全文获取类型
收费全文 | 147970篇 |
免费 | 1527篇 |
国内免费 | 399篇 |
专业分类
化学 | 81057篇 |
晶体学 | 2389篇 |
力学 | 6082篇 |
综合类 | 3篇 |
数学 | 13732篇 |
物理学 | 46633篇 |
出版年
2021年 | 1045篇 |
2020年 | 1206篇 |
2019年 | 1293篇 |
2018年 | 1655篇 |
2017年 | 1704篇 |
2016年 | 2570篇 |
2015年 | 1602篇 |
2014年 | 2399篇 |
2013年 | 6107篇 |
2012年 | 4965篇 |
2011年 | 6078篇 |
2010年 | 4239篇 |
2009年 | 4240篇 |
2008年 | 5826篇 |
2007年 | 5592篇 |
2006年 | 5468篇 |
2005年 | 5024篇 |
2004年 | 4499篇 |
2003年 | 4165篇 |
2002年 | 4032篇 |
2001年 | 5549篇 |
2000年 | 3978篇 |
1999年 | 3079篇 |
1998年 | 2117篇 |
1997年 | 2220篇 |
1996年 | 2073篇 |
1995年 | 1918篇 |
1994年 | 1920篇 |
1993年 | 1728篇 |
1992年 | 2214篇 |
1991年 | 2299篇 |
1990年 | 2137篇 |
1989年 | 2104篇 |
1988年 | 2080篇 |
1987年 | 2086篇 |
1986年 | 1911篇 |
1985年 | 2374篇 |
1984年 | 2393篇 |
1983年 | 1912篇 |
1982年 | 1915篇 |
1981年 | 1757篇 |
1980年 | 1739篇 |
1979年 | 2028篇 |
1978年 | 2106篇 |
1977年 | 2051篇 |
1976年 | 1977篇 |
1975年 | 1862篇 |
1974年 | 1849篇 |
1973年 | 1882篇 |
1972年 | 1239篇 |
排序方式: 共有10000条查询结果,搜索用时 109 毫秒
131.
The influence of interatomic distances on magnetic ordering in RMnSi compounds (R=La, Y, Sm, and Gd)
S. A. Nikitin T. I. Ivanova Yu. A. Ovchenkova M. V. Maslennikova G. S. Burkhanov O. D. Chistyakov 《Physics of the Solid State》2002,44(2):308-311
Magnetic ordering in the RMnSi (R=La, Y, Sm, and Gd) compounds is investigated. It is found that the type of magnetic ordering depends on the d Mn-Mn distance between manganese atoms inside the magnetic layers located in the planes perpendicular to the c axis. This inference is based on the results of studies performed with SmMnSi and GdMnSi compounds in which the distances between manganese atoms are close to the critical value d Mn-Mn that corresponds to the crossover between ferromagnetic and antiferromagnetic ordering in RMnSi compounds. The introduction of lanthanum and yttrium atoms into the rare-earth sublattice leads to an increase and a decrease in the unit cell size, respectively, and brings about magnetic phase transitions in the compounds under investigation. 相似文献
132.
Sanzharov N. A. Yarovoi A. T. Bekhtereva E. S. Ulenikov O. N. 《Russian Physics Journal》2002,45(10):1024-1031
Analytical formulas are derived that describe the dependences of the transition probabilities in vibrational-rotational spectra of XY3-type molecules with C
3v
symmetry on the rotational quantum numbers. 相似文献
133.
The interaction between azathioprine (AZ) and bovine serum albumin (BSA) is mainly due to hydrophobic binding according to the dependence of the binding constant on the ionic strength obtained by equilibrium dialysis. The binding constant and partition coefficient of AZ were smaller than those of warfarin, phenylbutazone and ibuprofen. Little variation in the proton chemical shift of AZ was observed whether there was an absence or presence of BSA (7.25 x 10(-5) M). The spin-lattice relaxation time (T1) of AZ decreased in the presence of BSA to 6-22%. The spin-spin relaxation rate (1/T2) of AZ increased 16-24 times for the methyl group and the imidazole ring and 8-13 times for the purine ring in the presence of BSA. The ratio of the spin-spin relaxation rate of the free AZ to the bound AZ ((1/T2)b/(1/T2)f) of the methyl group and the imidazole ring was 2-3 times larger than that of the purine ring. The binding of AZ to BSA was concluded to be mainly at the methyl group on the imidazole ring of AZ. 相似文献
134.
135.
136.
137.
A three-dimensional molecular dynamics (MD) model is utilized to investigate the effect of tool geometry on the deformation process of the workpiece and the nature of deformation process at the atomic-scale. Results show that different states exist between the atomic force microscope (AFM) pin tool and the workpiece surface, i.e. the non-wear state, the ploughing state, the state in which ploughing is dominant and the state in which cutting plays a key role. A relationship between the deformation process of the workpiece and the potential energy variation is presented. The potential energy variation of atoms in different deformed regions in the workpiece such as plastically deformed region, elastically deformed region and the mixed deformation region is different. The features of variations of potential energy are discussed. 相似文献
138.
A systematic study on the electrochemical behavior of diosmin in Britton-Robinson buffer (pH 2.0-10.0) at a glassy carbon electrode (GCE) was made. The oxidation process of the drug was found to be quasi-reversible with an adsorption-controlled step. The adsorption stripping response was evaluated with respect to various experimental conditions, such as the pH of the supporting electrolyte, the accumulation potential and the accumulation time. The observed anodic peak current at +0.73 V vs. Ag/AgCl reference electrode increased linearly over two orders of magnitude from 5.0x10(-8) M to 9.0x10(-6) M. A limit of detection down to 3.5x10(-8) M of diosmin at the GCE was achieved with a mean recovery of 97+/-2.1%. Based on the electrochemical data, an open-circuit accumulation step in a stirred sample solution of BR at pH 3.0 was developed. The proposed method was successfully applied to the determination of the drug in pharmaceutical formulations. The results compared favorably with the data obtained via spectrophotometric and HPLC methods. 相似文献
139.
This paper is concerned with the implementation and testing of an algorithm for solving constrained least-squares problems. The algorithm is an adaptation to the least-squares case of sequential quadratic programming (SQP) trust-region methods for solving general constrained optimization problems. At each iteration, our local quadratic subproblem includes the use of the Gauss–Newton approximation but also encompasses a structured secant approximation along with tests of when to use this approximation. This method has been tested on a selection of standard problems. The results indicate that, for least-squares problems, the approach taken here is a viable alternative to standard general optimization methods such as the Byrd–Omojokun trust-region method and the Powell damped BFGS line search method. 相似文献
140.