Interaction between graphene and the surface of SiO2

The interaction between graphene and a SiO(2) surface has been analyzed with first-principles DFT calculations by constructing the different configurations based on α-quartz and cristobalite structures. The fact that single-layer graphene can stay stably on a SiO(2) surface is explained based on a general consideration of the configuration structures of the SiO(2) surface. It is found that the oxygen defect in a SiO(2) surface can shift the Fermi level of graphene down which opens up the mechanism of the hole-doping effect of graphene adsorbed on a SiO(2) surface observed in a lot of experiments.     

103 W in-band dual-end-pumped Ho:YAG laser

An efficient 2?μm in-band pumped Ho:YAG laser was demonstrated. The resonator involves two Ho:YAG crystals, each of which was dual-end-pumped by two orthogonally polarized diode-pumped Tm:YLF lasers. The maximum continuous wave output power of 103?W was achieved, corresponding to a slope efficiency of 67.8% with respect to the incident pump power and an optical-to-optical conversion efficiency of 63.5%. Under Q-switched mode, we obtained 101?W laser output at 30?kHz, corresponding to a slope efficiency of 66.2%. The beam quality or M² factor was found to be less than 2.     

A finite element model using multi-layered shell element in laser forming

Due to its enormously high flexibility laser forming has been gaining importance in recent years. This rapidness and flexibility demand very precise controlling strategies especially when simulating the process of large plates and challenging the limited computation power of the current workstation. A simple, robust and accurate modeling method of laser forming has been demonstrated to solve this problem. The simplified model is meshed by multi-layered shell element, simulated with a more real scanning method and fewer parameters. The intelligent meshing strategies have reduced the number of elements dramatically. Thus the simulation efficiency has been improved significantly. By comparing the simulation results under the simplified model with the results under the traditional model for laser forming, the applicability of proposed method has been proven. The method of these simplified models is also suitable to simulate complex finite element models, which take much time to simulate. It would throw some light on the thermal mechanically coupled-field simulation of large sheet.     

掺铁铌酸锂晶体中光致散射的锂组分和温度依赖关系研究

研究了单掺铁铌酸锂晶体的光致散射行为随锂组分以及温度的变化关系.实验表明,随晶体组分的升高,光致散射得到了大幅抑制;不同组分晶体光致散射被完全抑制的温度不同.由此提出掺铁铌酸锂晶体在48.9 mol%-49.3 mol%范围内可能存在一临界锂组分,当晶体组分超过这一临界组分时,晶体光致散射被大幅抑制,而光致散射行为的温度依赖关系明显改变.     

斯特林发动机换热器系统内工质的压力传递变化特性研究

斯特林发动机由于其外部加热特性适合用于分布式供能系统而正在得到越来越多的重视。斯特林机运转时,其内部工质的压力传递变化特性决定了输出机械功率的大小。本文首先采用施密特分析法对自主研制的某型斯特林机在预充氦气压力为2 MPa的工况下计算其压力的周期性变化情况,然后在同样的工况下用实验测试的方法研究工质在换热器系统内的压力传递变化特性。最后比较理论计算值与实验测试值得出,施密特分析法可以反映出斯特林机换热器系统内工质压力的真实变化情况,且叠网式的回热器结构是造成换热器系统内压力损失的主要因素之一。     

Nature of the high-pressure transition in Fe2O3 hematite

We present a new method to separate the crystallographic and electronic phase transitions in hematite using x-ray emission spectroscopy and x-ray diffraction. Our observations, based on the behavior of a metastable high-pressure phase in the stability domain of the low-pressure phase, show that the electronic transition is preempted by the crystallographic transition. The former occurs only afterwards in the high-pressure phase, possibly as a result of a Mott transition. The idea that the electronic transition drives the transition in hematite is therefore invalidated. Such methods should help elucidate the mechanics and the driving forces behind a number of first-order high-pressure phase transitions.     

