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991.
A feasibility study in the use of membranes for the recovery of L-asparaginase from the fermentation stage has been undertaken. In the cell harvesting stage 100 l of broth (0.55% dry weight approx) of Erwinia carotovora is concentrated to 3.2 l by a I m2 prototype cross flow microfiltration unit in just over 4 hours. Cell disruption was carried out by raising the cell suspension to pH 11.5 to release the enzyme, which is stable in alkali, for a short period. After neutralisation by acetic acid addition, the enzyme is separated from the cell debris by filtration with 0.45 μm Asypor membranes. A preliminary economic analysis shows that the membrane process can compete favourably with the conventional process, which employs high speed centrifuges. 相似文献
992.
M. Olomucki J.Y. Le Gall S. Colinart F. Durant B. Norberg G. Evrard 《Tetrahedron letters》1984,25(32):3471-3474
The NH2 group and the adjacent ring nitrogen of adenosine and cytidine react with α-acetylenic esters by addition across the triple bond and formation of a lactam with the ester group. 相似文献
993.
The temperature dependence of the drift mobility of excess charge carriers in liquid and solid hydrogen has been investigated. Both negative and positive carriers are observed in the liquid with mobilities ~ 5 × 10-3 cm2 V-1 sec-1 at 15 K; the mobile carriers in the solid are believed to be negatively Charged with a mobility ~ 6 × 10-6 cm2 V-1 sec-1 at 13 K. The mechanisms of charge localization and transport are discussed. 相似文献
994.
Summary Caesium stearate- and caesium palmitate-water systems are investigated by DSC measurements. Thermodynamical data of transition between crystallized form and mesomorphic state indicate a greater disorder of the chains for these soaps than for lecithin, in the same lamellar structure. The study of the water melting in an extended range of concentration allows us to distinguish different behaviors: the simplest two phases model for the two extremes ranges of concentration (y < 20% and > 60%) is proposed to explain the stability of the freezing temperature and enthalpy; the solubilization of conter-ions in water and the bonding of some water molecules could explain the depression of freezing temperature and the decrease of enthalpy, in the intermediate range of concentration.
With 4 figures and 1 table 相似文献
Résumé Nous avons étudié par DSC les transitions de phase dans les systemes stearate et palmitate de cesium-eau. Les parametres thermodynamiques de la fusion des chaines paraffiniques révèle que dans les phases mésomorphis le désordre des chaines est plus grand que dans les systemes lecithine-eau. L'étude de la fusion de l'eau, a l'intérieur d'une phase lamellaire bien caractérisée, nous permet de distinguer plusieurs comportements: le modele le plus simple ä deux phases permet d'interpreter la stabilité de l'enthalpie et de la température de fusion dans les deux domaines extremes de concentration en eau (y < 20% et > 60%); la solubilisation des contre ions dans l'eau et la fixation de quelques molecules d'eau pourrait expliquer l'abaissement de la température de fusion et la diminution d'enthalpie, dans le domaine intermédaire de concentration.
With 4 figures and 1 table 相似文献
995.
996.
Phosphorescence excitation and emission spectral peaks, lifetimes, working curves and limits of detection of 22 organic compounds of pharmacological importance in rigid (77°K) ethanolic solution are given. Ethanol can be easily prepared in a high degree of purity, and most drugs are much more soluble in ethanol than in most solvents previously used for phosphorimetric studies. The possible application of phosphorimetry to the trace analysis of drugs in biological fluids is discussed. 相似文献
997.
998.
999.
1000.
The energy transfer of homogeneous scalar turbulence is studied numerically by triad interaction in spectral space. The different transfer properties between turbulent kinetic energy and turbulent scalar energy reveal that non-local energy transfer exists as important as the local energy transfer in scalar turbulence. The non-local energy transfer of scalar turbulence results from non-local triad interaction. As a result there will be longer inertiaconvective range in scalar turbulence than the inertial subrange in turbulent kinetic transfer at Reλ = Peλ. The non-local transfer of turbulent scalar energy generates more energy transfer into dissipation range. The discovery of non-local transfer of turbulent scalar energy indicates that this phenomenon should be concerned carefully in numerical scheme and subgrid modelling of direct numerical simulation or large eddy simulation scalar turbulence. 相似文献