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61.
Mono and disubstituted acetylenes react with aryl iodides containing a variety of functional groups in the presence of palladium catalyst, formic acid and a tertiary amine to give trisubstituted alkenes. 相似文献
62.
63.
Giuseppe Chidichimo Marcello Longeri Giuseppina Menniti Giovanni Romeo Alida Ferlazzo 《Magnetic resonance in chemistry : MRC》1984,22(1):52-54
The ring mobility of some 1,5-benzodiazepine-2,4-diones and 1,4-benzodiazepin-2-one has been investigated by the temperature dependence of their 1H NMR spectra. The activation parameters have been obtained, and the influence of N-1 substitution on the ring mobility is discussed, taking into account previously reported data for similar compounds. 相似文献
64.
M. Tiecco L. Testaferri M. Tingoli D. Chianelli M. Montanucci 《Tetrahedron letters》1984,25(43):4975-4978
Alkyl and aryl selenide anions react with unactivated vinyl halides, in dipolar aprotic solvents, to give alkyl or aryl vinyl selenides in good yields. These reactions are stereospecific and occur with retention of configuration. 相似文献
65.
66.
Alvarez Ruiz J Kivimäki A Stankiewicz M Melero García E Coreno M Ali S Koperski J Rachlew E Vall-Llosera I Serrano G Feyer V Tuckett R 《Physical chemistry chemical physics : PCCP》2006,8(44):5199-5206
The interaction of SF(5)CF(3) with vacuum-UV radiation has been investigated by photon induced fluorescence spectroscopy. Total fluorescence yield and dispersed fluorescence spectra of SF(5)CF(3) were recorded in the 200-1000 nm fluorescence window. In all cases, the fluorescence spectra resemble those of CF(3)X (X = H, F, Cl, and Br) molecules. At photon energies below 20 eV, the emission is attributed to the excited CF(3) and CF(2) fragments. The threshold for the CF(3) emission is 10.2 +/- 0.2 eV, giving an upper limit estimate for the SF(5)-CF(3) bond dissociation energy of 3.9 +/- 0.3 eV. The excitation functions of the CF(3) and CF(2) emissions were measured in the photon energy range 13.6-27.0 eV. The resonant structures observed in SF(5)CF(3) are attributed to electronic transitions from valence to Rydberg orbitals, following similar assignments in CF(3)X molecules. The photoabsorption spectrum of SF(5)CF(3) shows features at the same energies, indicating a strong contribution from Rydberg excitations. 相似文献
67.
68.
This article concerns the antisymmetry, uniqueness, and monotonicity properties of solutions to some elliptic functionals involving weights and a double well potential. In the one-dimensional case, we introduce the continuous odd rearrangement of an increasing function and we show that it decreases the energy functional when the weights satisfy a certain convexity-type hypothesis. This leads to the antisymmetry or oddness of increasing solutions (and not only of minimizers). We also prove a uniqueness result (which leads to antisymmetry) where a convexity-type condition by Berestycki and Nirenberg on the weights is improved to a monotonicity condition. In addition, we provide with a large class of problems where antisymmetry does not hold. Finally, some rather partial extensions in higher dimensions are also given. 相似文献
69.
Marcello Bernardara 《Comptes Rendus Mathematique》2010,348(9-10):565-569
We study semistable pairs on elliptic K3 surfaces with a section: we construct a family of moduli spaces of pairs, related by wall crossing phenomena, which can be studied to describe the birational correspondence between moduli spaces of sheaves of rank 2 and Hilbert schemes on the surface. In the 4-dimensional case, this can be used to get the isomorphism between the moduli space and the Hilbert scheme described by Friedman. 相似文献
70.
Eulogio J. Llorent-Martínez Pilar Ortega-Barrales Muhammad Zakariyyah Aumeeruddy Marcello Locatelli Adriano Mollica 《Analytical letters》2019,52(5):852-868
This study investigates into the pharmacological potential of three solvent extracts (ethyl acetate, methanol, and water) of two Ajuga species (Ajuga chamaepitys subsp. chia var. chia and Ajuga bombycina) based on their antioxidant activity and enzyme inhibitory effects along with establishing the phytochemical profile. Spectrophotometric and high-performance liquid chromatography–electrospray ionization–tandem mass spectrometry (HPLC–ESI–MSn) were used to determine the total and individual phytocompounds, respectively. Antioxidant potential was assessed using different assays such as DPPH, ABTS, CUPRAC, FRAP, phosphomolybdenum, and metal chelation. Enzyme inhibitory effects were studied against acetylcholinesterase, butyrylcholinesterase, tyrosinase, α-amylase, and α-glucosidase. The aqueous extract of both plants showed better ABTS scavenging, FRAP, and metal chelating activities. The methanol extracts displayed the highest tyrosinase inhibitory and antioxidant activity in the phosphomolybdenum assay while the ethyl acetate extracts of both plants showed better butyrylcholinesterase (BChE), α-amylase, and α-glucosidase inhibition. The total phenolic content was highest in the aqueous extract of A. chamaepitys while the methanolic extract of A. bombycina showed the highest flavonoid content. Identification by HPLC–ESI–MSn revealed the presence of some individual compounds including phenolic acids, flavonoids, iridoid glycosides, phenylethanoid glycosides, and other compounds. To conclude, both A. chamaepitys and A. bombycina can be considered as rich sources of phytocompounds to manage chronic diseases. 相似文献