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41.
2,2-Dimethyl-4-methoxychromans (1–12) have been converted into 2,2-dimethyl-2H-chromenes (13–24) in acidic media. 相似文献
42.
Jan Rosenboom Dr. Lukas Chojetzki Dr. Tim Suhrbier Dr. Jabor Rabeah Dr. Alexander Villinger Dr. Ronald Wustrack Dr. Jonas Bresien Prof. Dr. Axel Schulz 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(36):e202200624
The activation of C−Br bonds in various bromoalkanes by the biradical [⋅P(μ-NTer)2P⋅] ( 1 ) (Ter=2,6-bis-(2,4,6-trimethylphenyl)-phenyl) is reported, yielding trans-addition products of the type [Br−P(μ-NTer)2P−R] ( 2 ), so-called 1,3-substituted cyclo-1,3-diphospha-2,4-diazanes. This addition reaction, which represents a new easy approach to asymmetrically substituted cyclo-1,3-diphospha-2,4-diazanes, was investigated mechanistically by different spectroscopic methods (NMR, EPR, IR, Raman); the results suggested a stepwise radical reaction mechanism, as evidenced by the in-situ detection of the phosphorus-centered monoradical [⋅P(μ-NTer)2P-R].< To provide further evidence for the radical mechanism, [⋅P(μ-NTer)2P-Et] ( 3Et ⋅) was synthesized directly by reduction of the bromoethane addition product [Br-P(μ-NTer)2P-Et] ( 2 a ) with magnesium, resulting in the formation of the persistent phosphorus-centered monoradical [⋅P(μ-NTer)2P-Et], which could be isolated and fully characterized, including single-crystal X-ray diffraction. Comparison of the EPR spectrum of the radical intermediate in the addition reaction with that of the synthesized new [⋅P(μ-NTer)2P-Et] radical clearly proves the existence of radicals over the course of the reaction of biradical [⋅P(μ-NTer)2P⋅] ( 1 ) with bromoethane. Extensive DFT and coupled cluster calculations corroborate the experimental data for a radical mechanism in the reaction of biradical [⋅P(μ-NTer)2P⋅] with EtBr. In the field of hetero-cyclobutane-1,3-diyls, the demonstration of a stepwise radical reaction represents a new aspect and closes the gap between P-centered biradicals and P-centered monoradicals in terms of radical reactivity. 相似文献
43.
Felipe J. Llanes-Estrada Tim Van Cauteren Ángel P. Martín 《The European Physical Journal C - Particles and Fields》2007,51(4):945-952
We study the multiple solutions of the truncated propagator Dyson–Schwinger equation for a simple fermion theory with Yukawa
coupling to a scalar field. Upon increasing the coupling constant g, other parameters being fixed, more than one non-perturbative
solution breaking chiral symmetry becomes possible and we find these numerically. These “recurrences” appear as a mechanism
to generate different fermion generations as quanta of the same fundamental field in an interacting field theory, without
assuming any composite structure. The number of recurrences or flavors is reduced to the question of the value of the Yukawa
coupling, and it has no special profound significance in the standard model. The resulting mass function can have one or more
nodes and the measurement that potentially detects them can be thought of as a collider-based test of the virtual dispersion
relation for the charged lepton member of each family. This requires the three independent measurements of the charged lepton’s energy,
three-momentum and off-shellness. We illustrate how this can be achieved for the (more difficult) case of the tau lepton.
PACS 12.15.Ff; 11.30.Rd 相似文献
44.
A. Ertoprak B. Cederwall C. Qi M. Doncel U. Jakobsson B. M. Nyakó G. Jaworski P. Davies G. de France I. Kuti D. R. Napoli R. Wadsworth S. S. Ghugre R. Raut B. Akkus H. Al Azri A. Algora G. de Angelis A. Atac T. Bäck A. Boso E. Clément D. M. Debenham Zs. Dombrádi S. Ertürk A. Gadea F. Ghazi Moradi A. Gottardo T. Hüyük E. Ideguchi H. Li C. Michelagnoli V. Modamio J. Nyberg M. Palacz C. M. Petrache F. Recchia M. Sandzelius M. Siciliano J. Timár J. J. Valiente-Dobón Z. G. Xiao 《The European Physical Journal A - Hadrons and Nuclei》2018,54(9):145
45.
