全文获取类型
收费全文 | 276篇 |
免费 | 9篇 |
国内免费 | 2篇 |
专业分类
化学 | 203篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 25篇 |
物理学 | 55篇 |
出版年
2024年 | 1篇 |
2023年 | 3篇 |
2022年 | 3篇 |
2021年 | 10篇 |
2020年 | 9篇 |
2019年 | 8篇 |
2018年 | 8篇 |
2017年 | 14篇 |
2016年 | 11篇 |
2015年 | 5篇 |
2014年 | 6篇 |
2013年 | 18篇 |
2012年 | 24篇 |
2011年 | 26篇 |
2010年 | 9篇 |
2009年 | 11篇 |
2008年 | 32篇 |
2007年 | 16篇 |
2006年 | 22篇 |
2005年 | 17篇 |
2004年 | 10篇 |
2003年 | 5篇 |
2002年 | 5篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1999年 | 1篇 |
1996年 | 2篇 |
1994年 | 3篇 |
1993年 | 2篇 |
1981年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有287条查询结果,搜索用时 15 毫秒
31.
We prove that a C
*-algebra A or a predual N
* of a von Neumann algebra N has the Daugavet property if and only if A (or N) is non-atomic. We also prove a similar (although somewhat weaker) result for non-commutative L
p-spaces corresponding to non-atomic von Neumann algebras. 相似文献
32.
Timur Oikhberg 《Archiv der Mathematik》2006,86(4):356-364
We construct a “universal space” for 1-exact finite dimensional operator spaces (an analogue of the Gurarii space).
Received: 20 June 2005 相似文献
33.
Weng CC Liao JD Wu YT Wang MC Klauser R Zharnikov M 《The journal of physical chemistry. B》2006,110(25):12523-12529
The modification of octadecanethiolate self-assembled monolayers on Au and Ag by nitrogen-oxygen downstream microwave plasma with variable oxygen content (up to 1%) has been studied by synchrotron-based high-resolution X-ray photoelectron spectroscopy. The primary processes were dehydrogenation, desorption of hydrocarbon and sulfur-containing species, and the oxidation of the alkyl matrix and headgroup-substrate interface. The exact character and the rates of the plasma-induced changes were found to be dependent on the substrate and plasma composition, with the processes in the aliphatic matrix and headgroup-substrate interface being mostly decoupled. In particular, the rates of all major plasma-induced processes were found to be directly proportional to the oxygen content in the plasma, which can be, thus, considered as a measure of the plasma reactivity. Along with the character of the observed changes, exhibiting a clear dominance of the oxidative processes, this suggests that the major effect of the oxygen-nitrogen downstream microwave plasma is provided by reactive oxygen-derived species in the downstream region, viz. long-living oxygen radicals and metastable species. 相似文献
34.
35.
Zubavichus Y Shaporenko A Grunze M Zharnikov M 《The journal of physical chemistry. B》2006,110(7):3420-3427
The experimental solid-state near-edge X-ray absorption fine structure spectra for a series of glycine-related samples including alpha-glycine, beta-glycine, glycinium chloride, glycinium trifluoroacetate, and sodium glycinate at the C, N, and O K-edges measured under identical conditions are reported and compared. An assignment of spectral features for alpha-glycine is proposed on the basis of extended theoretical simulations of polarization-dependent spectra performed within the real-space multiple-scattering formalism explicitly taking into account the intermolecular environment of a glycine molecule in a crystal. 相似文献
36.
Chen CH Huang ML Wang SC Klauser R Shaporenko A Zharnikov M 《The journal of physical chemistry. B》2006,110(36):17878-17883
Patterned self-assembled monolayers (SAMs) of alkanethiolates (AT) on Au and Ag substrates were imaged and characterized by scanning photoelectron microscopy (SPEM). The patterns were prepared in situ by direct writing with the zone-plate-focused X-ray beam provided by the SPEM station. Whereas both AT/Au and AT/Ag behaved alike upon the irradiation, which resulted in similar contrasts in the fabricated patterns and similar microspot spectra from the irradiated areas, the intensity relationship between the patterned and nonpatterned areas changed by different pathways for the Au and Ag substrates after the exposure of the patterns to ambient. The SPEM data imply that weakly bound molecular fragments are desorbed from the irradiated areas upon air exposure in the case of Ag, whereas adsorption of airborne molecules from ambient occurs for the Au substrate. The origin of the observed differences is presumably related to the specific branching patterns of irradiation-induced modification of AT/Au and AT/Ag. 相似文献
37.
We study problems in interfacial fluid dynamics which do not have well-posed initial value problems. We prove existence of solutions for these problems by considering instead boundary value problems, where boundary data is specified at two different times. We develop a general framework, for problems on the real line and for problems which are spatially periodic. A variety of boundary conditions are considered, including Dirichlet, Neumann and mixed conditions. The framework is applied to two specific problems from interfacial fluid dynamics: a family of generalizations of the Boussinesq equations developed by Bona, Chen and Saut, and the vortex sheet. 相似文献
38.
Timur I. Nezhmetdinov 《代数通讯》2013,41(12):4669-4681
Let R be a finite commutative ring with identity and ? p d be the cyclic group of prime power order. Define R? p d to mean the group ring of ? p d over R. We determine the structure of the group of units of R? p d in the case when R is generated by an element whose order is not divisible by p. 相似文献
39.
Mathieu Lobet Masaki Kando James K. Koga Timur Zh. Esirkepov Tatsufumi Nakamura Alexander S. Pirozhkov Sergei V. Bulanov 《Physics letters. A》2013
A method for the controlled generation of intense high frequency electromagnetic fields by a breaking Langmuir wave (relativistic flying mirrors) in a gradually inhomogeneous plasma is proposed. The wave breaking threshold depends on the local plasma density gradient. Compression, chirping and frequency multiplication of an electromagnetic wave reflected from relativistic mirrors is demonstrated using Particle-In-Cell simulations. Adjusting the shape of the density profile enables control of the reflected light properties. 相似文献
40.
Timur M. Galiullin Nadezhda V. Pokhvishcheva Andrey V. Kalinichev Maria A. Peshkova 《Electroanalysis》2019,31(9):1708-1718
In this paper we report on the novel polymeric membranes for the liquid junction‐free reference electrodes. The membranes contain the ionic liquids (ILs) based on the amino acid anions, namely valine‐, leucine‐, lysine‐ and histidine‐anions, and 1‐butyl‐3‐methylimidazolium cation. Addition of the ILs, and especially of the valine‐based one, to the polymeric plasticized membranes allows significant stabilization of the electrode potential and makes it insensitive to the solution composition. A simple criterion based on the calculated lipophilicities of the cation and anion of the IL is proposed for a priori estimation of its applicability for potential stabilization. The addition of the IL as a microcomponent is found to be advantageous over plasticizing the membrane with the IL due to better potential stability, higher dissociation degree and mobility of the species. The resistance of the novel reference membranes can be tuned by addition of the lipophilic membrane electrolytes, e. g. ETH500. The applicability of the developed reference electrodes is verified in the potentiometric calibration of the indicator K+‐ and Ca2+‐selective electrodes. Implementation of the amino acid‐based ionic liquids with low environmental toxicity can make a significant contribution to the development of nature‐friendly potentiometry. 相似文献