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41.
We consider the appearance of discrete spectrum in spectralgaps of magnetic Schrödinger operators with electric backgroundfield under strong, localised perturbations. We show that forcompactly supported perturbations the asymptotics of the countingfunction of the occurring eigenvalues in the limit of a strongperturbation does not depend on the magnetic field nor on thebackground field. 相似文献
42.
Khaneja N Reiss T Kehlet C Schulte-Herbrüggen T Glaser SJ 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2005,172(2):296-305
In this paper, we introduce optimal control algorithm for the design of pulse sequences in NMR spectroscopy. This methodology is used for designing pulse sequences that maximize the coherence transfer between coupled spins in a given specified time, minimize the relaxation effects in a given coherence transfer step or minimize the time required to produce a given unitary propagator, as desired. The application of these pulse engineering methods to design pulse sequences that are robust to experimentally important parameter variations, such as chemical shift dispersion or radiofrequency (rf) variations due to imperfections such as rf inhomogeneity is also explained. 相似文献
43.
Bishop AI Nieminen TA Heckenberg NR Rubinsztein-Dunlop H 《Physical review letters》2004,92(19):198104
We demonstrate an optical system that can apply and accurately measure the torque exerted by the trapping beam on a rotating birefringent probe particle. This allows the viscosity and surface effects within liquid media to be measured quantitatively on a micron-size scale using a trapped rotating spherical probe particle. We use the system to measure the viscosity inside a prototype cellular structure. 相似文献
44.
Lahtinen P Korpi H Haavisto E Leskelä M Repo T 《Journal of combinatorial chemistry》2004,6(6):967-973
A simple and efficient parallel screening method to evaluate the catalytic activities of homogeneous copper complexes for the oxidation of benzylic alcohols in aqueous solutions with molecular oxygen is reported. Copper(II) sulfate was treated in situ with 22 nitrogen donor ligands, and the catalytic activities of these combinations were studied at four different pH values with two substrates (benzyl alcohol and 3,4-dimethoxy benzyl alcohol (veratryl alcohol)), resulting in 176 oxidation experiments in the primary screening stage. Copper complexes based on N,N,N',N'-tetramethyl ethylenediamine (TMEDA), 9,10-diaminephenanthrene (DAPHEN), and 1,2-diaminocyclohexane (DACH) were determined to be the most active catalysts. In the second screenings, the influence of reaction conditions on Cu(DACH)-, Cu(TMEDA)-, and Cu(DAPHEN)-catalyzed reactions were investigated in more detail. It was found that highly basic reaction conditions favor the reaction with the exception of Cu(TMEDA), which is active at a lower pH range. Under optimized conditions, Cu(DAPHEN) catalyzes the transformation of veratryl alcohol to the corresponding aldehyde with 100% conversion. 相似文献
45.
2-chloro-1,3,2-diazastibolenes react with Lewis acids either via Sb-Cl cleavage to yield stable Sb-analogues of an N-heterocyclic carbene, or via an unprecedented oxidative fragmentation to give a diazadiene-SbCl3 complex. 相似文献
46.
Anomalous absorption of bulk shear sagittal acoustic waves in a layered structure with viscous fluid
It is demonstrated theoretically that the absorptivity of bulk shear sagittal waves by an ultra-thin layer of viscous fluid between two different elastic media has a strong maximum (in some cases as good as 100%) at an optimal layer thickness. This thickness is usually much smaller than the penetration depths and lengths of transverse and longitudinal waves in the fluid. The angular dependencies of the absorptivity are demonstrated to have significant and unusual structure near critical angles of incidence. The effect of non-Newtonian properties and non-uniformities of the fluid layer on the absorptivity is also investigated. In particular, it is shown that the absorption in a thin layer of viscous fluid is much more sensitive to non-zero relaxation time(s) in the fluid layer than the absorption at an isolated solid-fluid interface. 相似文献
47.
48.
Timo Seppä lä inen 《Transactions of the American Mathematical Society》2001,353(12):4801-4829
We prove laws of large numbers for a second class particle in one-dimensional totally asymmetric -exclusion processes, under hydrodynamic Euler scaling. The assumption required is that initially the ambient particle configuration converges to a limiting profile. The macroscopic trajectories of second class particles are characteristics and shocks of the conservation law of the particle density. The proof uses a variational representation of a second class particle, to overcome the problem of lack of information about invariant distributions. But we cannot rule out the possibility that the flux function of the conservation law may be neither differentiable nor strictly concave. To give a complete picture we discuss the construction, uniqueness, and other properties of the weak solution that the particle density obeys.
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50.
Laura Äkäslompolo Ana M. Sánchez Qi Hang Qin Antti Hakola Timo Kajava Sebastiaan van Dijken 《Applied Physics A: Materials Science & Processing》2013,110(4):889-894
We report on the growth of all-oxide SrRuO3/CoFe2O4/La2/3Sr1/3MnO3 and La2/3Sr1/3MnO3/CoFe2O4/SrRuO3 heterostuctures on SrTiO3(001) and MgO(001) substrates by pulsed laser deposition. Structural analyses by X-ray diffraction and transmission electron microscopy clearly indicate the preservation of epitaxial relations when the La2/3Sr1/3MnO3 layer is grown first, whereas trilayers with SrRuO3 at the bottom are more disordered. Both the substrate material and the deposition sequence strongly influence the formation of various structural defects such as interfacial dislocations and sub-grain structures, and this is clearly reflected by a reduction of the saturation magnetization in the top electrode. When the substrate material and the deposition sequence are correctly chosen, however, the magnetic moments of the La2/3Sr1/3MnO3 and SrRuO3 layers reverse independently, and the La2/3Sr1/3MnO3 layer retains bulk-like magnetic properties. 相似文献