全文获取类型
收费全文 | 15503篇 |
免费 | 2665篇 |
国内免费 | 2200篇 |
专业分类
化学 | 11296篇 |
晶体学 | 172篇 |
力学 | 883篇 |
综合类 | 150篇 |
数学 | 1907篇 |
物理学 | 5960篇 |
出版年
2024年 | 40篇 |
2023年 | 315篇 |
2022年 | 563篇 |
2021年 | 633篇 |
2020年 | 639篇 |
2019年 | 717篇 |
2018年 | 556篇 |
2017年 | 527篇 |
2016年 | 769篇 |
2015年 | 811篇 |
2014年 | 964篇 |
2013年 | 1175篇 |
2012年 | 1400篇 |
2011年 | 1407篇 |
2010年 | 993篇 |
2009年 | 1014篇 |
2008年 | 1039篇 |
2007年 | 879篇 |
2006年 | 815篇 |
2005年 | 666篇 |
2004年 | 562篇 |
2003年 | 447篇 |
2002年 | 515篇 |
2001年 | 390篇 |
2000年 | 321篇 |
1999年 | 333篇 |
1998年 | 261篇 |
1997年 | 228篇 |
1996年 | 209篇 |
1995年 | 179篇 |
1994年 | 149篇 |
1993年 | 157篇 |
1992年 | 103篇 |
1991年 | 101篇 |
1990年 | 84篇 |
1989年 | 81篇 |
1988年 | 71篇 |
1987年 | 41篇 |
1986年 | 39篇 |
1985年 | 47篇 |
1984年 | 28篇 |
1983年 | 18篇 |
1982年 | 24篇 |
1981年 | 11篇 |
1979年 | 7篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 4篇 |
1973年 | 3篇 |
1972年 | 4篇 |
排序方式: 共有10000条查询结果,搜索用时 8 毫秒
71.
72.
73.
芦荟大黄素的电化学研究 总被引:8,自引:1,他引:8
用单扫示波极谱法研究了芦荟大黄素的电化学行为。在5%Na2CO3+5%NaOH(9+1)底液中,芦荟大黄素于-0.84V(P1)和-0.97V(P2)处产生两个示波极谱峰,利用P1可测定芦荟大黄素,线性范围为 0.11-24mg/L和3.0-28.6mg/L,检测限为0.06mg/L。将该法应用于中药大黄中的芦荟大黄素的测定,结果满意。另外,讨论了芦荟大黄素清除由邻苯三酚自氧化产生的超氧自由基(O2)的作用。 相似文献
74.
75.
Spectroscopic characterization of effective components anthraquinones in Chinese medicinal herbs binding with serum albumins 总被引:2,自引:0,他引:2
Bi S Song D Kan Y Xu D Tian Y Zhou X Zhang H 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(1-3):203-212
The interactions of serum albumins such as human serum albumin (HSA) and bovine serum albumin (BSA) with emodin, rhein, aloe-emodin and aloin were assessed employing fluorescence quenching and absorption spectroscopic techniques. The results obtained revealed that there are relatively strong binding affinity for the four anthraquinones with HSA and BSA and the binding constants for the interactions of anthraquinones with HSA or BSA at 20 degrees C were obtained. Anthraquinone-albumin interactions were studied at different temperatures and in the presence of some metal ions. And the competition binding of anthraquinones with serum albumins was also discussed. The Stern-Volmer curves suggested that the quenching occurring in the reactions was the static quenching process. The binding distances and transfer efficiencies for each binding reactions were calculated according to the F?ster theory of non-radiation energy transfer. Using thermodynamic equations, the main action forces of these reactions were also obtained. The reasons of the different binding affinities for different anthraquinone-albumin reactions were probed from the point of view of molecular structures. 相似文献
76.
HanMingDING LiPingWANG YongKuiSHAN MingYuanHE 《中国化学快报》2003,14(8):852-855
Deposition of inorganic-organic nano-hybrid ultrathin films onto mesoporous silicate materials has been proven possible by using layer-by-layer assembly method. In combination with sol-gel method, titania, subsequently dye molecules (or polymer) were successfully fabricated onto the inner wall of SBA-15. Their structures were preliminarily characterized by FTIR and solid-state UV-Vis spectroscopy, thermal analysis, and BET surface area measurements,respectively. 相似文献
77.
78.
79.
80.
A single phase solid solution of Ce-Zr-O can be made by using NH4HCO3 solution as precipitating agent. The influence of preparation conditions, such as pH, Zr4+/(CO3
2-+HCO3
-) and Ce3+/Zr4+ ratio on the formation of the solid solution were investigated. The results show that a single phase Ce-Zr-O solid solution
can be formed only under a narrow window of preparation conditions, indicating that some compounds are formed in the precipitating
process. The compound may contain Ce3+, Zr4+, CO3
2-, HCO3-, and OH-. The solid solution so prepared can be described as Ce0.37Zr0.63O2.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献