Hyun Jong Park Olga Kryliouk Tim Anderson Dmitry Khokhlov Timur Burbaev 《Physica E: Low-dimensional Systems and Nanostructures》2007,37(1-2):142
InN films and nanorods were grown by hydride metalorganic vapor phase epitaxy (H-MOVPE) and the effects of growth temperature, and NH3/TMIn and HCl/TMIn ratios on morphological dependences were studied. The growth habit of InN varied from thin film to microrod to nanorod to no deposition as the growth conditions were changed about transition from growth to etching conditions. The growth and etch regimes were also predicted by chemical equilibrium calculations of In–C–H–Cl–N-inert system. The optical properties of InN nanorods and columnar structured films were measured by room temperature PL and a maximum intensity was observed at 1.08 eV for both structures. 相似文献
46.
Durković M Habigt T Rothbucher M Diepold K 《The Journal of the Acoustical Society of America》2011,130(6):EL392-EL398
Sound source localization algorithms determine the physical position of a sound source in respect to a listener. For practical applications, a localization algorithm design has to take into account real world conditions like multiple active sources, reverberation, and noise. The application can impose additional constraints on the algorithm, e.g., a requirement for low latency. This work defines the most important constraints for practical applications, introduces an algorithm, which tries to fulfill all requirements as good as possible, and compares it to state-of-the-art sound source localization approaches. 相似文献
47.
48.
Daniel Townsend Prof. Dr. Kenneth Shankland Dr. Alex Weymouth-Wilson Dr. Zofia Komsta Dr. Tim Evans Dr. Alexander J. A. Cobb 《Chemistry (Weinheim an der Bergstrasse, Germany)》2020,26(16):3504-3508
A highly enantioselective, organocatalytic, and scalable synthesis of a very unusual cis-decalin-cis-hydrindane tricyclic diterpenoid system has been achieved. Despite the prevalent pharmacological space that the related trans,trans and trans,cis-systems occupy, there have been no reports of an asymmetric synthesis of the cis,cis systems in the literature until now. We demonstrate the flexibility of our approach not only through access to a diverse range of products, all of which are attained in exceptionally high selectivities, but also by showing their easy conversion to the corresponding trans,cis-system and other derivatives. 相似文献
49.
Tim Gutzmer 《Results in Mathematics》1996,29(1-2):69-77
In this research a method for interpolation on arbitrary locally compact groups is developed. The method is based on positive definite functions definable on spaces with group multiplication. To be able to use these functions two steps are necessary. First, positive semidefinite functions are determined using Bochners theorem on commutative groups respectively representation theory in the non commutative case. Then transformations are given to get positive definite out of positive semidefinite functions. For the compact group 50(3) the result is explicitly calculated and implemented in the case of three and five dimensional representations, and is applied to the approximation of energy functions of molecule interactions in 3-space. 相似文献
50.
Tim Schuster 《Progress in Particle and Nuclear Physics》2009,62(2):373-374
Two experimental programs are aiming to study nuclear collisions in the energy regime in order to explore an essential part of the phase diagram of strongly interacting matter. The programs are motivated by observations that indicate a phase transition to take place in this energy domain: the onset of deconfinement. The STAR collaboration proposes an energy scan in the Relativistic Heavy Ion Collider (RHIC) at BNL. The ongoing program of the NA61/SHINE experiment consists of a two-dimensional energy-system size scan in nuclear and elementary collisions. The goal of both programs is to study the properties of the onset of deconfinement and to eventually discover the conjectured critical point of strongly interacting matter. A comparison of the strengths and limitations reveals the complementarity of the two programs. 相似文献