Shape-dependent local internal stress of α-Cr2O3 nanocrystal fabricated by pulsed laser ablation

The α-Cr₂O₃ single-crystal nanocondensates were fabricated by pulsed laser ablation in air and characterized by analytical electron microscopy regarding shape-dependent local internal stress of the anisotropic crystal. The nanocondensates formed predominantly as rhombohedra with well-developed surfaces and occasionally hexagonal plate with thin edges and blunt corners. Such nanocondensates showed Raman shift for the CrO₆ polyhedra, indicating a local compressive stress up to ca. 4 GPa on the average. Careful analysis of the lattice fringes revealed a local compressive stress (0.5% strain) at the thin edge of the hexagonal plates and a local tensile stress (0.3–1.0% strain) near the relaxed , , and (0 0 0 1) surfaces of truncated rhombohedra. The combined effects of nanosize, capillarity force at sharp edge, and specific surface relaxation account for the retention of a local internal compressive stress built up in an anisotropic crystal during a very rapid heating–cooling process.     

He-BH碰撞体系微分截面的理论计算

用公认精确的密耦近似方法计算了入射能量从25至150 meV时,He原子与基态BH分子碰撞的弹性微分截面、非弹性微分截面和总微分截面,进一步讨论了微分截面的变化趋势及特征.计算结果表明：He-BH碰撞体系的总微分截面具有原子与双原子分子散射的一般规律和特征;随着入射能量的增加,低转动激发态-态微分截面在大角区的散射振荡现象会更加明显. 关键词： He-BH复合物 相互作用势 密耦近似 微分截面     

非晶/结晶共混对聚合物光伏电池性能的影响

以局域规整聚（3-己基噻吩） （P3HT）制备了TiO₂/聚合物型双层结构光伏电池.利用稳态电流-电压测试和动态强度调制光电压谱,结合差热分析、吸收光谱和荧光光谱, 研究了非晶支化聚亚乙基亚胺（BPEI）作为P3HT膜层的添加成分对TiO₂/P3HT双层电池性能的影响.由于P3HT链的高结晶性,使得TiO₂/P3HT界面接触不好,导致电池性能差.当在P3HT中共混重量比W_BPEI/P3HT=1％—5％的BPEI时,电池性能得到显著改善;尤其是当W_BPEI/P3HT= 1％时,电池表现出近0.8V的开路电压和20μA/cm²的短路电流.结果表明BPEI对电池性能的影响不是源于P3HT-BPEI共混体系光学性能的变化,而主要是由于其改变了TiO₂/P3HT界面接触性能.BPEI对TiO₂/P3HT界面接触有两个相互竞争的影响,这取决于P3HT-BPEI共混体系的组成.一方面,通过降低P3HT的结晶度和增强与TiO₂表面的相互作用,改善P3HT链在TiO₂ 表面的附着;另一方面,当BPEI含量过高时,BPEI在TiO₂表面的附着量将增加,反而会阻碍P3HT与TiO₂表面的接触.良好的TiO₂/P3HT界面接触有利于提高激子的界面分离效率、光生电子的寿命和电池效率.本文结果有望为聚合物光伏电池性能的改善提供新的认识和方法. 关键词： 聚（3-己基噻吩） 二氧化钛 共轭聚合物 光伏电池     

New type of Y-branch power splitter and beam expander based on eliminating anomalous reflection effect

We propose a new type of Y-branch power splitter and beam expander with scales of microns in two- dimensional （2D） photonic crystals （PCs） by drilling air holes in a silicon slice. Its functionality and performance are numerically investigated and simulated by finite-difference time-domain （FDTD） method. Simulation results show that the splitter can split a TE polarized light beam into two parallel sub-beams and the distance between them is tunable by changing the parameters of the splitter, while the expander can expand a narrow beam into a wider one, which is realized in an integrated optical circuit. The proposed device is based on the avoiding of anomalous reflection effect and the coupling transmission of defect modes of the interfaces.