral ketones and imines in water by using sodium formate and formic acid as co-hydrogen donors. Various substrates were reduced with high yields and good to excellent enantioselectivities (up to >99% ee).     

Si-rhodamine based water-soluble fluorescent probe for bioimaging of Cu+

A Si-substituted rhodamine based water-soluble fluorescent probe bearing a tetrathia-azacrown was designed for fluorescence imaging of Cu⁺ with substantial affinity and selectivity.In physiological condition,the developed probe with outstanding water-solubility exhibits ultrahigh sensitivity to Cu⁺,ensuring the reliable fluorescence imaging in vivo.     

The twoscale asymptotic error analysis for piezoelectric problems in the quasi-periodic structure

Applications for piezoelectric efect have grown rapidly,and piezoelectric materials play important roles in countless areas of modern life.By means of twoscale method and coupled boundary layer,some new kinds of twoscale asymptotic expansions for solutions to the electrical potential and the displacement in quasi-periodic structure under coupled piezoelectric efect are derived,and the homogenization constants of piezoelectric materials are presented.The coupled twoscale relation between the electrical potential and the displacement is set up,and some improved asymptotic error estimates are analyzed.     

n次单位根在代数问题中的应用

主要论述n次单位根在一些组合数求和、多项式的整除、因式分解中的应用,说明了n次单位根法可拓宽解题思路,是一种方便、快捷的数学解题方法.     

Chemoselective and enantioselective transfer hydrogenation of β,β-disubstituted nitroalkenes catalyzed by a water-insoluble chiral diamine–rhodium complex in water

Asymmetric transfer hydrogenation of β,β-disubstituted nitroalkenes catalyzed by a chiral diamine–rhodium complex in combination with HCO₂Na–HCO₂H as a hydrogen source in water was successfully realized with high reactivity, excellent chemoselectivity and good enantioselectivity. The metal precursor and pH value of the aqueous solution have a large influence on the reactivity and chemoselectivity. The substituents on the benzene rings and the sulfonyl groups of TsDPEN have significant effects on the enantioselectivity. This catalytic asymmetric transformation is one of the most practical pathways to obtain optically active nitroalkanes.     

微波消解-火焰原子吸收光谱法测定三七中的微量元素

采用微波消解处理三七,用火焰原子吸收光谱法测定Mn、Zn、Cu、Fe4种微量元素的含量.三七中Mn、Zn、Cu、Fe含量分别为9.30、19.54、178.45、3.05μg· g-1.该方法加标回收率在98.1％-102.8％之间,方法简单、快捷、准确,可为三七的现代研究提供依据.